Perovskite ceramic oxide as an efficient electrocatalyst for nitrogen fixation

The electrochemical conversion of N₂ to NH₃ is an interesting research topic as it provided an alternative and energy-saving method compared with the traditional way of NH₃ production. Although different materials have been proposed for N₂ reduction, the use of defects in oxides was only reported recently and the relevant working mechanism was not fully revealed. In this study, Sr was used as the dopant for LaFeO₃ to create oxygen vacancies, forming the Sr-doped LFO (La_0.5Sr_0.5FeO_3-δ) perovskite oxide. The La_0.5Sr_0.5FeO_3-δ ceramic oxide used as a catalyst achieves an NH₃ yield of 11.51 μgh^?1 mg^?1 and the desirable faradic efficiency (F.E.) of 0.54% at ?0.6 V vs reversible hydrogen electrode (RHE), which surpassed that of LaFeO₃ nanoparticles. The ¹⁵N isotope labeling method was employed to prove the La_0.5Sr_0.5FeO_3-δ catalyst had the function of converting N₂ into NH₃ under the electrolysis condition. The first principle calculations were used to investigate the mechanism at the atomistic level, revealing that the free energy barriers changed significantly with the introduction of oxygen vacancies that accelerated the overall nitrogen reduction reaction (NRR) procedure.     

稀土元素铈对P9钢组织及性能的影响

研究了稀土Ce对P9钢显微组织和力学性能的影响.结果表明,稀土Ce加入量小于0.5％时,稀土Ce能起到净化基体和细化晶粒的作用,对P9钢的综合力学性能有一定改善.     

大直径薄壁X60钢级管线用无缝钢管的开发

介绍了采用局部感应加热热扩工艺开发生产X60钢级Φ406.4 mm×7.92 mm管线用无缝钢管的工艺过程。通过检测成品的几何尺寸、机械性能以及金相组织分析,证明该产品尺寸符合标准要求,金相组织均匀,综合性能达到API Spec 5L标准PSL2水平。热扩成型的同时进行热处理,消除了钢管内应力,缩短了生产周期,降低了大直径薄壁高钢级管线用无缝钢管的生产成本。     

自然循环条件下倒U型管蒸汽发生器一次侧倒流现象关键影响因素研究

倒U型管蒸汽发生器（UTSG）在自然循环条件下存在倒流现象，影响一回路冷却剂系统载热能力及自然循环能力。本文参照芬兰压水堆热工实验装置（PWR PACTEL）中UTSG设计参数，利用计算流体力学（CFD）软件Fluent模拟流量匀速下降工况下UTSG中的倒流现象，研究一次侧运行参数、UTSG设计参数以及二次侧运行参数对于倒流现象的影响。结果表明，提高UTSG一次侧温度、一次侧运行压力、倒U型管热导率将增大UTSG的临界质量流量，使得UTSG更易发生倒流；提高UTSG二次侧给水量、二次侧温度以及倒U型管内壁粗糙度将使得UTSG临界质量流量下降，抑制倒流现象发生；而倒U型管壁厚对倒流现象几乎无影响；相较于改变二回路温度，改变一回路温度对于倒流现象的影响更为显著。本研究结果可为UTSG的参数优化提供一定参考。      

A mechanism informed neural network for predicting machining deformation of annular parts

Controlling machining deformation of annular parts is crucial for ensuring the performance of high value products and equipment. For example, during manufacturing of critical parts in aircrafts and spacecrafts, accurate prediction of machining deformation is the basis for guiding the formulation of deformation control strategies. However, due to the complexity of the machining deformation of annular parts, existing methods still have limitations in accurate prediction. To this end, this paper proposes a mechanism informed neural network (MINN) to predict machining deformation of annular parts. MINN is realized by establishing the dual sub-networks structure and using enhanced loss functions with the consideration of the deformation mechanism model characteristics of annular parts. The deformation was decomposed into the axisymmetric portion and the non-axisymmetric portion according to the deformation superposition principle, and modeled separately based on the thin-shell theory and Fourier series. Experiment results showed that the proposed method could predict the machining deformation of annular parts more accurately and stably with a small amount of training data, compared with previous methods.     

