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排序方式: 共有169条查询结果,搜索用时 15 毫秒
21.
《International Journal of Hydrogen Energy》2019,44(39):21865-21872
ZnO/CdS photoanode with an excellent photoelectrochemical (PEC) performance for water splitting to produce hydrogen, but its practical application is seriously hindered owing to the photocorrosion induced by photoholes on the surface of CdS. Herein, a 3D cross-linked heterostructure ZnO/CdS/BiOI nanorod arrays (NRAs) has been prepared by a simple solvothermal strategy. Under visible light illumination (λ > 420 nm), the ZnO/CdS/BiOI NRAs photoanode shows an excellent PEC activity and generates a photocurrent density of 9.12 mA cm−2 at 1.1 V vs. RHE, which is 1.8 times higher than that of the ZnO/CdS NRAs photoanode in the alkaline electrolyte. Furthermore, the photoanode achieves a high photo conversion efficiency of 3.49% and a long-time stability over 6000 s. It is proposed that the BiOI nanosheets not only serve as protecting layer to restrain the photocorrosion of CdS, but also facilitate the charge separation in CdS by the virtue of the p-n junction formed between CdS and BiOI. 相似文献
22.
微波和超声波辅助提取穿心莲内酯 总被引:1,自引:1,他引:1
用正交法对微波和超声波辅助提取穿心莲内酯的工艺条件进行优化。微波辅助法提取穿心莲内酯的最佳工艺条件为温度40℃、提取溶剂为体积分数75%的乙醇、提取时间8 min;超声波辅助法提取穿心莲内酯的最佳工艺条件是提取溶剂为体积分数75%的乙醇,超声效率40%、超声时间50 min。微波提取法的平均回收率为99.9%,RSD为0.31%;超声波提取法的平均回收率为100.5%,RSD为0.21%。与超声波提取法相比,微波提取法提取时间较短,提取得率较高。 相似文献
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Computer modeling and the microcalorimetry method were employed to investigate the adsorption of xanthate, dithiophosphate (DTP) and dithiocarbamate (DTC) on the galena and pyrite surfaces. The calculated results show that the pyrite surface undergoes greater relaxation than galena, while galena has a more electronegative surface than pyrite. The pyrite Fe atom is more active than the galena Pb atom. The simulations of adsorption show that the adsorbates coordinate mainly to the surfaces through interaction between their S atoms with the surface Pb or Fe atoms. The analysis of the density of states (DOSs) suggests that the adsorption of xanthate on the pyrite surface is stronger than that on the galena surface, while that of DTP and DTC are stronger on the galena surface than on the pyrite surface.The heat of adsorption and kinetics parameters of DTC and DTP at the galena and pyrite surfaces differ greatly, suggesting that DTC and DTP exhibit good selectivity in the separation of pyrite and galena, while these two parameters for xanthate at the two minerals differ little, indicating the poor selectivity of xanthate. 相似文献
26.
《Journal of Industrial and Engineering Chemistry》2014,20(2):605-609
Adsorption of water on mineral surfaces was studied using density functional theory and microcalorimetry technique. The calculation results show that galena and molybdenite are hydrophobic, while pyrite and sphalerite is hydrophilic. Thermokinetic analysis shows that the heat of adsorption is in decreasing order of pyrite, sphalerite, galena and molybdenite, which is in good agreement with the calculation results. The adsorption kinetics parameters of hydrophobic galena and molybdenite surfaces are close, while those of hydrophilic pyrite and sphalerite surfaces are very different. The adsorption rate of water on the sphalerite surface is larger than that of water on the pyrite surface. 相似文献
27.
以葡萄糖和天然海泡石为原材料,利用水热碳化法制备了新型葡萄糖碳化物/海泡石复合材料,冷冻真空干燥法干燥样品。利用X射线衍射分析(XRD)、红外吸收光谱(IR)、扫描电镜(SEM)、比表面积(BET)对样品进行了表征,选择亚甲基蓝作为吸附质考察其吸附性能,并通过单因素和响应面法优化了材料制备的工艺。实验结果表明,复合材料制备最优工艺条件为:葡萄糖与海泡石质量比为1.49∶1.0、碳化时间为7.33 h(440 min);碳化温度为175℃,对亚甲基蓝的最优吸附量为45.22 mg/g;各因素对复合材料吸附亚甲基蓝性能的影响顺序为:碳化时间>碳化温度>葡萄糖与海泡石质量比。 相似文献
28.
《Materials Research Bulletin》2013,48(4):1420-1427
Hierarchical β-Bi2O3/Bi2MoO6 heterostructured flower-like microspheres assembled from nanoplates with different β-Bi2O3 loadings (0–26.5 mol%) were synthesized through a one-step template-free solvothermal route. Under visible-light illumination (λ > 420 nm), over 99% of rhodamine B was degraded within 90 min on the 21.9 mol% of β-Bi2O3 loading Bi2O3/Bi2MoO6 microspheres. The remarkable enhancement of photocatalytic activity of the hierarchical Bi2O3/Bi2MoO6 micro/nanostructures can be attributed to the effective separation of the photoinduced charge carriers at the interfaces and in the semiconductors. The electrons (e−) are the main active species in aqueous solution under visible-light irradiation. The Bi2O3/Bi2MoO6 also displays visible-light photocatalytic activity for the destruction of E. coli. In addition, the β-Bi2O3 in the hierarchical Bi2O3/Bi2MoO6 microspheres is very stable and the composite can be easily recycled by a simple filtration step, thus the second pollution can be effectively avoided. A possible photocatalytic mechanism was proposed based on the experimental results. 相似文献
29.
《Materials Letters》2005,59(14-15):1889-1892
Eutectic alloy Sn–9Zn is regarded as one of the potential substitutes for Pb-containing solders, although it has some drawbacks yet to overcome. One of the problems involved is drastic viscosity increase of rosin-based flux during soldering or storage. In the present work we investigated the role of ZnO in the viscosity transition of rosin. The results show that the viscosity transition is directly caused by the presence of ZnO in molten rosin and, at a certain temperature, there exists a critical ZnO concentration for its occurrence. The critical ZnO concentration increases with temperature. A graph is presented to show the conditions for the viscosity transition, in a ZnO concentration–temperature space. The transition is found to be reversible when shifting temperature or ZnO concentration across the boundary and to assume the features of a thermally activated phase transformation. 相似文献
30.
Ammonium-iron(II) phosphate monohydrate was synthesized via solid-state reaction at low temperature and characterized by X-ray diffraction, infrared spectroscopy, chemical analysis and scanning electron microscope. Thermochemical study was performed by an isoperibol solution calorimeter at 298.15 K. The results show that the obtained product is NH4FePO4·H2O with plate shape of nanometer measure. According to Hess's law, a new thermochemical cycle was designed, and the standard enthalpy of formation of the titled complex at 298.15 K is . 相似文献