Enzymatic sensing with laccase-functionalized textile organic biosensors

Herein we present a textile wearable electrochemical transistor by functionalizing a single cotton yarn with semiconducting polymer. The organic electrochemical transistor (OECT), which is low cost and completely integrated e-textile, is decorated by adsorption of the fungal laccase POXA1b, and is used as biosensor for the direct detection of Tyrosine (L-Tyr) without the use of electron mediators. The detection of Tyr in real-case scenario such as human physiological fluids would own a paramount importance in noninvasive analysis of the patient's condition, monitoring and preventing several pathologies. To assess the reaction progression, the redox process is studied by UV–visible absorption with test reference molecule of 2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonate) (ABTS): the results confirmed that the oxidation reaction is driven by the presence of laccase enzyme and direct electron transfer occurred. The modulation of the signal response and the kinetic of the signal is used to detect Tyr molecule in aqueous solution and the role of the enzyme adsorption on the textile is analyzed. A kinetic analysis of the characteristic modulation times of the sensing curves, confirm the sensing properties of the textile device. The textile-based biosensor is demonstrated to monitor human health biomarkers through wearable applications in a non-invasive way, finding potential application in sport, healthcare and working safety.     

Joint power control and user scheduling for backbone-assisted industrial wireless networks with successive interference cancellation

In a backbone-assisted industrial wireless network (BAIWN), the technology of successive interference cancellation (SIC) based non-orthogonal multiple access (NOMA) provides potential solutions for improving the delay performance. Previous work emphasizes minimizing the transmission delay by user scheduling without considering power control. However, power control is beneficial for SIC-based NOMA to exploit the power domain and manage co-channel interference to simultaneously serve multiple user nodes with the high spectral and time resource utilization characteristics. In this paper, we consider joint power control and user scheduling to study the scheduling time minimization problem (STMP) with given traffic demands in BAIWNs. Specifically, STMP is formulated as an integer programming problem, which is NP-hard. To tackle the NP-hard problem, we propose a conflict graph-based greedy algorithm, to obtain a sub-optimal solution with low complexity. As a good feature, the decisions of power control and user scheduling can be made by the proposed algorithm only according to the channel state information and traffic demands. The experimental results show that compared with the other methods, the proposed method effectively improves the delay performance regardless of the channel states or the network scales.

     

A study of drilling performances with minimum quantity of lubricant using fuzzy logic rules

Nowadays the increasing interest to perform machining operations is in dry/near-dry environments. The reason includes health and safety of operator, cost, ease of chip recyclability, etc. However one important process, which is difficult to perform in dry, is drilling. Without coolant, drilling leads to excessive thermal distortion and poor tool life. In order to tackle these conflicting requirements, the essentiality of study on machining performances with minimum quantity lubricant (MQL) becomes important.Fuzzy logic rules, which are derived based on fuzzy set theory, are used to develop fuzzy rule based model (FRBM). The performance of FRBM depends on two different aspects: structures of fuzzy rules and the associated fuzzy sets (membership function distributions, MFDs). The aim of this study is to investigate the performances of FRBMs based on Mamdani and TSK-types of fuzzy logic rules with different shapes of MFDs for prediction and performance analysis of machining with MQL in drilling of aluminum alloy. A comparison of the model predictions with experimental results and those published in the literature shows that FRBM with TSK-type fuzzy rules describes excellent trade-off with experimental measurements.     

Thiol-Functionalized Covalent Organic Frameworks as Thermal History Indictor for Temperature and Time History Monitoring

Various products, including foods and pharmaceuticals, are sensitive to temperature fluctuations. Thus, temperature monitoring during production, transportation, and storage is critical. Facile indicators are required to monitor temperature conditions via color changes in real time. This study aimed to prepare and apply thiol-functionalized covalent organic frameworks (COFs) as a novel indicator for monitoring thermal history and temperature abuse. The COFs underwent obvious color changes from bright yellow to purple after exposure to different temperatures for varying durations. The reaction kinetics are analyzed under isothermal conditions, which reveal that the order of reaction rates is k_−20°C < k_4°C < k_20°C < k_35°C < k_55°C. The activation energy (E_a) of the COFs is calculated using the Arrhenius equation as 50.71 kJ moL⁻¹. The COFs are capable of sensitive color changes and offer a broad temperature tracking range, thereby demonstrating their application potential for the monitoring of temperature and time exposure history during production, transportation, and storage. This excellent performance thermal history indicator also shows promise for expanding the application field of COFs.     

Iron Distribution in Heated Beef and Chicken Muscles

Distribution of iron in six fractions (water-soluble, water-insoluble, diffusate, hematin, total heme, and ferritin) of beef and chicken muscles hcatcd to 55, 70, 85, and 100°C was determined. Iron content decreased in water-soluble fractions and increased in water-insoluble fractions as temperature increased from 27°C to 100°C. Heme iron decreased more from 55°C to 85°C than from 27°C to 55°C or 85°C to 100°C. The increase in diffusate iron appeared to be less than the decrease in heme iron at each heating temperature. As temperature increased from 27°C to 100°C, hematin iron content increased and extractable ferritin iron content decreased. These findings may help explain rapid development of oxidative rancidity in cooked meat.     

