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31.
32.
Na Zhou Takuya Matsumoto Takahiro Hosokawa Tetsuya Suekane 《Flow Measurement and Instrumentation》2010,21(3):262-267
Entrapment of the non-wetting phase in porous media has been observed in a variety of fields such as petroleum engineering, geological storage of carbon dioxide, and remediation of ground water. We investigated gas trapping in porous media from a microscopic point of view. High-resolution, three-dimensional images of pore structure and trapped gas bubbles in Berea sandstones were obtained using a micro-focused X-ray CT scanner. We used vertical and horizontal Berea sandstone cores, 8 mm in diameter and 15 mm long. Based on the three-dimensional image analysis, the statistical distribution of the trapped gas volume was estimated. Trapped bubbles have a pore-network scale size and distribute over several pores. In the case of the vertical core, the porosity fluctuates along the flow direction due to the layered structure. The residual gas saturation also fluctuates with porosity along the flow direction. The higher gas saturation in porous layers at the end of gas injection results in a higher trapped gas saturation compared to dense layers. On the other hand, in dense layers the gas saturation at the end of gas injection is almost the same as residual gas saturation. Therefore, most of the gas injected into the dense layers would be trapped. In the case of the horizontal core, the gas saturation at the irreducible water condition is lower than that for the vertical core, because the injected gas selectively passes through the more permeable layers. However, the residual gas saturation is 29.2% for the horizontal core, which is comparable with that for the vertical core (30.9%). Finally, the effect of capillary number on stability of trapped gas bubbles has been estimated. Trapped gas bubbles are stable against the increased flow rate up to a capillary number of 1.0×10?5. 相似文献
33.
《Reactive and Functional Polymers》2007,67(6):515-521
MCM-41-supported poly(γ-mercaptopropylsiloxane palladium(0)) complex [MCM-41-SH-Pd(0)] was conveniently synthesized from commercially available and cheap γ-mercaptopropyltriethoxysilane via immobilization on MCM-41, followed by reacting with palladium chloride and then the reduction with hydrazine hydrate. XRD and XPS spectroscopy were employed to characterize the title palladium complex. It was found that this complex is a highly active and stereoselective catalyst for Heck arylation of conjugated alkenes with aryl halides and can be reused many times without loss of activity. 相似文献
34.
《International Journal of Heat and Mass Transfer》2007,50(7-8):1577-1591
A model of the suction evaporation mode in nucleate boiling from tunnel and pore structures is presented. The model is based on the analysis by Nakayama et al. [W. Nakayama, T. Daikoku, H. Kuwahara, T. Nakajima, Dynamic model of enhanced boiling heat transfer on porous surfaces – Part II. Analytical model, ASME J. Heat Transfer 102 (3) (1980) 451–456] and L.H. Chein and R.L. Webb [A nucleate boiling model for structured enhanced surfaces, Int. J. Heat Mass Transfer 41 (14) (1998) 2183–2195]. Additionally, a detailed phenomenological model of liquid refill has been developed. It has been shown that the process of liquid refill and the time needed for it is strongly dependent on pool height. Effect of liquid pool height on bubble frequency has also been discussed. Finally, a generalized methodology is given for the prediction of boiling data from a structured surface. 相似文献
35.
Dynamic cross-sectional liquid distribution and hold-up in a DN80 separation column filled with structured packings was studied using an ultrafast electron-beam X-ray tomograph with high temporal resolution of 2000 images per second. The modality allows visualisation and characterisation of the counter-current flow before and at the flooding point representing the upper operation limit. Two packings of the same type (Montz B1-MN) with different specific surface area were used to investigate the influence of the packing geometry on the spatial liquid distribution. The system studied was water/air at different gas and liquid loads. The results of the tomographic imaging and corresponding post-processing routines were validated by comparison with conventional draining measurements. 相似文献
36.
Jorge A. Vieyra Salas Anton A. Darhuber 《Chemical Engineering and Processing: Process Intensification》2011,50(5-6):583-588
We studied evaporation rates of volatile liquids deposited onto chemically patterned surfaces by means of experiments and numerical simulations. We quantified the influence of the droplet geometry, in particular circular, triangular, rectangular and square shapes, as well as the influence of contact angles. We considered the two cases of vaporization both in stagnant atmospheres as well as in the presence of well-defined laminar airflows. While lateral air-convection enhances evaporation, it causes a dependence of the evaporation rate on the pattern orientation with respect to the airflow. Neighboring droplets and rivulets tend to mutually reduce their evaporation rate relative to isolated patterns. 相似文献
37.
