二价铁离子对零价铁还原硝基苯的影响

为了解地下水环境中铁离子对零价铁(zero valention)还原作用的影响,采用批次实验,研究不同质量浓度二价铁离子对ZVI还原硝基苯的影响,利用HPLC和GC-MS作为分析工具,观测反应过程中硝基苯的质量浓度,同时跟踪溶液中Fe2+、pH、ORP的变化.结果表明,有无Fe2+存在,硝基苯均可被ZVI还原为苯胺,Fe2+没有改变还原产物;溶液中投加Fe2+后,ZVI还原硝基苯的反应速率明显加快,溶液中Fe2+对于还原反应起促进作用;溶液中Fe2+对ZVI体系pH起缓冲作用,含有Fe2+的ZVI体系ORP下降明显.反应动力学分析表明,硝基苯的还原反应符合假一级动力学模型,表观速率常数kobs值随Fe2+质量浓度的升高而增加,Fe2+离子的存在有助于ZVI对硝基苯的还原.     

广西老堡铅锌矿褶皱形成机制及其控矿规律

老堡铅锌矿床主要赋存在陡山沱组白云岩或老堡组硅质岩中,顺层产出,受地层与褶皱的双重控制。矿区主干褶皱为一复式向斜,由2个次级向斜和1个次级背斜组成。从构造几何学、运动学角度,运用现代测试技术,对矿区的小构造、显微构造和组构进行构造分析后揭示,老堡褶皱构造的形成机制是以弯滑作用为主、兼具弯流作用的纵弯褶皱作用的产物。铅锌矿体主要赋存在褶皱的转折端虚脱部位及两翼滑移量较大的层间滑动破碎带中。     

应用Markov理论定量描述土壤剖面中菲的垂向运移分布特征

马尔可夫(Markov)链理论是用来描述随时间(空间)变化的一个离散状态序列的状态转移特性的,本文将其引入来研究土壤剖面多环芳烃有机污染物的垂向变化规律,建立了基于空间离散化的马尔可夫(Markov)链理论数学模型及垂向归趋极限.研究结果表明,基于空间离散化的马尔可夫(Markov)链理论数学模型及垂向归趋极限能够很好地模拟区域土壤剖面多环芳烃(菲)的垂向变化特征,并有迁移规律的识别功能.     

住宅辐射-送风末端冷负荷分担率研究——从热舒适及室内空气品质角度

以住宅建筑为研究对象,针对低、中、高负荷3种不同住宅负荷工况,对不同冷负荷条件下不同负荷分担率下的室内热环境进行了数值模拟,分别分析比较不同冷负荷分担率匹配时室内热舒适性水平及室内空气品质情况,从舒适和健康的角度,分析适宜的冷负荷分担率范围。研究结果表明辐射供冷末端承担的显热负荷分担率ωc〈0．7时,可将工作区人体热舒适性指标控制在舒适性标准允许范围内。从避免局部不舒适度方面讲,ωc宜取0．4～1。从室内空气品质角度讲,定风量模式低中负荷工况,ωc宜取0．5～0．9,高负荷工况,叫。宜取0．35～0．6;变风量模式,ωc值越小,室内空气品质越好。     

Bi2O3 vaporization from ZnO-based varistors

Bi₂O₃-doped ZnO ceramic varistors are usually sintered at temperatures near to 1200 °C in the presence of a Bi-rich liquid phase, which is partially vaporized during the sintering process. Volatilization of bismuth oxide depends on the total surface area in direct contact to the reaction atmosphere and this in turn is related to the area/volume ratio of the ceramic compact. This loss of Bi₂O₃ has a significant role on the development of the varistor microstructure and more specifically ZnO grain growth, which is strongly enhanced by the presence of the liquid phase, should be particularly affected. In the present paper, X-ray fluorescence analysis is performed to describe the Bi₂O₃ vaporization profile as a function of distance to the outer surface, taking into account its influence on microstructural evolution.     

An unusual 3D three-fold parallel interpenetrating network self-assembled from the grid-containing 2D layer motifs

The new complex {[Cu(dde)(bpe)] · H₂O}_n (1) (dde = 4,4′-dicarboxydiphenyl ether, bpe = 1,2-bis(4-pyridyl)ethene) has been synthesized and characterized. It exhibits a novel (2D → 3D) three-fold parallel interpenetrating architecture that is obtained for the first time from the self-assembly of grid-containing 2D (4, 4) layer motifs. The fluorescent property of 1 is discussed.     