A data-based photonuclear simulation algorithm for determining specific activity of medical radioisotopes

For simulating more accurately neutron or proton production from photonuclear reactions,a data-based photonuclear reaction simulation algorithm has been developed.Reliable photonuclear cross sections from evaluated or experimental database are chosen as input data.For checking the validity of the use of the data-based photonuclear algorithm,benchmarking simulations are presented in detail.We calculate photonuclear cross sections or reaction yield for ~9Be,~(48)Ti,~(133)Cs,and ~(197)Au and compare them with experimental data in the region of incident photon energy below ~30 MeV.While Geant4 can hardly reproduce photonuclear experimental data,results obtained from the data-based photonuclear algorithm are found in good agreement with experimental measurements.Potential application in estimation of specific activity of radioisotopes is further discussed.We conclude that the developed data-based photonuclear algorithm is suitable for an accurate prediction of photoninduced neutron or proton productions.     

基于C8051F040单片机的动态血糖监测系统的低功耗设计

动态血糖监测有助于糖尿病人监控血糖、控制病情。在动态血糖监测仪器设计中,微处理器是影响系统功耗的重要因素。为了最大限度地延长连续监测时间,论文提出了一种基于高速、高集成度的混合信号片上系统级单片机C8051F040的动态血糖监测系统的低功耗设计方案,采取了一系列的硬件和软件优化措施,通过理论计算和实测,给出了在连续血糖监测条件下系统功耗的优化方法。结果显示,使用一节5号电池供电,系统可以连续工作400小时以上。     

Performance-driven design of Biocompatible Mg alloys

Magnesium (Mg) and its alloys provide numerous benefits as a resorptive biomaterial and present the very real possibility of replacing current metallic implant materials in a variety of roles. The development of suitable biodegradable implant alloys is a multidisciplinary challenge, since alloy design must be confined to a range of alloying additions that are biologically nontoxic, whilst still providing the requisite mechanical properties. This leaves a small number of compatible elements that can provide benefits when alloyed with Mg, including calcium (Ca) and zinc (Zn). To date, although a range of different Mg alloys have been investigated both in vitro and in vivo, little work has been performed to characterize the relationship between the composition of Mg alloys, their corrosion and resulting mechanical properties over time. Consequently it is crucial to understand how these properties may be related if alloys are to be successfully screened for implantation in the body.     

复合型热泵在商住楼中的应用

针对商住楼,提出了一种复合型热泵系统。在夏季,该系统给室内供冷的同时利用热回收制备生活热水,在环境温度较高时,利用生活给水带走一部分冷凝热;在冬季,该系统既可以制备生活热水,也能给室内供热,在环境温度较低时,利用消防水池的水作为热源,实现了设备本身和建筑物内水资源的充分利用,从而保证热泵常年都有较高的能效值。     

废玻璃粒径对废玻璃砂浆耐高温性能的影响

用粒径1.18~5.00mm,600μm~1.18mm,300~600μm和＜300μm这4种废玻璃分别取代（质量分数）30%,60%,100%天然砂配制砂浆,测试砂浆在20,300,400,600,800,900℃的抗压强度和劈裂抗拉强度.结果表明：在常温下,用粒径≥300μm废玻璃取代天然砂后,砂浆强度低于基准砂浆,且随废玻璃取代率增大而降低;用粒径＜300μm的废玻璃取代部分天然砂后,砂浆劈裂抗拉强度略大于基准砂浆,抗压强度则大大高于基准砂浆;所有配合比砂浆强度均随着加热温度的提高不断降低,强度与加热温度间呈良好的线性关系,相关系数大多＞0.980;用粒径＜300μm废玻璃取代60%以上天然砂,高温益化系数＞1.25,可显著提高砂浆的高温性能.