A method for the measurement of the photovoltaic cell or module current-voltage characteristic

For the measurement of the current-voltage characteristic of a photovoltaic (PV) cell or module, an experimental “self testing” method is proposed which uses as “load” one or more PV cells (modules), appropriately connected to the test cell and subjected to a variable irradiance. Depending on the irradiance values towards the test cell (module), the “load” cell will behave as a true load, a reverse voltage generator or a reverse current generator. Therefore, it is possible to obtain, by an automatic data acquisition system, the points of the test cell I = I(U) characteristic in quadrants I, II and IV. On this basis, a simple three quadrant I = I(U) curve tracer, based on a digital or analog storage oscilloscope, is produced. Laboratory and field tests on cells and modules have shown the easy feasibility of implementatitg this method.     

Stability of polymer light-emitting diodes

In this paper, we report on the lifetime of polymer LEDs fabricated at Philips Research. For single-layer LEDS, we find that the operational lifetime in nitrogen gas is limited by the stability of the indium-tin-oxide (ITO) anode. By using a polymeric capping layer for the ITO, we obtain more stable devices. In air, the lifetime is limited by black spot formation. Small pinholes in the cathode layer are the origins of the black spots. Water or oxygen may diffuse through these pinholes and react with the cathode, causing degradation. By encapsulating the devices we can prevent black spot formation. Our present 8 cm² devices have lifetimes of many thousands of hours at daylight visibility under ambient conditions.     

新陈玉米的拉曼光谱快速判别研究

本文采用拉曼光谱结合判别分析方法对新陈玉米进行了判别研究。在河南省内收集郑单958新陈玉米样品共75份,粉碎过筛后置于样品袋中,使用光纤直接采集他们的拉曼光谱。对原始光谱进行多项式平滑滤波、基线校正及一介导数处理后,首先运用主成分马氏距离判别分析方法建立了判别模型,主成分数为9,光谱建模范围为914~1369 cm-1时模型结果最优,此时建模集总正确判别率为92.7%,验证集总正确判别率为90%。然后运用偏最小二乘判别分析方法建立了相应的识别模型,当建模因子数为7,采用全谱建模时结果最优,此时建模集样品正确判别率为100%,验证集样品正确判别率为95%。偏最小二乘判别分析方法正确识别率较高,结果表明拉曼光谱可以应用于玉米新陈度的快速识别,在粮食储藏品质评价中具有极大的应用潜力。     

Heat transfer from a spinning disk during semi-confined axial impingement from a rotating nozzle

Conjugate heat transfer from a uniformly heated spinning solid disk of finite thickness and radius during a semi-confined liquid jet impingement from a rotating nozzle is studied. The model covers the entire fluid region including the impinging jet on a flat circular disk and flow spreading out downstream under the spinning confinement plate and free surface flow after exposure to the ambient gaseous medium. The model examines how the heat transfer is affected by adding a secondary rotational flow under semi-confined jet impingement. The solution is made under steady state and laminar conditions. The study considered various plate materials such as aluminum, copper, silver, constantan and silicon. Ammonia, water, flouroinert FC-77 and MIL-7808 oil were used as working fluids. The range of parameters covered included Reynolds number (220–900), Ekman number (7.08 × 10^?5–∞), nozzle-to-target spacing (β = 0.25–1.0), disk thicknesses to nozzle diameter ratio (b/d_n = 0.25–1.67), Prandtl number (1.29–124.44) and solid to fluid thermal conductivity ratio (36.91–2222). It was found that a higher Reynolds number increased local heat transfer coefficient reducing the interface temperature difference over the entire disk surface. The rotational rate also increased local heat transfer coefficient under most conditions. An engineering correlation relating the Nusselt number with other dimensionless parameters was developed for the prediction of the system performance.     

Inkjet and microcontact printing of functional materials on foil for the fabrication of pixel-like capacitive vapor microsensors

The work presented demonstrates the utilization of micro-contact printing of self-assembled monolayers (SAMs) of gold nanoparticles (NPs) to pattern the porous thin metallic film composing the top electrode of an ultra-fast capacitive relative humidity sensor based on miniaturized parallel-plates electrodes. The rest of the device, which occupies an area of only 0.0314 mm², is fabricated by inkjet printing stacked individual drops of functional materials, namely gold NPs for the bottom electrode and a polymeric humidity sensing layer, on a polymeric foil. Compared to other printing methods, the use of microcontact printing to pattern the top electrode enables the additive transfer of a solvent-free metallic layer that does not interact chemically with the sensing layer, permitting the thinning of the latter without risk of short-circuits between electrodes, and broadening the range of usable sensing materials for detection of other gases. Thinning the sensing layer yields to ultra-fast response devices with high values of capacitance and sensitivity per surface area. The fabrication process is compatible with low heat-resistant polymeric substrates and scalable to large-area and large-scale fabrication, foreseeing the development of low-cost vapor sensing sheets with high space–time resolution, where every sensor would correspond to a pixel of a large array.