响应面法优化芽孢杆菌LJ-7发酵产酯酶条件

为了获得海洋芽孢杆菌LJ-7发酵产酯酶的最佳条件,采用响应面法对其发酵条件进行了优化。首先,通过单因素试验选出对酯酶产量影响较显著的3个因素,即发酵温度、初始pH和发酵时间。在单因素试验的基础上,采用Box-Benhnken中心组合方法进行三因素三水平的试验设计,以酶活为响应值,利用响应面分析法进行进一步优化,确定最佳发酵条件为:发酵时间42.81h,发酵温度29.40℃,pH为6.21,此时预测的酯酶酶活为24.91 U/mL。在此最佳条件下,平行试验测得实际酶活为24.63U/mL,达到理论预测值的95%以上。该模型较好地预测了实际发酵情况,得到的优化条件具有实际应用价值。     

The measurements of vapor liquid phase equilibrium for R717 + R152a system at temperatures ranging from 253.150 K to 293.150 K

In contrast to pure ammonia, some additives into it may provide better solubility of the mineral oils, higher refrigeration capacity and lower discharge temperature of the compressor. In this paper, the vapor liquid phase equilibrium for the ammonia + 1,1-difluoroethane system at temperatures ranging from 253.150 K to 293.150 K were studied. The Peng–Robinson equation of state with the Huron–Vidal mixing rule involving the non-random two-liquid activity coefficient model was employed to describe the VLE behavior of the system concerned. The maximum average absolute relative deviation of pressure and average absolute deviation of vapor phase are 0.31% and 0.009, respectively. A positive azeotropic behavior was exhibited at the experimental temperature range.     

Project manager's emotional intelligence and project performance: The mediating role of project commitment

Emotional intelligence is considered to be important for project managers to affect project performance, but emotional intelligence does not always play an effective role. Based on conservation of resource theory, this article explores the impact of project managers’ emotional intelligence on project performance. The results show that the emotional intelligence of project managers affects project performance through the mediating effect of project commitment, and project complexity negatively moderates the impact of project managers’ emotional intelligence on project commitment. This article provides practical guidance on how project managers can handle emotional intelligence in different complex situations and serves as a reference for the selection and appointment of project managers in complex projects.     

The effect of solvent and ionomer on agglomeration in fuel cell catalyst inks: Simulation by the Discrete Element Method

We simulate agglomeration in different fuel cell catalyst ink solutions using Discrete Element Method. Carbon support is modelled as particles in various inks with ionomer and various solvents. The particles interact with particle-pair forces resulting in agglomerate build-up. The classical colloidal theory with van der Waals and electric double layer forces underestimates the ink stability, which motivates the development of a new model of polymer force between particles. The force is activated when there is a bridging of polymer between the carbon black particles, and the strength is dependent on the ionomer interaction with the solvent by the dielectric constant. A critical dielectric constant was defined for which ionomer form a web-like polymer network that increases the ink stability. This modification can explain the trend of the ink stability, and the model can simulate the effect of different solvents on the agglomerate size distribution with good agreement with experimental results.     

模糊控制技术及其在化工中的应用

介绍了模糊控制技术的发展历程和特点，讨论了模糊控制技术的缺点和研究热点，概述了模糊控制技术在化工中的应用，提出了模糊控制技术的发展方向。     

地埋管热泵系统实例分析

结合实例对地埋管土壤源热泵系统从方案选择、技术经济分析、设计要点等多个方面进行分析论证,结果表明运行费用较传统空调方式可节省30%,节能效果十分明显,尤其适合有制冷、采暖、供生活热水等多种需求的工程。     

高速动车组用散热器结构及关键工艺对比

对高速动车组散热器结构进行了全面的对比和分析,提出国内高速动车组散热器的改进措施建议。     

基于GIS的大孤山露天矿边坡稳定性分析研究

针对辽宁省鞍山市大孤山露天铁矿北端边坡出现滑动变形这一现象,通过详细的地质调查和边坡节理裂缝的测定,利用TM30监测露天矿边坡的变形情况。用FLAC软件进行数值模拟分析边坡的稳定性。采用时间序列分析监测数据,并总结出边坡变形的一般性规律。建立起基于GIS的大孤山露天矿变形监测预警系统。     

重度受损混凝土梁修复后抗剪性能试验研究

针对建筑抗震设防目标"小震不坏、中震可修、大震不倒"中"中震可修"情况,以重度受损钢筋混凝土梁为对象,研究其经加固修复后的抗剪性能。制作4根模拟重度受损钢筋混凝土框架梁端的倒T型试件,采用灌浆料全截面置换受损区域混凝土并外部环贴碳纤维布的复合加固方法对其进行加固修复,通过施加低周期往复荷载试验,分析其受剪承载力。本文部分作者已对正截面承载能力有所研究,这里侧重研究斜截面承载能力。试验结果表明,修复后梁的受剪承载力显著提高;灌浆料应用于全截面加固,可很好地与原混凝土共同工作;碳纤维布不仅有效提高构件受剪承载力,还限制裂缝的开展。试验结果与理论计算对比分析,得出修复后梁受剪承载力提高幅度,验证此复合加固方法的可行性,为工程实践提供试验依据。