Improving the fill factor of N2200-based all polymer solar cells by introducing EPPDI as a solid additive

A cheap and commercially available small molecule (namely EPPDI) is introduced to the active layer of N2200-based all polymer solar cells as a solid additive. EPPDI at the optimal ratio can improve the D-A nano-scale morphology and reduce trap density of the active layer by filling morphological spaces. As a result, the photovoltaic performance of the resulting devices based on PF2:N2200 are increased from 6.28% to 7.03% with significantly enhanced fill factor. This work demonstrates a facile approach for improving the performance of all polymer solar cells.     

Benzodithiophene-based small molecules with various termini as hole transporting materials in efficient planar perovskite solar cells

In this study we prepared four benzodithiophene (BDT)-based small organic molecules presenting bithiophene (TT), thiophene (FT), carbazole (CB), and triphenylamine (TPA) units, respectively, as termini, and used them as hole transporting materials for perovskite solar cells (PSCs). The high degrees of planarity of these BDT-based small molecules imparted them with high degrees of stacking and charge transport. These small molecules had suitable optical properties and energy level alignments for use in PSCs based on MAPbI₃, with compact-TiO₂ as the electron transporting layer and a BDT-based material as the hole transporting layer, in a n–i–p structure. Among our tested BDT-based materials, the PSC incorporating BDT-TT had the best performance, with an average power conversion efficiency of 13.63%.     

High performance black-to-transmissive electrochromic device with panchromatic absorption based on TiO2-supported viologen and triphenylamine derivatives

A novel black-to-transmissive electrochromic device based on TiO₂-supported viologen and triphenylamine derivatives was designed and constructed via the absorption-complementary approach. In the device, cathodically coloring electrochromic material 1,4-bis[((N-phosphono-2-ethyl)-4,4′-bipyridinium)-methyl]-benzene tetrachloride acted as working electrode and novel anodically coloring electrochromic material (4-((4-(dimethylamino)-phenyl)(4-methoxyphenyl)-amino)-benzyl) phosphonic acid acted as counter electrode. The assembled electrochromic device achieved panchromatic absorption over entire visible spectrum with almost zero transmittance in colored state. The optical contrast (ΔT) of the device realized in this work was comparable to the highest value (60%) among all reported black-to-transmissive ECDs. Furthermore, excellent cycling stability was achieved, which maintained almost 80% of the initial ΔT value at 570 nm after continuous 100,000 switchings. These outstanding comprehensive electrochromic performances potentially make this device a promising candidate for electrochromic device applications.     

Novel spiro-based host materials for application in blue and white phosphorescent organic light-emitting diodes

Two novel spiro-based host materials, namely 3-(9,9′-spirobi[fluoren]-6-yl)-9-phenyl-9H-carbazole (SF3Cz1) and 9-(3-(9,9′-spirobi[fluoren]-6-yl)phenyl)-9H-carbazole (SF3Cz2) were designed and synthesized. Due to the meta-linkage of spirobifluorene backbone, both SF3Cz1 and SF3Cz2 possess triplet energies over 2.70 eV, indicating they could serve as suitable hosts for blue and even white phosphorescent organic light-emitting diodes (PHOLEDs). The fabricated bis(4,6-(difluorophenyl)-pyridinato -N,C′)picolinate (FIrpic) based PHOLEDs hosted by SF3Cz1 and SF3Cz2 exhibited excellent performance with maximum external quantum efficiencies (EQEs) of 18.1% and 19.7%, respectively. Two-color warm white PHOLEDs fabricated by utilizing SF3Cz1 and SF3Cz2 as hosts also achieved high EQEs and low efficiency roll-offs. The results demonstrate that SF3Cz1 and SF3Cz2 are promising hosts for blue and white PHOLEDs.     

Enhanced intrinsic stability of the bulk heterojunction active layer blend of polymer solar cells by varying the polymer side chain pattern

Organic photovoltaics (OPVs) have acquired huge attention over the past years as potential renewable energy sources, adding attractive features such as aesthetics, semi-transparency, flexibility, large area printability, improved low-light performance, and cost-effectiveness to the well-known Si-based photovoltaics. Steady improvements in OPV power conversion efficiencies are continuously reported, notably for bulk heterojunction solar cells based on conjugated polymer:fullerene blends. However, apart from efficiency and cost, the stability of organic solar cell devices is of particular concern. Among the different factors contributing to OPV instability, gradual loss of the optimum phase-separated nanomorphology of the photoactive layer blend is a critical parameter. In this paper, we present the results of ‘shelf-life’ accelerated lifetime tests performed for devices containing a range of functionalized poly(3-alkylthiophene) (P3AT) donor polymers upon prolonged thermal stress. By the incorporation of functional moieties on the side chains of P3HT-based copolymers, a remarkable improvement of the intrinsic stability of the active layer blend morphology is accomplished, even for fairly low built-in ratios (5–15%) and without crosslinking to covalently anchor the polymer and/or fullerene molecules. Moreover, these alterations do not influence the initial power conversion efficiencies to a large extent. As such, the presented approach can be regarded as an attractive paradigm for OPV active layer stability.     

