Modification of polysulfide sealant with polysulfide polythio‐urethane‐urea

With a small amount of isocyanate‐terminated polysulfide (NCO‐PSF‐NCO) as additive, the commercial polysulfide‐based sealant had significant improvement in mechanical properties. The test results showed that 5% of NCO‐PSF‐NCO could help to rise 50% in the tensile strength and 27% in the ultimate elongation of the polysulfide sealant. The adhesive strength to substrates such as steel, epoxy‐coated or polyurethane‐coated surface also increased significantly. Dynamic mechanical thermal analysis and differential scanning calorimetry analysis revealed that formed polysulfide polythio‐urethane‐urea (polysulfide‐urea) contributed to a slight increase in the T_g of the polysulfide sealant. It might be due to the domains of polysulfide‐urea, which had effects of physical crosslinking and chain‐extending on the polysulfide sealant. However, the introduction of polysulfide‐urea structures had no appreciable influence on oil resistance of the polysulfide sealant. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

A comprehensive approach to evaluating watershed models for predicting river flow regimes critical to downstream ecosystem services

Selection of strategies that help reduce riverine inputs requires numerical models that accurately quantify hydrologic processes. While numerous models exist, information on how to evaluate and select the most robust models is limited. Toward this end, we developed a comprehensive approach that helps evaluate watershed models in their ability to simulate flow regimes critical to downstream ecosystem services. We demonstrated the method using the Soil and Water Assessment Tool (SWAT), the Hydrological Simulation Program–FORTRAN (HSPF) model, and Distributed Large Basin Runoff Model (DLBRM) applied to the Maumee River Basin (USA). The approach helped in identifying that each model simulated flows within acceptable ranges. However, each was limited in its ability to simulate flows triggered by extreme weather events, owing to algorithms not being optimized for such events and mismatched physiographic watershed conditions. Ultimately, we found HSPF to best predict river flow, whereas SWAT offered the most flexibility for evaluating agricultural management practices.     

超高交联树脂吸附处理2,4-D含酚废水的研究

采取超高交联树脂NDA-150吸附处理2,4-二氯苯氧乙酸含酚生产废水,取得了良好的效果。通过静态吸附比较和动态吸附-脱附研究,确定了最佳工艺参数。原废水呈深红褐色,总酚质量浓度>16000mg/L,树脂吸附后出水无色透明,总酚质量浓度<0.5mg/L,达到国家排放标准。原废水酸化和高浓脱附液酸化处理,能回收大量的2,4-二氯酚和2,4-二氯苯氧乙酸。该工艺简单,操作方便,是一项具有环境效益和经济效益,值得推广的技术。     

[Zn(BDC)(H2O)2]n: a novel blue luminescent coordination polymer constructed from BDC-bridged 1-D chains via interchain hydrogen bonds (BDC = 1,4-benzenedicarboxylate)

A novel coordination polymer [Zn(BDC)(H₂O)₂]_n 1 (where BDC = 1,4-benzenedicarboxylate), has been synthesized and characterized by X-ray diffraction. 1 crystallizes in the monoclinic space group C2/c, a=15.09(2) Å, b=5.058(7) Å, c=12.196(16) Å, β=103.62(2)°, , Z=4. The most striking feature of 1 is that it consists of a high-dimensional network structure constructed from BDC-bridged 1-D chains via interchain hydrogen bonds. The coordination sphere of the zinc(II) ion is a distorted tetrahedron completed by four oxygen atoms from two water molecules and two BDC ligands. BDC adopts the bis-monodentated (syn–anti) coordination mode linking two adjacent zinc(II) ions. 1 shows strong blue photoluminescence as the result of the fluorescence from the intraligand emission excited state.     

基于平衡采样的轻量级广告点击率预估方法

类似Google AdSense这样的定向广告投放系统在过去十年得到了长足的发展和进步, 在定向广告投放系统中, 机器学习方法在广告点击率预估扮演着重要角色。目前, 广告点击率预估模型中的训练数据逐渐呈指数级增长, 越来越大的训练数据给模型的扩展性带来了极大的不便。很多有用的特征以及复杂的模型受限制于训练集规模而无法加入到模型之中。借鉴类别不平衡问题中的平衡采样策略, 通过多次采样的负样本数据和集成学习, 缩短训练时间, 改善学习准确率。实验证明在采用了平衡采样之后, 点击率预估效果和线上资源消耗都得到了优化。     

Preparation of ultrafine metal particles/polyurethane composites

Summary A new type of coordination polyurethane was prepared by incorporating the transition metal ions into the pyridine containing thermoplastic polyurethane films. Then the metal ions dispersed in the polyurethane matrix were reduced by controlling the exposure of the metal sites to NaBH₄ under mild condition. The reduction of the polyurethane metal complex films resulted in the production of amorphous ultrafine metal powders. The size of these powders was controlled by the content of the metal ions and the polarity of the polymer matrix. A polar polymer backbone and lower metal ion concentration favored to achieve a smaller particle. It was also found that the polymer chains prohibited the excessive aggregation of the metal atoms and have protective effect on the final metal powders.     

基于数据仓库的法院信息决策支持系统的设计

为了加快法院信息化建设,为法院决策层提供决策信息支持,提出了一种基于数据仓库的法院信息决策支持系统的总体框架。在DSS系统设计过程中,采用了OLAP+DM+Web相结合的方式,重点介绍分析了多维数据模型的设计,数据仓库的构建,以及以可视化交互的决策支持,最后通过实例展示决策支持系统的设计分析过程。     

双序渐进式概念格合并算法

针对传统的概念格合并算法仅为单向的纵向或横向合并,提出一种基于概念内涵、外延升降序的双序渐进式合并算法。按照概念的内涵或外延的升序和降序,从两个方向(由上到下和由下到上)同时进行子概念格的纵向或横向合并。算法分析和示例结果表明,该算法不仅在结构上较好地保留了原有信息,而且在效率上也获得了显著的提高。     

超高交联树脂吸附酚类的热力学研究与机理探讨

合成和表征了超高交联树脂AM-1，以大孔吸附树脂Amberlite XAD-4为参照，比较研究了其在水溶液中吸附邻硝基苯酚，对硝基苯酚的吸附行为和热力学性质，测定了不同温度下的平衡吸附量，Langmuir模型和Freundlich模型均能很好拟合。利用Freundlich模型求得△H、△G、△S。研究发现，AM-1型树脂比表面小于XAD-4型树脂的比表面，而吸附能力却更强。这得益于其更多的微孔体积及表面活性基团。     

Two novel 3D 3d–4f polymers with triethylenetetraaminehexaacetic acid: Syntheses,structures, and magnetic properties

Two novel 3d–4f polymers [La(H₂O)₄][M₂TTHA(SCN)₂] · H₃O⁺ (M = Ni(1), Cu(2), H₆ TTHA = triethylenetetraaminehexaacetic acid) were synthesized and characterized by X-ray single-crystal diffraction, elemental analysis, IR and magnetic properties. Two complexes show 3D framework, comprising an unusual infinite 1D chain based on heterometallic La₂M₂ rings (M = Ni(1), Cu(2)).