硼酸三甲酯流化催化精馏工艺的研究

以负载氯化锂强酸性离子交换树脂为催化剂,对硼酸三甲酯流化催化精馏工艺进行了研究。结果表明:催化精馏塔1适宜的操作条件为:回流比为4、进料高度为0.6 m、进料速率为4.48 m L/min、全塔压降为200 mm水柱、塔釜1的反应体积为200 m L;催化精馏塔2适宜的回流比为10。催化精馏塔1中硼酸三甲酯的收率为82.4%,精馏塔2中硼酸三甲酯的收率为97.8%。     

[Poly(styryl)phenanthroline]palladium as heterogeneous catalyst for heck arylation using iodobenzene

The effects of different bases on Heck arylation catalyzed by the polymeric catalyst

have been studied. The yield of product and the lifetime of the catalyst are influenced by the nature of the base used. The leaching of palladium from the polymeric catalyst is caused mainly by the competitive complexation of the ligands existing in the reaction media towards the metal. When tributylamine is replaced by DMF-H₂O-NaOAc, the catalyst can be easily recovered and reused, the yields are higher and the products are found to be more pure. For the reaction of acrylamide with iodobenzene, even after ten consecutive runs the recovered catalyst still has high catalytic activity. In the DMF-H₂O-NaOAc system, the catalyst can also tolerate the presence of a variety of functional groups; acrylamide could be introduced to react with substituted iodobenzenes in good yields.     

Plasma-polymerized metal phthalocyanine films: Preparation,properties and morphology

Thin polymeric nickel phthalocyanine (NiPc) and lead phthalocyanine (PbPc) films were prepared by the plasma-polymerization method. The phthalocyanine ring structure was largely undisturbed by this process. Lead phthalocyanine deposited in the high RF flux density regime produced some lead particles incorporated in the film, which were confirmed by electron diffraction patterns. In general the crystallite size of plasma-polymerized phthalocyanine films was much smaller than that for the chemical vapor deposited (CVD) phthalocyanine films. Plasma-polymerized phthalocyanine films deposited on interdigitated electrodes were evaluated as sensors for oxidizing and reducing gases. They showed fast response and excellent sensitivity to ppm level concentrations of NO₂ in air.     

纹理图像的局部区域提取方法

纹理分析是图像处理与识别的重点和难点之一。综合运用数字图像处理和计算机视觉技术,应用VC++开发环境,以竹材横截面细胞壁晶区为具体研究对象,通过应用各种结构微型窗口,比较近距离点之间像素值的方法将图像进行分割,再运用数学形态学的方法对图像进行增强处理,将人们感兴趣的区域孤立出来,以方便对所需区域进行形状描述、收集信息和求取图像特征参数。所开发的程序可以取得较好的纹理分析效果,其界面友好、使用方便。     

Stability and growth of silicalite seeds: an observation of initial breeding

The stability of silicalite seeds in solution is shown to depend on the cations in the liquid solution and the way in which seeds have been treated. Calcined seeds dissolve in caustic solutions, whereas uncalcined seeds are stable in some solutions. Na⁺ solutions appear to have greater solvating properties for silicalite than do NH₄⁺ solutions. Fresh seeds are shown to grow in a silicalite synthesis mixture. Dried or calcined seeds grow, but also produce a new population of nuclei that results from an initial breeding mechanism.     

Java多文档界面类库的设计和实现

随着Java编程语言的发展,基于Java的多文档界面桌面应用程序日益普及。简要总结了JFC中的多文档界面机制,包括桌面窗格、内部帧和桌面管理器,说明了JFC中的多文档界面与Windows环境下多文档界面的差别,最后介绍了利用卡片布局管理器设计和实现传统多文档界面类库的思想。     

MAPP/EAA处理对聚丙烯/小麦秸秆粉复合材料性能的影响

研究了马来酸酐接枝聚丙烯（MAPP）、乙烯丙烯酸共聚物（EAA）处理对聚丙烯（PP） /小麦秸秆粉（WSP）复合材料性能的影响。结果表明,随着体系中MAPP质量份数的增加,PP/WSP的拉伸强度和弯曲强度均逐渐增大,但冲击强度却先增加后减小,复合材料达到塑化峰的时间逐渐延长;使用EAA后,无论体系中是否已经使用了MAPP,PP/WSP的拉伸、弯曲和冲击强度均可得以提高,特别对于未使用MAPP的体系,效果更加明显,可分别提高65.04 %、45.42 %和6.75 %,储能模量增加,表面疏水性增强,平衡扭矩从13.9 N·m降至11.8 N·m,吸水尺寸变化率及吸水率下降,吸水平衡时间缩短;使用EAA可改善PP/WSP中WSP与PP间的界面结合,改善PP/WSP力学性能、热稳定性能、表面疏水性能、尺寸稳定性能和加工性能,降低其吸水率。     

不同紫外波长对热塑性淀粉塑料表面的光交联改性研究

为有效提高热塑性淀粉塑料（TPS）的力学和耐水性能,本文提出用不同波长的紫外光照的方法来实现TPS表面的光交联改性。将光引发剂2,4,6?三甲基苯甲酰基二苯基氧化膦（TPO）的乙醇溶液涂覆于TPS表面后进行紫外光照射,研究了不同紫外光波长（254、308、365 nm）对TPS交联度、力学性能、动态力学性能、耐水性和吸湿性的影响。结果表明,与254 nm和365 nm紫外光照后的样品相比,308 nm光照后TPS样品的拉伸、弯曲和冲击强度最大,分别为4.1 MPa,2.7 MPa和96.8 kJ/m²;TPS中淀粉富集区的玻璃化转变温度（T_α）、甘油富集区的玻璃化转变温度（T_β）分别达最高为-37.48 ℃和50.32 ℃,表面接触角最大为75 °,吸水性能也得到显著改善,交联度结果证实此时形成了最佳的交联结构。