Electrochemical characteristics of heme proteins in hydroxyethylcellulose film

A stable film made from hydroxyethylcellulose (HEC) on pyrolytic graphite (PG) electrode was employed for incorporating hemoglobin (Hb), myoglobin (Mb) and horseradish peroxidase (HRP), and the electrochemical characteristics of the proteins were studied correspondingly. Experimental results revealed that HEC film could greatly accelerate electron transfer between the proteins and electrode, and the proteins showed a thin layer electrochemical behavior in the film. Moreover, all the proteins in the film exhibited good catalytic activity towards the reduction of hydrogen peroxide (H₂O₂) in the low H₂O₂ concentration range. In the high concentration range, H₂O₂ would exhibit toxicity effect on the proteins. The electrochemical properties and electrocatalytic abilities of the three heme proteins in HEC film have been compared, and the optimal conditions for H₂O₂ biosensor fabrication have been obtained.     

ModDRE: A program to model deepwater-reservoir elements using geomorphic and stratigraphic constraints

In deepwater-reservoir modeling, the proper representation of the spatial distribution of architectural elements is important to account for pore-volume distribution and the connectivity of reservoir sand bodies. This is especially critical for rock and fluid-volume estimates, reservoir-performance predictions, and development-well planning.A new integrated stochastic reservoir-modeling approach (ModDRE—Modeling Deepwater Reservoir Elements) accounts for geomorphic and stratigraphic controls to generate the deepwater-reservoir architecture. Information on stratal-package evolution and sediment provenance can be integrated into the reservoir-modeling process. A slope-area analytical approach is implemented to account for topographical constraints on channel and sheet-form reservoir architectures and their distribution. Inferred sediment–source statistics and architectural-element variability (from seismic, outcrop, and stratigraphic studies) associated with relative changes in sea level can also be used to constrain the deepwater-reservoir-element statistics. Based on these geomorphic and stratigraphic constraints, deepwater-reservoir elements (channels, lobes) are built into the model sequentially (in stratigraphic order).Integration of realistic geological and engineering attributes into deepwater-reservoir models is vital for optimal reservoir management. This approach is unique in that it is more directly constrained to geomorphic and stratigraphic parameters than traditional object- or surface-based techniques for stochastic deepwater-reservoir modeling.     

在酸性介质中N-H伪酸Mannich反应机理的量子化学研究

用量子化学中的ＳＣＦ－ＭＯＡＭ１方法，全优化计算了以苯并唑酮为伪酸组分的（Ｎ－Ｈ酸）Ｍａｎｎｉｃｈ反应的反应物、过渡态和产物络合物的分子几何构型、电子结构和生成热。根据计算所得各反应的活化能，提出了该反应在酸性介质中的机理，即甲醛首先与苯并唑酮作用，其产物再与二甲胺作用生成Ｍａｎｎｉｃｈ碱，并就其缘由进行了讨论。     

弹丸外弹道优化设计初始点的选取

在弹丸外弹道优化设计中,需对优化设计变量赋于初始值.初始值选取得如何,对整个优化计算所耗机时、迭代点收敛到哪个极值点上等等,影响很大.该文对初始值的选取原则、选取方法等作了讨论,所得结果也可作为对弹丸主要结构参数选优的预估.     

几种新型的光电器件

描述用ＳＯＩ技术制造的光耦合ＭＯＳ继电器和多量子阱长波和红外探测器，以及集成异质结晶体管和激光二管于一体的高增益，高灵敏的光电子开关器件，文中着重介绍这些器件的结构，制造工和器件特性，并对其进行了讨论。     

An approximate method for evaluating hypersingular integrals

This paper describes a new method for direct numerical evaluation of multidimensional hypersingular integrals assigned on smooth curves and surfaces. These integrals arise when the boundary integral equations are used to solve problems of mechanics, electrodynamics, aerodynamics, etc. The hypersingular integrals are considered, in the sense of Hadamard, as finite parts. The main advantage of the proposed method is the numerical computation of the hypersingular integrals by the direct application of the developed cubature formulas, thus requiring little analytical pre-work. The method is not restricted to the type of problem however and may be easily applied to any hypersingular integrals. The convergence of the proposed technique has been proved and error estimates are given. An illustrative example demonstrates the accuracy and efficiency of the method.     

Theoretical hardness of the cubic BC2N

Vickers hardness of the cubic BC₂N has been investigated using the microscopic hardness model, in which the parameters have been obtained using first principles calculations. Ionicities of the chemical bonds in the cubic BC₂N depend on their surrounding chemical environments, which are included in the hardness calculations of the cubic BC₂N using the population ionicity scale. For the four selected configurations of the cubic BC₂N, the theoretical Vickers hardness has been found to lie between 70 and 72 GPa, consistent with the experimental value of 76 GPa. According to our calculations, it should be the cubic BC₂N that ranks second among the superhard materials instead of the cubic BN.     

Influence of phosphorus element on direct laser sintering of multicomponent Cu-based metal powder

This article presents a detailed investigation on the influence of the phosphorus element upon the laser sintering of a multicomponent Cu-based metal powder system consisting of Cu, Cu-10Sn, and Cu-8.4P. Powder systems containing 0, 10, 15, and 20 wt pct CuP were sintered in atmosphere at room temperature using the following optimal processing parameters: laser power of 350 W, scan speed of 0.04 m/s, scan line spacing of 0.15 mm, and layer thickness of 0.25 mm. It was found that the relative density of the sintered sample with 15 wt pct CuP increased by 24,4 pct as compared with the sample without phosphorus addition. A further increase in the CuP content (≥20 wt pct), however, resulted in a poor densification with a serious delamination. The exact metallurgical roles of the phosphorus element in the laser sintering process were addressed as follows. First, the phosphorus could prevent the sintering system from oxidation by forming CuPO₃, thereby improving the wetting characteristics and the sintering kinetics. Second, the phosphorus could decrease the surface tension of molten materials, leading to a successive transition from highly discontinuous sintered tracks to fairly coherent ones with increasing the phosphorus content. Third, the phosphorus could lower the melt viscosity, thereby improving the microstructural homogeneity of the laser-sintered samples.