激光焊接齿科CoCr-NiCr异种合金组织结构研究

选用齿科烤瓷用NiCr合金和支架用CoCr合金,利用脉冲Nd-YAG激光,在不同电压下进行焊接,考察焊件力学性能,优选电压条件,研究此条件下焊件熔焊区及其附近区域化学成分、显微组织变化规律.结果表明,适合齿科临床应用焊接电压为280V,此条件下可以得到显微组织致密、细小的熔焊区,熔焊区与两侧母材呈冶金结合,主要成分为Ni元素,以固溶体和化合物形式存在;Co、Cr元素部分溶入固溶体,部分与Mo、Be形成化合物.焊接中冶金过程充分,无新相生成.双向侧吹氩气可以对熔焊区起到良好的保护作用,无氧化物形成.     

深冷处理提高镀锌钢板点焊电极寿命的机理

为了提高镀锌钢板点焊电极寿命，作者提出了镀锌钢板点焊电极的深冷处理方法。采用不同深冷处理工艺参数处理了点焊镀锌钢板的Cr—Zr—Cu合金电极，用这些电极进行了镀锌钢板点焊电极寿命试验并与未深冷处理的电极寿命进行了比较。用扫描电子显微镜对深冷处理电极进行了背散射及面扫描分析，用X射线衍射法观测了深冷处理前后的电极晶粒度，测试了电极在深冷处理前后的电阻率。通过对深冷电极微观结构的观测及电极性能的测试，探讨了深冷处理提高镀锌钢板点焊电极寿命的机理。研究结果表明，深冷处理提高了镀锌钢板点焊电极基体的致密性，改变了合金元素的分布，细化了电极材料的晶粒，提高了镀锌钢板点焊电极的导电、导热能力及电极抗压渍变形的能力，从而提高了镀锌钢板点焊电极的寿命。     

新型硬齿面环面蜗杆传动研究

采用精确磨削TI蜗杆的砂轮，用类似直廓环面蜗杆或平面包络环面蜗杆的磨削方法加工环面蜗杆，使该蜗杆和齿面形状与砂轮曲面相同的蜗轮相配合，形成一种新型蜗杆传动，给出了这种传动蜗杆副齿面的数学模型，并通过计算机仿真得出了这种传动蜗轮齿面上接触线的形状及分布特征，初步分析了其啮合特点。     

30CrMnSiNi2A钢焊接接头热处理后的组织与性能

研究了30CrMnSiNi2A钢电子束焊接接头热处理后的组织和性能。试验结果表明，该钢电子束焊接接头焊缝为典型的粗大针状马氏体加残余奥氏体组织，HAZ（热影响区）为中温组织，经过900℃油淬加低温回火处理后，焊缝和热影响区组织转变为回火马氏体和残余奥氏体。焊态下，由于母材的强度较低，此种电子束焊接接头的拉伸试验断裂部位均在母材；经过上述热处理，母材的强度有了大幅度的提高，焊缝的强度虽然稍有降低，但伸长率提高了将近1倍，获得了良好的综合力学性能。但上述热处理后，焊缝和热影响区的冲击韧度和断裂韧度值较低，这主要是因为中碳马氏体中含碳量略高造成的。焊缝由于组织细小且均匀，与热影响区相比，具有相对较高的断裂韧度。     

CO2焊短路过程动特性与外特性的关系

CO2短路过渡焊在制造业上的应用非常广泛，对系统动特性有较高要求。该文结合电路理论和焊接短路过程的特点对过程动特性及其与外特性进行了细致的分析，突破了以往在外特性控制和动特性控制之间的关系上互不清楚、互不相关、相互分离的传统观念，认识到在CO2焊短路过渡过程中，动特性和外特性密切相关，既不能用外特性来解释动态过程；也不能认为动特性与外特性无关，动特性会受到外特性的制约，它们之间的关系可以用明确的数学语言进行分析，提出了动特性的最大响应能力及可控性的思想，分析结果有很大的理论意义。     

气液并流吸收过程中液相近界面浓度分布的全息干涉测量

1 INTRODUCTION Mass transfer across free interface of gas-liquid flow is of extensive importance and is encountered in most industrial applications. A close investigation of concentration distribution near the interface is helpful to understand mass transfer phenomena, to guide the development of transport theories, and to optimize the design of gas-liquid contact equipment. Laser holographic interference technique provides a precise and noncontact measurement method for measuring the tran…     

五种化合物临界温度和临界压力的测定

The critical properties of five compounds,including propanal,butanal,1-pentanal,2-methel butanal and trimer of ethanal,were determined for the first time by a new capillary quick-flow method. The apparatus was improved with a capillary tube and checked with hexane and 1-heptene as standard reagents. The experimental results proved that the determination of critical properties by quick-flow method with a capillary tube apparatus was successful.     

Perylene derivative sensitized multi-walled carbon nanotube thin film

Perylene-sensitized multi-walled carbon nanotubes (PV-MWNT) have been prepared by a π-stacking between nanotubes and perylene derivatives, N,N′-diphenyl glyoxaline-3,4,9,10-perylene tetracarboxylic acid diacidamide (PV). The resultant nanocomposites have been characterized by transmission electron microscope (TEM), UV-vis absorption, photoluminescence (PL) and photocurrent spectra. Long range ordering can be observed in the form of PV-MWNT via π-stacking by TEM. Red-shift in the optical spectra consisting of the UV-vis absorption and PL spectra with the attraction of PV on the surface of the MWNTs were observed. The evident quenching in PL spectra of PV-MWNT was ascribed to the absorption and transfer of recombination energy by MWNT. Photosensitivity spectra demonstrated an increasing photocurrent in the ultraviolet region and a broadening photosensitivity in the red spectral region for solar cells based on PV-MWNT.     

Preparation of solar selective absorbing CuO coating for medium temperature application

A new method of preparing CuO solar selective absorbing coating for medium temperature is presented. After pretreatment, brass was overlaid with CuO by chemical plating. The effects of reactant concentration, reaction temperature and reaction time on the absorptivity of CuO coating were investigated. The optimized condition of preparing CuO coating was obtained. The CuO coating was analyzed with X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). In order to prolong the period of use, the CuO coating was protected by TiO₂. The experiment shows that the TiO₂/CuO coating is more heat-resistant, acid-resistant, and wear resistant than CuO coating, without losing absorptivity markedly. The TiO₂ coating can reduce emissivity and protect the CuO coating. Translated from Journal of Tianjin University, 2006, 39(12): 1485–1489 [译自: 天津大学学报]     

模板剂在介孔分子筛合成中的作用机理

以模板法合成分子筛不但能够有效的控制其介观结构,而且环境友好,操作简单,成本低廉,但由于反应在高压釜中进行,模板剂对分子筛合成的作用机理尚未被认清。本文总结了目前提出的可能的模板剂作用机理,并加以分类讨论,以对分子筛合成过程提供指导。