Two novel 3D 3d–4f polymers with triethylenetetraaminehexaacetic acid: Syntheses,structures, and magnetic properties

Two novel 3d–4f polymers [La(H₂O)₄][M₂TTHA(SCN)₂] · H₃O⁺ (M = Ni(1), Cu(2), H₆ TTHA = triethylenetetraaminehexaacetic acid) were synthesized and characterized by X-ray single-crystal diffraction, elemental analysis, IR and magnetic properties. Two complexes show 3D framework, comprising an unusual infinite 1D chain based on heterometallic La₂M₂ rings (M = Ni(1), Cu(2)).     

Organic–inorganic hybrids containing polyimide,organically modified clay and in situ formed polydimethylsiloxane

A series of organic–inorganic hybrid consisting of polyimide (PI) prepared from pyromellitic dianhydride (PMDA) and 4,4′-oxydianiline (ODA), organically modified montmorillonite (OMMT) and polydimethylsiloxane (PDMS) were successfully prepared by in situ sol–gel process. OMMT was prepared by surface treatment of montmorillonite (MMT) with hexadecyltrimethylammonium bromide. X-ray diffraction (XRD) analysis showed that the OMMT layers were exfoliated into the polymer matrix at 2% of OMMT content. The PI–OMMT–PDMS hybrids at 2% of OMMT content were transparent when PDMS content was less than 5%. The PI–OMMT–PDMS hybrid showed better tensile modulus, strength and elongation at break than that of pristine PI due to the reinforcement effect of OMMT and toughening effect of PDMS. The thermal stability of hybrids such as the decomposition temperature and weight residue at 800 °C also increased with the increase of PDMS content as evidenced by thermogravimetric analysis (TGA).     

Preparation of dense β-CaSiO3 ceramic with high mechanical strength and HAp formation ability in simulated body fluid

In present study, dense CaSiO₃ (CS) ceramics have been fabricated through spark plasma sintering (SPS) technique using β-CS powder prepared by chemical precipitation method. The β-CS ceramic sintered at 950 °C has a relative density of about 95% and shows a fine microstructure with an average grain size of 0.6 μm, thus expresses good bending strength of about 294 MPa. The simulated body fluid (SBF) immersion tests show that the dense β-CS ceramic has a high hydroxyapatite (HAp) formation rate on its surface. The HAp layer formed on the CS ceramic surface has a granular structure consisting of silkworm-like HAp grains, and the thickness of HAp and Si-rich layer are 70 and 120 μm, respectively.     

Development of Si3Na/Al composite by pressureless melt infiltration

Pressureless infiltration process to synthesize Si3N4/Al composite was investigated. Al-2%Mg alloy was infiltrated into Si3N4 and Si3N4 containing 10% Al2O3 preforms in the atmosphere of nitrogen. It is possible to infiltrate Al-2%Mg alloy in Si3N4 and Si3N4 containing 10% Al2O3 preforms. The growth of the dense composite of useful thickness was facilitated by the presence of magnesium powder at the interface and by flowing nitrogen. During infiltration Si3N4 reacted with aluminium to form Si and AIN, the growth of composite was found to proceed in two ways, depending on the Al2O3 content in the initial preform. Firstly, preform without Al2O3 content gives rise to AIN, Al3.27Si0.47 and Al type phases after infiltration. Secondly, perform with 10% Al2O3 content gives rise to AIN-Al2O3 solid solution phase （AION）, MgAl2O4, Al and Si type phases. AlON phase was only present in composite, containing 10% Al2O3 in the Si3N4 preforms before infiltration.     

Fabrication of niobium doped Pb（Zr, Ti）O3 fibers by viscous polymer processing

A technique based on viscous polymer processing （VPP） was described, which can produce high ceramic content green fibers. PZT-5 ceramic powders were ball milled to get high dispersibility. The slurry prepared for VPP was a composition of PZT-5 powder, PVA binder and glycerin. High ceramic content PZT-5 fibers were extruded with the slurry. The results show that the ceramic powders have fine mean particle size of 0.54 pan, high specific surface area of 3.55 m^2/g and zeta potential of 8.81 mV after 16 h milling. The fibers sintered at 1 280 ℃ for 4 h have pure perovskite structure and grains of 2-5 μm in size, with little pores or cracks. The ultimate tensile strength of sintered fibers is up to 13.84 MPa compared with 2.88 MPa of green fibers. The remnant polarization （Pr） and coercive field （Ec） of the fibers are 50.65 μC/cm^2 and 2.45 kV/mm, respectively. This fiber can withstand an electric field of 9 kV/mm higher than the ceramic （5 kV/mm）, which shows high directional and compact qualities.     

Effect of temperature and moisture on electrical conductivity in polyaniline/polyurethane (PANI/PU) blends

Miscible blend of conductive polyaniline/polyurethane (PANI/PU) showed preferable electrical property at low percolation threshold compared to immiscible blend of PANI/polystyrene-isoprene-copolymer (PANI/SIS) and carbon black/PU composite (CB/PU). The time dependence of the electrical conductivity was investigated with these samples aged under different humidity and temperatures. The electrical conductivity of PANI/PU (11.5/88.5, v/v) decreased with aging time and the morphology changed with time in the coexistence of high moisture and high temperature. After the aging treatment, the film of the miscible blend was re-dissolved and re-cast. The morphology and electrical conductivity were found to recover to the same state as the original film. In addition, the recovery mechanism of the morphology and the conductivity was also proposed here.     

基于LASeR富媒体客户端的设计与实现

随着移动终端用户量的增长,用户对于体验的要求越来越高。在学术界,富媒体技术以其丰富的用户体验成为了这一问题的解决方案。由我国国情决定,富媒体技术尚处于初步研究阶段,因此本文基于MPEG4 LASER提出了完整的富媒体服务解决方案,设计实现了一个以SVG为场景展现的富媒体客户端,描述了系统分层体系结构,分析了核心功能模块并对该系统进行了测试。实验证明,富媒体客户端可以将各媒体资源有效的整合起来,极大的增强了展现能力和实时交互能力,丰富了用户的体验。     

基于序贯模式挖掘的宏观网络流量异常检测

基于序贯频繁模式挖掘,提出并实现了一种宏观网络流量异常检测的方法。定义了一个新的频繁模式和相对应的异常度概念。对863-917网络安全监测平台提供的全国流量数据进行了实验,得出对应于“橙色八月”的2006年8月上旬流量严重异常的结论。通过与相关的其他传统算法进行对比,如使用绝对流量的算法和简单使用不同小时流量排名的算法,进一步说明序贯频繁模式对网络流量分析的实用性。     

基于直接估计梯度思想的数据降维算法

高维非线性数据的降维处理对于计算机完成高复杂度的数据源分析是非常重要的。从拓扑学角度分析,维数约简的过程是挖掘嵌入在高维数据中的低维线性或非线性的流形。该文在局部嵌入思想的流形学习算法的基础上,提出直接估计梯度值的方法,从而达到局部线性误差逼近最小化,实现高维非线性数据的维数约简,并在Swiss roll曲线上采样测试取得了良好的降维效果。