Nb和时效时间对热轧中锰TRIP钢中P偏聚的影响

热轧态中锰TRIP钢首先经650 ℃退火2 h,随后在550 ℃进行等温时效热处理,采用场发射扫描电镜(FE-SEM)研究该钢中P的偏聚和时效析出行为的变化情况。结果表明,中锰TRIP钢中P在晶界的偏聚是一种非平衡偏聚现象,临界时间约为50 h,与理论计算结果48 h较为吻合。在局部偏聚区域内,C与P存在共偏聚的关系,即P偏聚量高的地方,C含量也高。而合金元素Nb具有抑制P偏聚的效果,在20~70 h时效时间内,可以相对降低6.57%~19.5%的最大P偏聚量。根据电子背散射衍射(EBSD)菊池线分析,P偏聚量低于2.28at%时,P为固溶状态,高于2.28at.%时,P为析出状态。     

Nickel foam-supported Fe,Ni-Polyporphyrin microparticles: Efficient bifunctional catalysts for overall water splitting in alkaline media

Developing highly active, stable and sustainable electrocatalysts for overall water splitting is of great importance to generate renewable H₂ for fuel cells. Herein, we report the synthesis of electrocatalytically active, nickel foam-supported, spherical core-shell Fe-poly(tetraphenylporphyrin)/Ni-poly(tetraphenylporphyrin) microparticles (FeTPP@NiTPP/NF). We also show that FeTPP@NiTPP/NF exhibits efficient bifunctional electrocatalytic properties toward both the oxygen evolution reaction (OER) and the hydrogen evolution reaction (HER). Electrochemical tests in KOH solution (1 M) reveal that FeTPP@NiTPP/NF electrocatalyzes the OER with 100 mA cm⁻² at an overpotential of 302 mV and the HER with 10 mA cm⁻² at an overpotential of 170 mV. Notably also, its catalytic performance for OER is better than that of RuO₂, the benchmark OER catalyst. Although its catalytic activity for HER is slightly lower than that of Pt/C (the benchmark HER electrocatalyst), it shows greater stability than the latter during the reaction. The material also exhibits electrocatalytic activity for overall water splitting reaction at a current density of 10 mA cm⁻² with a cell voltage of 1.58 V, along with a good recovery property. Additionally, the work demonstrates a new synthetic strategy to an efficient, noble metal-free-coordinated covalent organic framework (COF)-based, bifunctional electrocatalyst for water splitting.     

Simulation of police shooting stability training based on FPGA and sensors

Stability training refers to the practice, while the surface is unstable and activation stabilizer muscles of the trunk and goals, which may ignore other forms of exercise. For stability, the train network control system is caused by network latency and packet drop out of school. The current study aimed to analyze the accuracy of necessary shooting skills and check the balanced posture, stability, and rifle shooting performance bracelets. There is no burden on the body in different performance groups. No. Equivalent continuous-time model, proposed account. The train network control system model uses Romanov theory, some new analytical techniques to get in, and less conservative results. It will be completed. The effectiveness of the proposed method of numerical display. The proposed training in the correct use of architecture to shape muscle memory training interns position signal trainee lead to incorrect behavior. Students warned that the recent shooting would be suspended after the retry using the selected function when needed for phase detection of unnecessary or excessive exercise pistol. Combined with real-time biofeedback applications, it can lead to accelerated learning, training the number of shots that poverty can be reduced, thereby saving time and costs.     

