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11.
Energy bands, effective mass of carriers, absolute band edge positions and optical properties of tetragonal AgInS2 were calculated using a first-principles approach with the exchange correlation described by B3LYP hybrid functional. The results indicate that tetragonal AgInS2 has a direct band gap of 1.93 eV, which reproduce well experimental value. Calculated effective masses of electrons and holes are both small which are beneficial to separation and migration of electron and hole pairs. This implies that AgInS2 has good photocatalytic performance. The calculated optical characteristics indicate that AgInS2 has a slight anisotropy for both the real and imaginary parts of the dielectric function and exhibits large optical absorption in the visible light region. Furthermore, the calculated band edge positions in (100), (010) and (001) surfaces indicate that tetragonal AgInS2 is beneficial to the reduction and oxidation of water to hydrogen and oxygen under visible light irradiation. 相似文献
12.
在无线传感器网络中,大量感知数据汇集到sink节点的采集方法会导致sink节点附近的节点能量耗尽,造成能量空洞。针对该问题,利用移动的sink节点进行数据收集是一种解决方法,其中移动sink的路径规划成为一个重要的问题。提出了一个移动sink路径规划算法,将无线传感器中随机分布的节点划分为不同的子区域,寻找sink节点移动的最佳转向点,最终得到最优的移动路径,以实现无线传感器网络生命周期最大化。仿真实验表明,与现有方案相比,该算法能显著延长网络的生命周期。 相似文献
13.
《Ceramics International》2015,41(6):7366-7373
The accumulative damage behaviour of BN-coated Hi-Nicalon™ SiC fibre-reinforced SiC matrix composite was examined under tensile cyclic loading at room and elevated temperatures. The accumulative damage occurring during the cyclic loading was quantitatively characterised using the damage parameter obtained by the hysteresis loop curves. The damage parameter increased with increasing applied stress beyond the matrix cracking stress, and it subsequently retained a nearly constant value until just before fracture. Moreover, the dielectric constant, dielectric loss and loss tangent of the composite were measured before and after the fracture in the frequency range 1–1000 MHz. The dielectric properties had similar frequency dependency before and after the fracture. However, the dielectric constant, dielectric loss and loss tangent were lower in the post-fractured specimens than in the pristine ones. The reduction of the dielectric properties was associated with the accumulative damage stored in the specimens. In addition, the relationships between the dielectric properties and the damage parameter were described in detail. 相似文献
14.
Massive Open Online Courses (MOOCs) are becoming an essential source of information for both students and teachers. Noticeably, MOOCs have to adapt to the fast development of new technologies; they also have to satisfy the current generation of online students. The current MOOCs’ Management Systems, such as Coursera, Udacity, edX, etc., use content management platforms where content are organized in a hierarchical structure. We envision a new generation of MOOCs that support interpretability with formal semantics by using the SemanticWeb and the online social networks. Semantic technologies support more flexible information management than that offered by the current MOOCs’ platforms. Annotated information about courses, video lectures, assignments, students, teachers, etc., can be composed from heterogeneous sources, including contributions from the communities in the forum space. These annotations, combined with legacy data, build foundations for more efficient information discovery in MOOCs’ platforms. In this article we review various Collaborative Semantic Filtering technologies for building Semantic MOOCs’ management system, then, we present a prototype of a semantic middle-sized platform implemented at Western Kentucky University that answers these aforementioned requirements. 相似文献
15.
《Journal of the European Ceramic Society》2020,40(15):5475-5482
The lead-free Ba0.53Sr0.47TiO3 (BST) thin films buffered with La0.67Sr0.33MnO3 (LSMO) bottom electrode of different thicknesses were fabricated by pulsed laser deposition method on a (001) SrTiO3 substrate. It was found that the roughness of electrode decreases and substrate stress relaxes gradually with the increase of LSMO thickness, which is beneficial for weakening local high electric field and achieving higher Eb. Therefore, the recoverable energy density (Wrec) of BST films can be greatly improved up to 67.3 %, that is, from 30.6 J/cm3 for the LSMO thickness of 30 nm up to 51.2 J/cm3 for the LSMO thickness of 140 nm after optimizing the LSMO thickness. Furthermore, the thin film capacitor with a 140 nm LSMO bottom electrode shows an outstanding thermal stability from 20 °C to 160 °C and superior fatigue resistance after 108 electrical cycles with only a slightly decrease of Wrec below 1.6 % and 3.7 %, respectively. Our work demonstrates that optimizing bottom electrodes thickness is a promising way for enhancing energy storage properties of thin-film capacitors. 相似文献
16.
