Bonelike apatite formation on carbon microspheres

Carbon microspheres with a diameter of 2 μm were prepared by hydrothermal process. The apatite-formation ability of the carbon microspheres was evaluated by soaking them in a simulated body fluid (SBF) for 5 and 10 d and apatite-formation mechanism was also analyzed. The result showed that bonelike apatite was formed on the surface of carbon microspheres. Our study indicates that the carbon microspheres synthesized by this method possess apatite-formation ability and may be used as a bioactive injectable filler for bone tissue regeneration.     

The Effect of High Spatial Harmonics in RF Linac

The effect of high spatial harmonics on beam dynamics in a axisymmetric radio frequency linear accelerator (RF linac) is examined. The high spatial harmonics forms the second order ponderomotive focusing for the relativistical particle beam when the transverse motion is averaged over the period of RF structure, the beam transverse envelop equation is obtained including the ponderomotive focusing force which is useful for the design of RF gun and linac. Under a certain of high spatial harmonics coefficients, the high spatial harmonics increase the energy spread due to the stochasitical beam energy diffusion.     

Chemical compositions and optical properties of HfOxNy thin films at different substrate temperatures

High-k HfO_xN_y thin films have been grown by radio frequency (rf) reactive sputtering of metal Hf target in N₂/Ar/O₂ ambient at different substrate temperatures. The chemical compositions of the films have been investigated as a function of substrate temperature by X-ray photoelectron spectroscopy (XPS). XPS measurements showed that nitrogen concentration increases with an increase in substrate temperature. Room-temperature spectroscopic ellipsometry (SE) with photon energy 0.75–6.5 eV was used to investigate the optical properties of the films. SE results demonstrated that refractive index n increases with an increase in substrate temperature. Based on TL parameters which were obtained from the best fit results used in a simulation of the measured spectra, meanwhile, we conclude that the energy band gap (E_g) decreases with an increase in substrate temperature.     

Application of an electronic nose for quality assessment of modified atmosphere packaged poultry meat

The applicability of an electronic nose for the quality control of modified atmosphere (MA) packaged broiler chicken cuts was evaluated in different temperature regimes. The electronic nose results were compared with those obtained by microbiological, sensory and headspace GC analyses. The electronic nose could clearly distinguish broiler chicken packages with deteriorated quality from fresh packages either earlier than or at the same time as the sensory quality deteriorated. Concerning the microbiological quality, the counts of Enterobacteriaceae and hydrogen sulphide-producing bacteria were most consistent with the electronic nose results. The results indicated that the electronic nose was capable of detecting even early signals of spoilage in MA packed poultry meat.     

An Interval Fuzzy Multiobjective Watershed Management Model for the Lake Qionghai Watershed, China

Integrated watershed management is required to ensure the reasonable use of resources and reconcile interactions among natural and human systems. In the present study, an interval fuzzy multiobjective programming (IFMOP) method was used to solve an integrated watershed management problem. Based on system analysis, an IFMOP model suitable for a lake watershed system {IFMOPLWS} was developed and applied to the Lake Qionghai watershed in China. Scenario analysis and an interactive approach were used in the solution process. In this manner, various system components were incorporated into one framework for holistic consideration and optimization. Integrality and uncertainty, as well as the multiobjective and dynamic characteristics of the watershed system, were well addressed. Using two scenarios, two planning schemes were generated. Agriculture, tourism, macroeconomics, cropland use, water supply, forest coverage, soil erosion, and water pollution were fully interpreted and compared to identify a preferable planning alternative for local agencies. This study showed that the IFMOPLWS is a powerful tool for integrated watershed management planning and can provide a solid base for sustainable watershed management.     

丙酮低压一步法合成甲基异丁基酮催化剂体系研究进展

对丙酮低压一步法合成甲基异丁基酮所需要的催化剂体系及反失活机理进行了详尽的综述，并对近年来的研究工作进行了系统地分析与比较，提出了未来的研究方向。     

First-principles study of the tensile and fracture of the Al/TiN interface

Employing the density functional theory, we investigate the tensile and fracture processes of the Al/TiN(0 0 1) interface. The simulation presents directly the strain–stress relationship, the ideal tensile strength and the process of bond breaking of the system. Through the analysis of deformation, we find that the softer Al layers deform larger than the harder TiN layers during the tensile process. And fracture occurs between the interface and the sub-interface Al layers. In addition, the results show that during the tensile process, the ripple of the interfacial TiN layer decreases gradually with the increment of the strain. Charge transfer was detected from the Al to TiN layers near the interface area during the tensile process by means of charge density and density of states analyses. The charge transfer affects the fracture process. Compared to our previous study of the Al/TiN(1 1 1) interface, the Al/TiN(0 0 1) interface has smaller work of adhesion and larger tensile strength than the Al/TiN(1 1 1) interface. Our investigation shows that the fractures of the Al/TiN(0 0 1) and (1 1 1) interface systems both happen in the Al layers near the interface.     

Preparation of Pb(Zr0.52Ti484848)O3 thin films on silicon-on-insulator substrates by excimer laser deposition combined with rapid thermal annealing

In this paper we report the fabrication of ferroelectric Pb(Zr_0.52Ti_0.48)O₃ (PZT) thin films on Si-on-Insulator (SOI) substrates with and without an electrode by pulsed excimer laser deposition combined with rapid thermal annealing. Based on the structural and interfacial characteristics analysis by X-ray diffraction (XRD), Rutherford backscattering spectroscopy (RBS), cross-sectional transmission electron microscopy (XTEM) and automatic spreading resistance measurement (ASR), the film structure and orientation were revealed to be dependent on the annealing time and annealing temperature as well as deposition temperature. From RBS spectra and XTEM observation it is shown that the PZT thin films did not interact with the top silicon layers of SOI and that the composition of the film was similar to the target. The ASR measurements showed that the electrical properties of PZT/SOI as well as PZT/Pt/SOI were abrupt, and that the electrical properties of the SOI substrates were still good after the PZT growth.