Aromatization of n-hexane on Mo2C catalysts

The deposition-precipitation method was used to prepare gold catalysts based on different supports. Their catalytic activities for combustion of carbon monoxide (CO) and formaldehyde (HCHO) were investigated. All these catalysts showed good activity for the two reactions and the Au/CeO₂-a catalyst exhibited the highest activity for the two reactions. Furthermore, catalysts derived from the as-precipitate hydroxides exhibited higher activity than that from corresponding oxide supports. The BET, XRD, TEM and XPS were carried out. The results indicated that the gold dispersed more homogeneous on the as-precipitate hydroxide supports than that on the corresponding oxide supports.     

Decreasing trends in total suspended solids and cumulative effects of nonpoint source projects in the Cuyahoga River Watershed,OH

Using the US EPA’s Grants Reporting and Tracking System (GRTS), we test if completion of best management practices (BMPs) through the Clean Water Act Section (4)319 National Nonpoint Source Program was associated with a decreasing trend in total suspended solids (TSS) load (metric tons/year). The study area chosen had 21 completed projects in the Cuyahoga River watershed in northeastern Ohio from 2000 to 2018. The 4319 projects ranged from dam removal, floodplain/wetland restoration to stormwater projects. There was an overall decreasing trend in TSS loads. We identified three phases of project implementation and completion, where phase 1 had ongoing projects, but none completed (2000–2004). The steepest decrease in loads, identified as phase 2 (2005–2011), was associated with completion of low-head dam modification and removal projects on the mainstem of the Cuyahoga River. A likely decreasing trend was associated with projects completed in the tributaries, such as natural channel design restoration and stormwater green infrastructure (phase 3). Pairing sediment reduction estimates from projects with the river’s flow normalized TSS loading trend, we estimated that the 4319 effort may account for a small fraction of the TSS load reduction. Other stream restoration projects (non-4319) have also been done in the Cuyahoga watershed by other organizations. However, trying to compile these other projects is challenging in larger watersheds having multiple municipalities, agencies, and nonprofits doing restoration without better coordinated record keeping and monitoring. While a decreasing trend in a pollutant load is a desirable water quality outcome, determining what contributed to that trend remains difficult.     

The impact of CCT on driving safety in the normal and accident situation: A VR-based experimental study

Correlated color temperature (CCT) of the light source inside the road tunnel plays a crucial role in ensuring driving safety, which is demonstrated by previous studies that CCT influences not only visual effects but also non-visual effects. Although conventional laboratory experiments could simulate the CCT environment inside the tunnel to some extent, they fail to restore driving experience, let alone simulate driving behavior in the accident situation. It has largely remained unclear whether and how CCT would influence visual/non-visual performance of the subjects who are performing driving tasks, especially in the accident situation. Motivated by this gap, a virtual-reality-based framework for assessing the influence of CCT on the visual and non/visual performance in normal driving situation and in accident situation was proposed. In this study, tunnel models under seven different CCTs were created and a rear-end accident was designed in the tunnel. By integrating analog driving equipment, all participants were required to perform virtual driving tasks both in the normal situation and in the accident situation. The non-visual performance (driving fatigue) and the visual performance (reaction time) of the participants were collected and analyzed. Results show that the CCT of light source inside the tunnel was significant on the driving fatigue of the driver who was performing driving task, and it also had a significant impact on the visual performance when the driver was faced with a rear-end accident. Detailed experimental methodology, behavioral explanations underlying these findings, validity of results and practical implications are also discussed in the paper.     

稻草强化生物膜浮床脱除工业尾水中氮素及COD的效果

工业污水处理厂排放的尾水中总氮含量偏高,容易引起地表水体的富营养化。为了提高尾水中总氮的去除效率,通过模拟稳定塘静态和动态试验,对比了不同稻草添加量(0,0.18,0.54 g/L)强化生物膜浮床脱除工业尾水中总氮(TN)的效果。静态试验结果表明:随着稻草量的增加,TN的去除率显著提高;10 d后,添加0(CK)、0.18 g/L(T1)和0.54 g/L(T2)稻草的尾水中,TN去除率分别为18%,40%,93%。动态试验结果显示,水力停留时间(HRT)为 4 d时,CK、T1和T2的平均TN去除率分别为10%,22%,49%,且3种情况下的进出水COD浓度无显著差异。这主要是由于稻草通过缓慢释放碳源为生物膜中异养反硝化细菌提供可利用的有机物。研究成果可为工业尾水深度处理脱氮技术提供参考。