大庆油田水平井分流压裂技术

水平井分流压裂的技术原理是将水平井的水平段分成若干个单元，在每个单元的最佳部位进行射孔，每段的射孔数由孔径、单元数、设计施工排量等参数决定，射孔方案为压裂方案的有机组成部分。大庆油田已有5口水平井实施分流压裂，根据油层厚度分为两类：裂缝限制在油层内和裂缝穿透隔层贯穿多个薄油层。通过肇57-平35井和肇57-平33井进行的分流压裂贯穿多个油层现场试验，介绍了大庆油田水平井分流压裂的设计方法、压裂液体系、现场施工控制方法和效果分析方法。微地震裂缝监测结果表明，在最大施工排量7．5m^3／mim条件下，一次施工形成3～4条裂缝，加砂量最大达到75m^3（陶粒），平均砂比达到35％以上。水平井采用分流压裂技术施工后，初期产能可达到相邻直井压裂后产能的2．0倍以上。如何检测裂缝是否穿透了隔层并贯穿多个油层，是指导水平井分流压裂技术的选井选层，提高压裂效果的关键技术。图8表2参2。     

用高梯度磁场净化轧钢废水

通过用高梯度磁场处理热轧厂废水的试验,得到了在试验条件下浊度(水中不溶物的含量)和铁的去除率,确定了最佳净化条件.在此条件下,能够有效去除废水中的不溶物和铁,经过处理的水质达到了工艺循环水的水质标准.     

磁场和库仑场对量子点中强耦合束缚极化子性质的影响

采用线性组合算符和幺正变换方法研究了磁场和库仑场对半导体量子点中强耦合极化子性质的影响.导出了强耦合束缚磁极化子的振动频率和基态能量与量子点的有效受限长度、库仑束缚势、磁场的回旋共振频率和电子-声子耦合强度的变化关系.数值计算结果表明:强耦合束缚磁极化子的振动频率和基态能量随量子点的有效受限长度的减小而迅速增大,随磁场的回旋共振频率的增加而增大.基态能量随电子-声子耦合强度和库仑束缚势的增加而减少.     

固体超强酸S_2O_8~(2-)/SnO_2-SiO_2催化合成环己酮1,2-丙二醇缩酮

采用沉淀-浸渍法制备了固体超强酸S2O28-/SnO2-SiO2,以它为催化剂催化环己酮和1,2-丙二醇合成了环己酮1,2-丙二醇缩酮;考察了带水剂种类及用量、酮醇摩尔比、催化剂用量、反应时间对产品收率的影响,并用正交实验对反应条件进行了优化。实验结果表明,适宜的反应条件为:n(环己酮)∶n(1,2-丙二醇)=1∶1.6、催化剂用量为反应物料总质量的2.0%、带水剂环己烷用量5.0mL、反应时间50min。在此条件下,环己酮1,2-丙二醇缩酮收率达到91.47%;催化剂的稳定性良好,在重复使用5次后环己酮1,2-丙二醇缩酮收率为82.20%,活性下降的主要原因为催化剂表面积碳和吸附了有机物;经傅里叶变换红外光谱和气相色谱质谱分析表明,产物为环己酮1,2-丙二醇缩酮,纯度为100%。     

WO3/CeO2/YSZ nanocomposite as a potential catalyst for methanol reforming

A WO₃/CeO₂/YSZ nanocomposite material [W/Zr nominal atomic ratio = 0.025, Ce/Zr nominal atomic ratio = 0.020] was prepared by wet impregnation and characterized by means of X-ray photoelectron and diffuse reflectance infrared Fourier transform spectroscopic techniques, X-ray diffraction and thermal analysis.Both tungsten and cerium oxides are significantly reduced at the interface with YSZ: Ce(III), in particular, seems to be the prevailing species.The interaction of the WO₃/CeO₂/YSZ nanopowder with pyridine and CO₂ allowed to investigate the acidic/basic sites. Weak contributions at 1602, 1625 and 1647 cm⁻¹ suggest the presence of Lewis and Brønsted acidic sites, whereas basic sites are not evidenced by the interaction with carbon dioxide. The presence of tungsten oxide causes the decrement of the acidic/basic sites, as indicated by the comparison with the results obtained on the CeO₂/YSZ support. Consistently, the interaction with methanol is mainly molecular.The oxidation of methanol was investigated both in the absence and in the presence of water. In the last case carbon dioxide starts forming from room temperature.