首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3618篇
  免费   427篇
  国内免费   67篇
电工技术   22篇
综合类   24篇
化学工业   2528篇
金属工艺   94篇
机械仪表   47篇
建筑科学   22篇
矿业工程   20篇
能源动力   525篇
轻工业   89篇
水利工程   5篇
石油天然气   48篇
武器工业   13篇
无线电   131篇
一般工业技术   403篇
冶金工业   53篇
原子能技术   11篇
自动化技术   77篇
  2024年   2篇
  2023年   130篇
  2022年   114篇
  2021年   118篇
  2020年   205篇
  2019年   137篇
  2018年   111篇
  2017年   177篇
  2016年   230篇
  2015年   213篇
  2014年   230篇
  2013年   260篇
  2012年   247篇
  2011年   215篇
  2010年   137篇
  2009年   166篇
  2008年   174篇
  2007年   336篇
  2006年   326篇
  2005年   115篇
  2004年   57篇
  2003年   64篇
  2002年   45篇
  2001年   51篇
  2000年   28篇
  1999年   26篇
  1998年   11篇
  1997年   4篇
  1996年   11篇
  1995年   6篇
  1994年   7篇
  1993年   15篇
  1992年   8篇
  1991年   10篇
  1990年   6篇
  1989年   8篇
  1988年   12篇
  1987年   28篇
  1986年   28篇
  1985年   9篇
  1984年   6篇
  1983年   3篇
  1982年   7篇
  1981年   5篇
  1980年   2篇
  1979年   3篇
  1978年   2篇
  1976年   1篇
  1951年   6篇
排序方式: 共有4112条查询结果,搜索用时 15 毫秒
11.
The coalescence behavior of two droplets with different viscosities in the funnel-typed expansion cham-ber in T-junction microchannel was investigated experimentally and compared with droplet coalescence of the same viscosity.Four types of coalescence regimes were observed:contact non-coalescence,squeeze non-coalescence,two-droplet coalescence and pinch-off coalescence.For droplet coalescence of different viscosities,the operating range of non-coalescence becomes narrowed compared to the droplet coalescence of same viscosity,and it shrinks with increasing viscosity ratio η of two droplets,indicating that the difference in the viscosity of two droplets is conducive to coalescence,especially when 1 < η< 6.Furthermore,the influences of viscosity ratio and droplet size on the film drainage time (Tdr) and critical capillary number (Cac) were studied systematically.It was found that the film drainage time declined with the increase of average droplet size,which abided by power-law relation with the size dif-ference and viscosity ratio of the two droplets:Tdr ~ (ld)0.25±0.04 and Tdr ~ (η)-0.1±002.For droplet coales-cence of same viscosity,the relation of critical capillary number with two-phase viscosity ratio and dimensionless droplet size is Cac =0.48λ0.26l-2.64,while for droplet coalescence of different viscosities,the scaling of critical capillary number with dimensionless average droplet size,dimensionless droplet size difference and viscosity ratio of two droplets is Cac =0.11 η-0.07ls-2.23ld0.16.  相似文献   
12.
五种化合物临界温度和临界压力的测定   总被引:1,自引:0,他引:1       下载免费PDF全文
The critical properties of five compounds,including propanal,butanal,1-pentanal,2-methel butanal and trimer of ethanal,were determined for the first time by a new capillary quick-flow method. The apparatus was improved with a capillary tube and checked with hexane and 1-heptene as standard reagents. The experimental results proved that the determination of critical properties by quick-flow method with a capillary tube apparatus was successful.  相似文献   
13.
A mathematical model for flowthrough (perfusion) chromatography, namely packed-microtubes (PMT) model, has been proposed for a column packed with biporous (BiP) anion exchanger in which the mesopores and flowthrough pores are created with liquid and solid porogens, respectively. The model is established based on the assumption that the BiP particle is made up of packed microtubes. Bovine serum albumin (BSA) is used as a model protein and three kinds of anion exchangers (i.e., mesoporous, macroporous and BiP resins) are used as adsorbents to determine the model parameters and to evaluate the model. Adsorption equilibrium and finite bath experiments are performed to determine the adsorption isotherms and kinetics parameters. Both the bound amounts of the protein on the surface of the mesopores and macropores are experimentally determined and taken into account in the mathematical model. With all the model parameters determined by independent experiments or calculated from available correlations, model simulations are performed and compared with the experimentally determined breakthrough profiles of the BiP column. It is found that the model predictions agree reasonably well with the experimental data obtained under various conditions and the PMT model fit experimental data better than the modified double linear driving force (LLDF) model proposed by Leitão and Rodriogues (1999. Biochemical Engineering Journal 3, 131) in which the adsorbent particle is considered to be made up of packed microparticles. The results indicate that the PMT model is more reasonable for this kind of BiP adsorbent.  相似文献   
14.
