Use of the time constant to detect corrosion speed in reinforced concrete structures

The relatively simple to measure ‘time constant’ is presented as an index for characterizing the level of corrosion experienced by steel in concrete. This communication, largely in the form of a technical note, explicitly illustrates that the time constant determined from electrochemical testing has significant merit for monitoring corrosion of steel in concrete, and appears to be insensitive to the area of electrode being probed. In this work, the time constant, κ, is determined following a galvanostatic excitation signal, revealing a good correlation between the value of κ and corrosion status across specimens of widely varying geometry. Although this notion has been suggested in the past, this work presents both a survey and consolidated review to indicate the utility of the parameter as an index to corrosion rate on-site.     

Changes in a Population of Exotic Rainbow Smelt in Lake Superior: Boom to Bust, 1974–2005

Changes in a population of rainbow smelt (Osmerus mordax) in the Apostle Islands region of Lake Superior were chronicled over a 32-yr time series, 1974-2005. At the beginning of the time series, rainbow smelt was the predominant prey species, abundance of lake herring (Coregonis artedi) was very low, and the dominant predator was stocked lake trout (Salvelinus namaycush). Following a period of successful lake trout stocking in the 1970s, the rainbow smelt population declined sharply in 1980, largely through mortality of adult fish and subsequent poor recruitment. In the succeeding 4 years, rainbow smelt populations reached historic low levels, resulting in reduced food resources for both wild and stocked lake trout. During 1985–1990 lake herring stocks began a spectacular recovery following the appearance of a very strong 1984 year class and subsequent 1988, 1989, and 1990 year classes. Rainbow smelt benefited from the high abundance of young lake herring as an alternate prey source for lake trout and showed a partial recovery in the late 1980s. However, a growing lake trout population coupled with an 8-yr period of low herring reproduction after 1990 resulted in a diminished rainbow smelt population dominated by age-1 and 2 fish and showing a pattern of alternating recruitment attributed to cannibalism. Low productivity of rainbow smelt and intermittent production of herring over the past decade has left lake trout populations with a diminished prey base. Although lake trout recovery benefited from the presence of rainbow smelt as a prey resource, the Lake Superior fish community was fundamentally altered by the introduction of rainbow smelt.     

Reappearance of Deepwater Sculpin in Lake Ontario: Resurgence or Last Gasp of a Doomed Population?

Deepwater sculpin (Myoxocephalus thompsonii) were abundant in Lake Ontario in the 1920s and at least common into the 1940s. By the 1960s they were rare and, thereafter, some considered the population extirpated even though a synoptic survey of the lake in 1972 produced three, relatively large (148–165 mm total length, TL), and presumably old, specimens from the northern half of the lake. Deepwater sculpin were absent from annual survey catches in the 1980s and did not reappear until 1996, when three were caught in northern Lake Ontario. Isolated collections of deepwater sculpin continued during 1998–2004. Catches during 1996–2004 included five smaller individuals, 89-118 mm TL. In 2005, catches increased sharply, with 18 deepwater sculpin collected from southern waters and one from northern waters. Moreover, young, small sculpin were dominant in 2005–16 of the 19 sculpins averaged 68 ± 12 mm total length (± 1 s.d.). The young fish observed since 1996 could have originated from reproduction by the small in-lake population, from downstream drift of planktonic larvae from Lake Huron, or both. The presence of juveniles is a clear sign that conditions for survival of young deepwater sculpin are becoming more favorable, perhaps because of reduced abundance of alewife (Alosa pseudoharengus), a pelagic planktivore linked to depression of deepwater sculpin in Lake Michigan, and also low bundances of burbot (Lota lota) and lake trout (Salvelinus namaycush), benthic piscivores     

Semi-batch extraction of anthocyanins from red grape pomace in packed beds: experimental results and process modelling

A semi-batch extraction process of anthocyanins was studied in a packed bed. Methanol was used as solvent and the raw material studied consisted of skins of the tempranillo grape, which was obtained from the pomace from red wine vinification. The results show large diffusional effects due to strong control from the mass transfer. The best results were obtained using a high temperature and a high flow rate. A penetration model is proposed in terms of a bed of spherical particles. The model provides a value for the diffusion coefficient of the solute within the solid matrix. It can be seen that the adjustment of the model is satisfactory and that it is able to predict, to a reasonable extent, the yield of the extraction process.     

Extension of the QUASAR River-Water Quality Model to Unsteady Flow Conditions

A modification of the well-known water-quality model 'quality simulation along river systems'(QUASAR) is presented in order to extend its ability, so that it may be considered applicable under unsteady-flow conditions. An aggregated dead-zone travel-time parameter, based on (a) the kinematic wave velocity (celerity) of the flow wave and (b) the behaviour of the solute within so-called 'dead zones', has been incorporated into the existing model formulation. This extends the current continuously-stirred tank reactor-based model process to account for the behaviour of solute under unsteady-flow conditions. The enhanced water-quality model has been validated by application to the Colorado River.     

A probabilistic method for calculating the usefulness of a store with finite energy capacity for smoothing electricity generation from wind and solar power

This paper describes a novel method of modelling an energy store used to match the power output from a wind turbine and a solar PV array to a varying electrical load. The model estimates the fraction of time that an energy store spends full or empty. It can also estimate the power curtailed when the store is full and the unsatisfied demand when the store is empty. The new modelling method has been validated against time–stepping methods and shows generally good agreement over a wide range of store power ratings, store efficiencies, wind turbine capacities and solar PV capacities.Example results are presented for a system with 1 MW of wind power capacity, 2 MW of photovoltaic capacity, an energy store of 75% efficiency and a range of loads from 0 to 3 MW average.     

Size distribution of polydispersed aerosols during condensation in the continuum regime: Analytic approach using the lognormal moment method

An analytic solution for polydispersed aerosol condensation was obtained in the continuum regime. In this new approach, lower order moments, as compared to a previous study, were used to the log-normal aerosol size distribution, in order to obtain an analytical solution. The resultant analytic solution based on the lognormal size distribution was compared with the exact solution and proved to be in good agreement. The obtained solution was also found to be consistent to a greater degree with the exact solution was the previous analytic moment solution for the polydispersed aerosol condensation process. This is particularly true for cases in which broad size distributions exist.     

Maximum bubble loads: Experimental measurement vs. analytical estimation

This paper presents an experimental technique to measure maximum bubble loads, which are then compared with geometrical model estimations. The geometrical models studied assume that a particle monolayer, having a square arrangement, covers the entire bubble surface. Comparison of the experimental and analytical results gave a fairly high statistical correlation (R² = 0.89), when a shape factor was used for particle volume estimation (λ = 0.32–0.41; [Kelly, E.G., Spottiswood, D.J. Introduction to Mineral Processing, John Wiley & Sons, 1982, p. 491]). This supports the applicability of geometrical models for maximum bubble load estimation.     

黄浦江上游水源地突发性水污染事故应急处置预案探讨

阐述了水源地突发污染事件的概念、特点及其对于供水安全和城市经济社会系统安全运行的重要意义.论述了城市水源地突发污染事件应急研究的主要内容;以上海市黄浦江上游水源地为例,探讨了突发性污染事件应急处置体系的构建,并提出了相应的政策建议。