Synthesis,electrochemical and electrochromic properties of novel 2,4,6-Tri(pyridine-4-yl)pyridilium derivatives

Four star-shaped like fused heterocyclic compounds multi-electrochromic materials 2,4,6-Tri(pyridine-4-yl)pyridilium derivatives (TPPDs) were successfully synthesized and characterized by NMR, Solid IR spectra, APCI-MS, and UV–vis spectroscopy. The electrochemical properties, electrochromic behavior, electro-optical properties, and electrochromic mechanism were investigated by thermogravimetric analysis, cyclic voltammetry and UV–vis absorption spectra. Electrochromic devices based on these compounds were fabricated with an active area of 3 cm × 4 cm and their electrochromic performances were further studied. It was found the ECDs presented a stable as well as multicolor electrochromic change from colorless to blue, then violet-blue and finally black-blue between 0 V and +4.0 V. In addition, the prepared electrochromic materials had high coloration efficiency, low switching time, and nice redox stability. This type of multi-electrochromic materials would thus be promising candidates for applications in electrochromic devices.     

A novel Temperature–Humidity–Time defrosting control method based on a frosting map for air-source heat pumps

To improve the defrosting accuracy and the energy efficiency of the air-source heat pump (ASHP) under frosting and defrosting conditions, a novel Temperature–Humidity–Time (T–H–T) defrosting control method, based on a frosting map for the ASHP unit, is proposed in this paper. A field test was conducted for two heating seasons, to verify the feasibility and applicability of the T–H–T method. The advantages of the T–H–T method, compared to the conventional Temperature–Time (T–T) defrosting control method, are presented. In total, eight cases are shown in this paper. Cases 1 to 4 were chosen to reveal the T–H–T performance under different frosting conditions. It was found that no matter what kind of frosting conditions, defrosting was always initiated in a similar situation: ∼90% of the outdoor coil surface was covered by frost; the temperature difference between the compressor suction and discharge increased by ∼20%; and the heating capacity decreased by ∼30%. These results indicate that the T–H–T method can make an accurate decision under different frosting conditions. Cases 5a, 5b and Cases 6a, 6b were two groups of cases to compare the advantages of the T–H–T method against the conventional T–T method. Cases 5a and 5b were chosen for the non-frosting condition. It was found that the T–T method initiated the defrosting operation 31 times within 24 h. However, none of the defrosting operations was conducted for the T–H–T method. Cases 6a and 6b were chosen to compare these two methods under consecutive and variable frosting conditions. For the T–T method, 63% of the defrosting processes were found to be executed under conditions where defrosting was not necessary. However, for the T–H–T method, all the defrosting controls were found to be accurate and reasonable. These results indicated that the novel T–H–T method is suitable for the defrosting control of the ASHP, and has a more competitive performance than the conventional T–T method.     

Addressable growth of oriented organic semiconductor ultra-thin films on hydrophobic surface by direct dip-coating

Oriented organic field-effect transistor (OFET) stripe arrays on hydrophobic substrates were fabricated by fast dip-coating technique. The addressable growth was achieved by decreasing surface energy of the channel areas with respect to the electrodes via hydrophobic treatment. The higher surface energy of the electrodes allows solution to adhere and then organic semiconductors nucleate and bridge the channels after evaporation of the solvent. Area-selective behaviour can be controlled by adjusting surface property of transistor channel, geometry features of the gold electrodes, pulling speed and evaporation atmosphere. The mechanism behind is the competition between receding of the solution and evaporating of the solvent that generate the organic semiconductor films on the substrate. The patterned bottom-contact transistor arrays exhibit carrier mobility of 2.0 × 10⁻³ cm² V⁻¹ s⁻¹, while no field-effect characteristics can be detected for bottom-contact arrays without hydrophobic treatment. Such reliable, fast and solution-based patterned OFET arrays are highly desirable for large-scale and low-cost production.     

A numerical database for ultrasonic defect characterisation using array data: Robustness and accuracy

Elastodynamic scattering matrices are known to contain geometrical information about a given scatterer, such as its size and shape. Here, the extent to which this scattered information can be retrieved using an ultrasonic array and used to characterise defects for Non-Destructive Evaluation is explored. Experimentally measured defect scattering matrices are compared to a database of possible scatterers and the nearest neighbour used to characterise the defect's geometry in terms of crack length and orientation. As an example, a database of scattering matrices for small (lengths 0.2–2.0 mm) cracks at a range of frequencies (2–20 MHz) is formed. The short range similarity (i.e. that between close neighbours) and the long range similarity (i.e. uniqueness) are used to understand the uncertainties inherent in this approach. In addition, the effect of spatially coherent noise, such as grain scattering in a polycrystalline metal, on the scattered information content is quantified. It is shown that as the noise level or frequency increases, so the information retrievable from a given crack is reduced, setting bounds on the accuracy of characterisation possible from a given ultrasonic dataset.     

Laser induced formation of copper species over TiO2 nanotubes towards enhanced water splitting performance

We proposed fast and scalable route where the ordered TiO₂ nanotubes coated with thin copper layers were annealed by the laser beam of 355 nm wavelength at different fluencies in the range of 15–120 mJ/cm². As a result, copper species are integrated with the titania substrate and the formed material exhibits unique optical absorption bands in the visible range. Moreover, X-ray photoelectron spectroscopy analysis reveals the formation of Cu₂O while the 4⁺ oxidation state of titanium is preserved. According to the electrochemical results, the material treated by laser exhibits outstanding photoelectrochemical activity comparing to the pristine titania or the one only covered by the thin copper film. In particular, when the fluence of 60 mJ/cm² was used for the modification of the titania decorated with Cu film, the current density recorded in KOH electrolyte reaches nearly 4.5 mA/cm² at +2.0 V vs. Ag/AgCl/0.1 M KCl upon visible light.