Fabrication of nano-porous silicon oxide layers by plasma polymerisation methods

We report on the synthesis of nano-porous silicon oxide (SiO₂) layers by gas phase polymerisation reactions of hexamethy disiloxane and oxygen. The SiO₂ layers are deposited onto one or more layers of poly(methylmethacrylate) (PMMA) particles spin coated onto the substrate surface. Subsequent annealing of the films to high temperature (500 °C) leads to the pyrolysis of the polymeric particles resulting in a 3D nanoporosity in the film. X-ray Photoelectron (XPS) and Fourier Transform Infra Red Spectroscopy (FTIR) show an SiO₂-like surface chemistry and virtually complete removal of the organic components. These materials offer a very high surface area-to-volume ratio suitable for sensing applications.     

水动力学数学模型并行计算技术研究及实现

基于MPI(Message Passing Interface)消息传递实现了黄河二维水动力学数学模型的并行编程。以数据的分布存储作为区域划分的依据,实现了计算量的负载平衡;在全局网格和局部区域之间建立映射关系,并且在临界单元、进出口单元、共用节点等通过规约等进行特殊处理,一方面尽可能的减少通讯量,另一方面也避免消息的阻塞。采用曙光4000A系统的8个CPU进行计算的加速比达0.8,多CPU并行计算极大的提高了计算任务的容量,使得无法在单机上完成的巨量计算成为可能。     

后热处理对新型马氏体耐热钢焊缝性能的影响

针对电力施工过程中对具有冷裂倾向的马氏体型耐热钢焊后后热处理时机选择与标准存在差异，即是否必要在冷却至100-120℃恒温一段时间后再进行后热处理的问题，安排了一系列的试验对后热处理的最佳时机予以讨论，对热处理后的焊缝组织进行力学性能试验和金相分析，对冲击后的试样进行了断口分析。试验证明，后热处理时机的不同对马氏体耐热钢焊缝冲击韧度有比较大的影响，马氏体耐热钢的后热处理应在马氏体转变完全后开始较为合适。     

Negative effect of [bmim][PF6] on the catalytic activity of alcohol dehydrogenase: mechanism and prevention

BACKGROUND: [bmim][PF₆] is a hydrophobic ionic liquid which could be considered as an environmentally friendly solvent for biocatalysis. In pure [bmim][PF₆], however, alcohol dehydrogenase from yeast (YADH) has no catalytic activity. The aim of the present work was (1) to quantitatively study the negative effect of [bmim][PF₆] on the catalytic activity of YADH and the related mechanism and (2) to made an attempt to lessen the negative effect of [bmim][PF₆] on YADH by microemulsifying [bmim][PF₆]. RESULTS: The activity of YADH in the homogeneous solution formed by H₂O, CH₃CH₂OH and [bmim][PF₆] decreased rapidly with the increase of the molar fraction of [bmim][PF₆]. The inhibitory effect of [bmim][PF₆] on YADH was probably caused by the competition of the imidazole group of [bmim][PF₆] with the coenzyme NAD⁺ for the binding sites on YADH. In a water‐in‐[bmim][PF₆] microemulsion, YADH was catalytically active due to the formation of the interfacial membrane of the nonionic surfactant TritonX‐100, which separated YADH from [bmim][PF₆] and avoided the direct inactivation of [bmim][PF₆] on YADH. Under optimal conditions, the activity of YADH was as high as 51 µmol L^?1 min^?1. CONCLUSION: [bmim][PF₆] was an inhibitor of YADH and its negative effect on YADH could be lessened by its microemulsification. Copyright © 2008 Society of Chemical Industry     

Synthesis and two-photon absorption property of new π-conjugated dendritic fluorophores containing styrylpyridyl moieties

Four new multi-branched two-photon absorption chromophores, namely 1-(4-bromobenzal)-3,5-bis(4-((E)-2-(pyridin-4-yl)vinyl)phenyl)benzene (4), tris(4-((E)-2-(pyridin-4-yl)vinyl)phenyl)-benzene (5), 6-chloro-N²,N⁴-bis(4-((E)-2-(pyridin-4-yl)vinyl)phenyl)-1,3,5-triazine-2,4-diamine (6), tris-[4-(2-pyridin-4-yl-vinyl)-phenyl]-amine (7), have been synthesized and characterized. One-photon fluorescence, fluorescent quantum yields and two-photon fluorescence have been investigated. The experimental two-photon absorption cross-sections of 4–7 in DMF are 6, 11, 13 GM (pumped by 740 nm laser) and 19 GM (pumped by 800 nm laser), respectively. The calculated two-photon absorption cross-sections of 4–7 are 5.41, 7.67, 9.57 and 76.14 GM, respectively. The two-photon induced fluorescent peak wavelengths of 4–7 in DMF are 421, 425, 474 and 534 nm pumped by 680, 680, 740 and 800 nm laser, respectively. The results show that molecule 7 is a good two-photon absorption fluorophore possessing long two-photon fluorescent lifetime, good fluorescent quantum yield and large two-photon absorption cross-section. The two-photon absorption peak wavelength of molecule 7 is at 800 nm, which is favourable for initiating two-photon photopolymerization.     

Input-output finite-time stability of time-varying linear singular systems

This paper studies the input-output finite-time stabilization problem for time-varying linear singular systems. The output and the input refer to the controlled output and the disturbance input,respectively.Two classes of disturbance inputs are considered,which belong to L-two and L-infinity.Sufficient conditions are firstly provided which guarantee the input-output finite-time stability.Based on this,state feedback controllers are designed such that the resultant closed-loop systems are input-output finite-time stable.The conditions are presented in terms of differential linear matrix inequalities.Finally,an example is presented to show the validity of the proposed results.     

基于游程编码思想的条码定位与识别方法

在复杂背景中的定位条码是图像式条码识别系统中的一个关键步骤,如何在复杂的背景中快速、白动地检测出条形码是该文的主要研究内容。首先介绍了条型码的编码结构,然后提出了一种基于游程编码思想的条码定位与识别方法,最后通过给出相关实验结果,验证了该算法的可行性和实用性。     

一种高效挖掘冠心病医案关联规则的仿真研究

研究中医冠心病医案,高效挖掘有益信息规则问题,由于中医医案数据量大、关联性强,针对传统的关联规则挖掘算法处理中医医案数据时存在效率低、收敛速度慢及漏报规则等问题,提出一种小生境技术和基因表达式编程相结合的挖掘关联规则的方法。通过惩罚函数设置支持度阈值,利用小生境技术执行小生境演化、融合算法,结合基因表达式编程算法操作简单、鲁棒性强的优势搜索强关联规则,有效避免了算法早熟,解决了规则冗余。针对治疗冠心病的中医医案进行了验证性实验,实验结果表明,改进算法在提取有效信息的效率上有较大的提高,挖掘结果对冠心病中医临床诊治具有一定的参考价值。