BiOCl/TiO2复合材料的制备与光催化性能

基于半导体异质结原理,设计并制备了新型氯氧铋/二氧化钛复合光催化材料,以甲基橙为目标污染物,研究了氯氧铋制备条件和复合比例对复合材料的光催化特性的影响,随后利用XRD、UV-Vis DRS、TEM、EPR等方法对催化材料进行表征,从表面形貌、自由基等角度,分析其光催化原理。结果表明,新型复合光催化材料相对氯氧铋、二氧化钛的单体,具有更强的紫外催化能力,对传统有色染料均具有良好的去除效果。这是由于氯氧铋和二氧化钛可以形成半导体异质结,光生电子传递降低了载流子负荷率,羟基自由基生成量增加,因此光催化性能大幅提升。     

金属化竹纤维的8mm微波干扰性能研究

为研制一种轻质毫米波干扰材料,试验以化学镀的方式对竹纤维进行表面金属化改性(镀覆的金属为铜和镍);并检测了金属化竹纤维的8mm波衰减性能.测试结果显示金属化竹纤维的8mm波衰减性能较好:20mg镀铜竹纤维可衰减17.5dB,30mg镀镍竹纤维可衰减24.2dB.化学镀工艺对金属化竹纤维的衰减性能有一定影响,在相同工艺下所制备试样的8mm波衰减分贝值随测试用量的增加而增加.试验结果表明金属化竹纤维可望成为一种新型毫米波干扰材料.     

吸毒现场吸毒工具中的甲基苯丙胺分析

Based on the details in the case, the analysis method of methamphetamine was built up, which is supposed to be used for in vitro material taken from the criminal scene. It is suggested that GC-FID is first used for methamphetamine concentration scanning. Thus, according to the results, the sample could be concentrated or diluted for the next GC/MS analysis. Using this procedure, the satisfying result was achieved.     

Phase transitions in adsorbed layers VIII: Evaluation of phase diagrams for monolayers of argon,krypton and xenon adsorbed on graphite

The theory of monolayer adsorption of simple atomic gases on crystalline solid is presented and is used to calculate the phase diagrams for noble gases adsorbed on graphite. It is shown that the third-order correction terms to the interaction energy between adsorbed atoms must be included in order to obtain results that are in agreement with experimental data. It is also demonstrated that our theory predicts the formation of a commensurate two-dimensional solid phas e for krypton monolayer films and an incommensurate two-dimensional solid phase for both argon and xenon monolayer films on graphite.     

活性炭纤维在脉冲放电水处理中的催化作用

为了探索脉冲放电水处理反应器与活性炭纤维联合应用的可行性以及活性炭纤维在脉冲放电过程中的作用,将活性炭纤维加入气液串联放电反应器中对模拟污染物甲基橙进行了联合降解,并对活性炭纤维在脉冲放电过程中表现出的催化作用进行了研究。实验结果表明:脉冲放电和活性炭纤维联合处理,大幅度提高了降解率近24%,说明活性炭纤维与脉冲放电联合具有协同效应;脉冲放电和吸附饱和活性炭纤维联合处理与单独脉冲放电处理相比降解率提高16.7%,活性炭纤维的催化作用显著;加入H2O2对OH的形成具有增强作用,同时提高了UV和O3的利用率而且还有利于活性炭纤维的再生。     

涂层中伴有化学反应的传质动力学模型及解析解

有害液体在均匀有界固体介质中的扩散通常是一个伴有化学反应的传质过程，本文采用拉普拉斯交换法对其动力学方程进行了新的求解，得出了吸收过程的解析解。通过定义标准函数err(x)及反函数aer(x)，推导出当降解速率常数k=0时扩散系数D的精确解，理论误差为O．以芥子气在醇酸漆涂层中的传递为例，验证得该方法与实验值的标准差为σ=1.95×10-10 cm2/S，其精度远远高于常规方法。在此基础上，求出了液体在涂层中的吸收量、扩散通量，得到了它们的时空分布规律，分析了降解速率常数k对它们的影响。丈章更为准确、系统地描述了有害液体在涂层中的吸收规律，所给出的扩散系数计算方法更加简洁、精确，对有害物质的洗消、危害评估及相应措施的制定提供了理论依据。     

Fractionation and characterization of ɛ-poly-l-lysine from Streptomyces albulus CGMCC 1986

ɛ-Poly-l-lysine (ɛ-PLL) produced by Streptomyces albulus CGMCC 1986 was fractionated using ultra-filtration technique with 2 and 5 kDa cut-offs of membrane. The number-average molecular weight of each fraction was determined by ¹H nuclear magnetic resonance (NMR) method. The number-average molecular weights of the cutoffs of 5 and 2 kDa and the filtrate are 4,230.95, 3,687.80, and 1,900.82 Da, respectively. ¹H NMR indicates the chemical shifts of α-H, β-H, γ-H, δ-H, and ɛ-H are very similar to all the fractions. Fourier transform-infrared (FTIR) spectra showed that the ɛ-PLL solid samples obtained by freeze-drying at pH 5 with molecular weights higher than 2 kDa take on a β-turn conformation, however, the fraction with molecular weight smaller than 2 kDa adopts random coil structure. The antibacterial test proved that the fraction between 2 and 5 kDa of membranes behaves the highest antibacterial activity than other fractions for the test strains of Staphylococcus aureus, Micrococcus luteus, Bacillus subtilis, Escherichia coli, and Shigella.     

装药起爆位置对爆炸能量传递影响的数值模拟

采用数值模拟软件LS-DYNA模拟了带壳装药在土壤层中在其不同端面起爆时爆炸产生的应力波,在上层半无限混凝土介质中的传播过程,得到了装药不同端面起爆时产生的应力波在混凝土中随时间和位置的变化规律.模拟结果表明,在装药底端面起爆时爆轰能量利用率较高,对混凝土的作用效果较好,能够为提高装药结构威力设计提供一定参考依据.     

一种数字调制器的设计与实现

介绍了一种实现宽带通用数字调制器的算法,该算法能产生输出频率从1M～60M的各种通用调制信号。通过验证,所产生的调制信号具有良好的误差向量幅度(EVM)和频谱特征。     

Readily prepared heterogeneous molybdenum-based catalysts as highly recoverable,reusable and active catalysts for alkene epoxidation

Polymer-bound aliphatic amines were prepared readily from Merrifield resin and used as supports for immobilization of molybdenum hexacarbonyl. The high activity of these polymer-supported molybdenum catalysts has been demonstrated in epoxidation of various alkenes in the presence of tert-butylhydroperoxide (TBHP). These new heterogenized molybdenum epoxidation catalysts can be recovered and reused several times without significant loss of their activities.