适于中小型冲床的经济型自动送料机械手研制

在分析目前中小企业冲压产业现状的基础上,对现有国内外冲床送料机构进行了分类汇总并予以比较评估,介绍了与某企业合作研制的一种适合中国中小型冲压生产企业的新经济型自动送料机械手,并对机械手结构进行说明.通过对机械手运动过程及运动原理的分析,得出计划性能指标,通过在企业中的应用,得出实际应用指标及性价比.最后,对由该机械手组...     

NiFe (Oxy) Hydroxides Derived from NiFe Disulfides as an Efficient Oxygen Evolution Catalyst for Rechargeable Zn–Air Batteries: The Effect of Surface S Residues

A facile H₂O₂ oxidation treatment to tune the properties of metal disulfides for oxygen evolution reaction (OER) activity enhancement is introduced. With this method, the degree of oxidation can be readily controlled and the effect of surface S residues in the resulted metal (oxy)hydroxides for the OER is revealed for the first time. The developed NiFe (oxy)hydroxide catalyst with residual S demonstrates an extraordinarily low OER overpotential of 190 mV at the current density of 10 mA cm^?2 after coupling with carbon nanotubes, and outstanding performance in Zn–air battery tests. Theoretical calculation suggests that the surface S residues can significantly reduce the adsorption free energy difference between O* and OH* intermediates on the Fe sites, which should account for the high OER activity of NiFe (oxy)hydroxide catalysts. This work provides significant insight regarding the effect of surface heteroatom residues in OER electrocatalysis and offers a new strategy to design high‐performance and cost‐efficient OER catalysts.     

水热温度对二氧化钛结构及光催化活性的影响

以四氯化钛、环氧丙烷和乙醇为原料,采用水热法在不同温度下分别合成了金红石相纳米二氧化钛及板钛矿相与金红石相混晶结构的纳米二氧化钛,并利用X射线衍射(XRD)、透射电镜(TEM)和N2吸附-脱附对其进行了表征。以甲基橙为探针研究了不同水热温度对二氧化钛光催化活性的影响。     

Effect of microstructural parameters on the properties of W-Ni-Fe alloys

The aim of this research was to examine the effect of microstructural parameters on the tensile properties of dif- ferent compositions of tungsten heavy alloys. The microstructural parameters (grain size, connectivity, contiguity, and solid volume fraction) were measured and were found to have a significant effect on the tensile properties of tungsten-based heavy alloys. The microstructural parameters of W-Ni-Fe alloys are sufficiently different to present a range of me- chanical properties. It is concluded that the mechanical properties of tungsten heavy alloys largely depend on the micro- structural parameters and their ductility is particularly harmed when grains are contiguous.     

Electrodeposition and characterization of Bi2Se3 thin films by electrochemical atomic layer epitaxy (ECALE)

Bismuth selenide thin films were grown on Pt substrate via the route of electrochemical atomic layer epitaxy (ECALE) in this work for the first time. The electrochemical behaviors of Bi and Se on bare Pt, Se on Bi-covered Pt, and Bi on Se-covered Pt were studied by cyclic voltammetry and coulometry. A steady deposition of Bi₂Se₃ could be attained after negatively stepped adjusting of underpotential deposition (UPD) potentials of Bi and Se on Pt in the first 40 deposition cycles. X-ray diffraction (XRD) analysis indicated that the films were single phase Bi₂Se₃ compound with orthorhombic structure, and the 2:3 stoichiometric ratio of Bi to Se was verified by EDX quantitative analysis. The optical band gap of the as-deposited Bi₂Se₃ film was determined as 0.35 eV by Fourier transform infrared spectroscopy (FTIR), which is consistent with that of bulk Bi₂Se₃ compound.     

Preparation of PZT suspensions for direct ink jet printing

The present paper contains an experimental study of two different kinds of PZT suspensions for direct ink jet printing at 25 and 120 °C, respectively. The effect of processing parameters such as mixing time, the amount of dispersant, solid loading and milling method was investigated for the optimisation of viscosity for feasible jetting. The viscosity of PZT suspensions was within 5–15 mPa·s range for room temperature suspensions with MEK/EtOH medium and 10–20 mPa·s for high temperature suspensions with wax medium. FTIR analysis is also presented to explain the rheological behaviour of PZT suspensions. Finally, a demonstration of room temperature jetting of PZT suspension is shown.     

Performance and long-term durability of direct-methane flat-tube solid oxide fuel cells with symmetric double-sided cathodes

In this work, we investigated the performance and stability of a large flat-tube SOFC with symmetric double-sided cathodes (DSC), which was directly fueled with methane. The effect of steam/carbon (S/C) ratio, temperature, and current density on the performance, and long-term stability of the DSC as well as the catalytic behavior of the anode was investigated in details. The thick anode support and inner channels of the DSC formed an efficient microreactor for steam-reforming of methane, resulting in high conversion rate of methane and CO selectivity. In particular, when the S/C was 2, the conversion of CH₄ at 750 °C achieved 100% in the DSC and no carbon deposition was observed. Moreover, the voltage of DSC with was stable throughout 190 h under a discharge current density of 0.257 A cm⁻².     

Stability and formability of complex oxides in M2O3–M′2O3 systems

Based on fundamental thermodynamics and a simple energy model for solid M₂O₃ oxides, two atomic parameters of their constituent elements are identified that govern the solid phase stability in an M₂O₃–M₂′O₃ binary system. They are P₁=|r_A−r_B| and P₂=(r_A+r_O)(r_B+r_O)(r_A+r_B+2r_O), where, r_A, r_B and r_O are the ionic radii of ion A, ion B and oxygen, respectively. Using 237 known M₂O₃–M₂′O₃ systems and these two parameters (P₁ and P₂), new rules were obtained not only on the formability of stable complex oxides but also on the conditions that these compounds being of MM′O₃ stoichiometry and further of ABO₃-type perovskite structure. The classification accuracy of such rules reaches respectively 98.7% for formability of complex oxides, 97.9% for the MM′O₃ stoichiometry test, and 100% for the ABO₃-type perovskite structure prediction. Thirty seven new systems are used to validate these empirical rules, and the prediction is in good agreement with experiment. The influence of ionic size difference on the phase stability is further discussed based on the proposed energy model. The new rules may help material scientists to practically predict new complex compounds as well as to further theoretically study phase stability in M₂O₃–M₂′O₃ systems.     

Carbide stoichiometry in TiCx and Cu–TiCx produced by self-propagating high-temperature synthesis

TiC_x and Cu–TiC_x have been formed by self-propagating high-temperature synthesis (SHS) from elemental powder mixtures with a range of C/Ti ratios. When no copper was present, the carbide stoichiometry closely followed that of the starting powders. In the presence of copper, formation of copper–titanium intermetallics and solid solutions resulted in a different carbide stoichiometry.