Andreas Bode 《International Journal of Heat and Mass Transfer》2008,51(1-2):353-360
This article investigates the growth and collapse of a single vapor bubble during subcooled nucleate pool boiling of water at a vertical copper surface. Two high-speed cameras and a hydrophone were used for a synchronized measurement of the bubble life cycle and the pressure transient in the surrounding liquid at a system pressure of 25 kPa. A pressure transient with the basic form of one and a half sine was expected. This expectation was basically confirmed, but additional significant minima and maxima corresponding to a frequency of approximately 60 Hz were found in the pressure transient. The comparison of the bubble volume and the pressure transient leads to the conclusion, that heat transfer effects will have to be considered to explain the deviations from the sine. Pressure wave reflections inside the evaporator are of minor importance since their wave length is much larger than the extensions of the evaporator. 相似文献
38.
Pursuant to the Energy Policy Act of 2005, the High Temperature Gas-Cooled Reactor (HTGR) has been selected as the reference design for the Next Generation Nuclear Plant (NGNP). Stemming from a U.S. Nuclear Regulatory Commission (NRC) HTGR research initiative, a need was identified for validation of systems-level computer code modeling capabilities in anticipation of the eventual need to perform licensing analyses. Because the NRC has used MELCOR for light water reactors (LWR) in the past and because MELCOR was recently updated to include gas-cooled reactor (GCR) physics models, MELCOR is among the system codes of interest to the NRC. This paper describes MELCOR modeling of the General Atomics' Modular High Temperature Gas-Cooled Reactor (MHTGR). The MHGTR is a suitable design for demonstration of MELCOR GCR modeling competency for two reasons: 1) the MHTGR is a predecessor to the more advanced General Atomics’ Gas-Turbine Modular High Temperature Reactor (GTMHR), and 2) experimental data useful for benchmark calculations may soon become available. Using the most complete literature references available for the MHTGR design, researchers at Texas A&M University (TAMU) constructed a MELCOR input deck for the MHTGR to partially validate MELCOR GCR modeling capabilities. Normal and off-normal system operating conditions were modeled with appropriate boundary and initial conditions. MELCOR predictions of system response were obtained for steady-state, pressurized conduction cool-down (PCC), and depressurized conduction cool-down (DCC) scenarios. Code results were checked against nominal MHTGR design parameters, physical intuition, and anticipated GCR thermal hydraulic response. No inherent deficiencies in MELCOR modeling capability were observed, suggesting that the newly-implemented GCR models are adequate for systems-level analysis. If and when experimental benchmark data becomes available, further validation activities may proceed given the modeling efforts discussed herein. 相似文献
39.
《Applied Thermal Engineering》2007,27(11-12):1823-1831
The thermal problems of most electronic components have been solved in recent years by installing various cooling equipments. The passive cooling, which has no need of the fluid-driving devices, can be more reliable and achieved with less cost. In this paper, the Taguchi’s method is applied on the optimization of the passive cooling for electronic systems, and a representative CFD (computational fluid dynamic) model is selectively implemented for statistical analysis. The selected parameters in this study are the power density, mother board orientation, chip geometry, opening between chips and the flow pattern. The optimal combination for thermal cooling is obtained by using a two-level statistical approach. Analysis results indicate that about 50% of the effort in performing experiments and simulations can be saved. Further, the results confirmed that the most important parameters affecting the thermal behaviors are the openings in the mother board, power density, and the flow pattern in sequence. Finally, the concept of opening increases the reliability, reduces the manufacturing cost, and simplifies the assembly procedures. 相似文献
40.
《Journal of power sources》2006,159(2):1300-1304
A composite photocatalyst, Pd–TiO2−xNx–WO3, was synthesized by the template method and characterized by energy dispersive X-ray microanalysis (EDX), X-ray diffraction (XRD), UV–vis spectrometer, and scanning electron microscope (SEM). The results of EDX analysis reveals that the molecular formula of the composite photocatalyst can be expressed as Pd–TiO1.72N0.28–WO3. The UV–vis absorption spectrum indicates that the absorption edge of the catalyst red-shifts to around 600 nm. Under the irradiation with ultraviolet and visible light, the catalyst showed good performance for photocatalytic hydrogen production with a Na2S/Na2SO3 system as the sacrificial agent. 相似文献