In this work, TiO2 nanoparticles are surface modified by NH2-terminated organic moieties arised from 4,4′-methylene diphenyl diisocyanate (MDI). These nanoparticles are incorporated into ether-based segmented polyurethane (SPU) matrix. MDI is utilized as monomer together with poly(tetramethylene oxide) (PTMO) comonomer for preparing the final polymer as well. The NH2-functionalized TiO2 nanoparticles are covalently linked to the NCO terminals of the resulting SPU macromolecules during film preparation stage. Therefore, in addition to butylene glycol, these surface modified nanoparticles with enhanced organophilicity could play the role of the second chain extender of NCO-capped SPU macromolecules through formation of urea linkages. Optical and thermal behaviors of the transparent and flexible film (SPU/TiO2–MDI) is compared with those of unmodified TiO2 (SPU/TiO2) and TiO2-unloaded SPU films. Though the particle loading is only 5 wt.%, incorporation of TiO2 and TiO2–MDI nanoparticles into the SPU polymer enhances significantly the light absorption in UV region at 300–400 nm. SEM images of the prepared films clearly show a considerable decrease in particle aggregation for TiO2–MDI into SPU matrix compared to that of unmodified TiO2. TG analyses indicate a one-step decomposition pattern with onset temperatures of about 360 and 380 °C for neat SPU and SPU/TiO2–MDI, respectively. Moreover, DTA thermograms of both nanocomposites show obviously two exothermic phase transitions in the thermal range of 330–440 °C. 相似文献
17.
In this article we illustrate a methodology for building cross-language search engine. A synergistic approach between thesaurus-based approach and corpus-based approach is proposed. First, a bilingual ontology thesaurus is designed with respect to two languages: English and Spanish, where a simple bilingual listing of terms, phrases, concepts, and subconcepts is built. Second, term vector translation is used – a statistical multilingual text retrieval techniques that maps statistical information about term use between languages (Ontology co-learning). These techniques map sets of t f id f term weights from one language to another. We also applied a query translation method to retrieve multilingual documents with an expansion technique for phrasal translation. Finally, we present our findings. 相似文献
18.
19.
The diffusion of solutes through milk and milk-derived media (i.e. dairy systems) is an important factor in the transformation and stabilization of dairy products. In several polymer systems, the diffusion of solutes largely depends on the microstructure within the material. The aim of this work was to establish how the diffusion of solutes is affected by the microstructure of dairy systems. Diffusion measurements were carried out using the technique of fluorescence recovery after photobleaching (FRAP). Diffusion coefficients of a range of 8 fluorescein isothiocyanate (FITC)–dextrans (molecular weights from 4 to 2000 kDa) were measured in dairy systems. These systems had the same casein concentration (130 g kg− 1) and water activity but their microstructure had been altered by different treatments: heat-treatment and rennet-induced coagulation. Microstructural parameters of these systems were estimated by the image analysis of transmission electron microscopy (TEM) micrographs. The results showed that the diffusion of solutes was affected by the microstructure of dairy systems. The application of heat-treatment hindered the diffusion of all solutes (irrespective of molecular weight), whereas rennet coagulation only increased the diffusion of the larger solute molecules (> 20 kDa). At the microscopic scale, the diffusion of solutes in dairy systems was mainly explained by both the pore size within the structure and by the interface area between the solute molecules and the surrounding matrix. Larger solutes diffused faster in dairy systems with larger pore sizes and less interface area. 相似文献
20.