李亚冰  王双元  王为 《电镀与精饰》2007,29(1):32-35,39
印制线路板微孔金属化的关键在于在高厚径比的微孔中形成无空洞、无接缝、均匀的铜沉积层.综述了目前微孔填充技术的发展现状,对电镀过程中采用的电流密度、搅拌因素和电流波形等进行了探讨,重点讨论了添加剂对填孔效果的影响及其作用机理.  相似文献   
15.
A new model to predict the adsorption equilibrium of mixtures containing supercritical components was presented. The difference in the adsorption mechanism between the supercritical components and the condensable components was accounted for in the new model. Lateral interaction in the adsorbed phase was also considered in the local isotherm. The new model was verified by the experimental data of the mixture CH4/CO2/C2H6 on activated carbon JX101 collected for 283-313 K and pressures up to . It was also verified with the experimental data published previously in literature. Considerable improvement in the prediction precision was achieved in using the new model to predict the adsorption of mixtures on activated carbon.  相似文献   
16.
The relationships of composition-properties of 80 jet fuels concerning chemical compositions and several specification properties including density, flashpoint, freezing point, aniline point and net heat of combustion were studied. The chemical compositions of the jet fuels were determined by GC-MS, and grouped into eight classes of hydrocarbon compounds, including n-paraffins, isoparaffins, monocyclopraffins, dicyclopraffins, alkylbenzens, naphthalenes, tetralins, hydroaromatics. Several quantitative composition-property relationships were developed with three artificial neural network (ANN) approaches, including single-layer feedforward neural network (SLFNN), multiple layer feedforward neural network (MLFNN) and general regressed neural network (GRNN). It was found that SLFNNs are adequate to predict density, freezing point and net heat of combustion, while MLFNNs produce better results as far as the flash point and aniline point prediction are concerned. Comparisons with the multiple linear regression (MLR) correlations reported and the standard ASTM methods showed that ANN approaches of composition-property relationships are significant improvement on MLR correlations, and are comparable to the standard ASTM methods.  相似文献   
17.
The spinel LiMn2O4 cathode material was synthesized with the solid-state reaction method. Four manganese compounds including electrolytic manganese dioxide (EMD), MnCO3, Mn3O4 and nano-EMD were used as Mn sources while LiOH·H2O was used as the uniform Li source. The crystal structure characteristics of these samples produced were investigated by means of XRD, SEM, particle size distribution analysis and specific surface area testing. Their electrochemical properties were also studied by comparing their specific capacity, charge and discharge efficiency and cycle performance.  相似文献   
18.
A mathematical model for simulating the dynamic behaviors of batch phenol biodegradation processes in internal loop airlift bioreactor (ILAB) with gas recirculation using free cells of the yeast Candida tropicalis was established by coupling the fluid dynamic model and the mass balance model. Based on the coupling arithmetic, the program for evaluating batch phenol biodegradation processes was achieved. The predicted results of linear liquid velocities, gas holdups, linear gas velocities, cell and phenol concentration profiles in the riser and the downcomer of the ILAB with gas recirculation agreed very well with the corresponding experimental data, and the applicability and reliability of this proposed model were validated.  相似文献   
19.
The possibility of multiplicity in an isothermal continuous mixed suspension-mixed product removal crystallizer is explored using the bifurcation theory.A process involving agglomeration controlled precipitation is considered in which secondary nucleation occurs simultaneously with primary nucleation.The determinant equations for the existence of multiple steady states are developed and the multiplicity boundaries dependent on the physical and kinetic properties and operational parameters of the process are obtained by resolving these determinant equations.The number of steady states in the precipitator for various multiplicity regions is determined and the linear stability of these steady states is analyzed by using the Routh criterion.  相似文献   
20.
The polymeric microspheres were synthesized by the precipitation copolymerization of glycidyl methacrylate (GMA) with methacrylic acid(MAA) or 2‐hydoxyethyl methacrylate (2‐HEMA) containing styrene (ST) in SC‐CO2. Scanning electron microscopy (SEM) showed that the products were spherical microparticles, with the addition of MAA and/or 2‐HEMA as the monomer, with diameter of 0.2–2 μm. The effects of copolymerization pressure, temperature, and ratios of GMA/MAA, ST, and/or GMA/2‐HEMA, on the particle size and morphology were investigated in detail. A new experiment setup is proposed for the large amount of production, based on the rule of lower monomer concentration, more stable system, and better use of the present polymerization apparatus. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2425–2431, 2007  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号