Synthesis,structure, and adsorption properties of a three-dimensional porous yttrium–organic coordination network

Deprotonation of 4,4′-biphenyldicarboxylic acid (H₂BPDC) with triethylamine followed by the copolymerization with Y(III) in N,N-dimethylformamide (DMF) at room temperature yields a new three-dimensional (3-D) porous metal–organic coordination network, [Y₂(BPDC)₃(DMF)₂(H₂O)₂]_n · (DMF)_n · (H₂O)_n (1). Compound 1 (C_24.50H₁₉N_1.50O₉Y) crystallizes in the triclinic P-1 space group (a = 8.220 (2), b = 13.998 (4), c = 14.212 (4) Å, α = 111.058 (5)°, β = 90.187 (5)°, γ = 94.318 (5)°, V = 1520.9 (7) ų, and Z = 2). X-ray crystallography reveals that 1 consists of a 3-D framework contained open 1-D channels with the dimension of 5 × 10 Å along the crystallographic a axis. The adsorption measurements show that compound 1 can adsorb N₂, Ar and CO₂ into its pores. The adsorption isotherms for MeOH and H₂O were also measured.     

Influence of polymer on cement hydration in SBR-modified cement pastes

The influence of styrene-butadiene rubber (SBR) latex on cement hydrates Ca(OH)₂, ettringite, C₄AH₁₃ and C-S-H gel and the degree of cement hydration is studied by means of several measure methods. The results of DSC and XRD show that the Ca(OH)₂ content in wet-cured SBR-modified cement pastes increases with polymer-cement ratio (P/C) and reaches a maximum when P/C is 5%, 10% and 10% for the pastes hydrated for 3 d, 7 d and 28 d, respectively. With wet cure, appropriate addition of SBR promotes the hydration of cement, while the effect of SBR on the content of Ca(OH)₂ and the degree of cement hydration is not remarkable in mixed-cured SBR-modified cement pastes. XRD results illustrate that SBR accelerates the reaction of calcium aluminate with gypsum, and thus enhances the formation and stability of the ettringite and inhibits the formation of C₄AH₁₃. The structure of aluminum-oxide and silicon-oxide polyhedron is characterized by ²⁷Al and ²⁹Si solid state NMR spectrum method, which shows that tetrahedron and octahedron are the main forms of aluminum-oxide polyhedrons in SBR-modified cement pastes. There are only [SiO₄]⁴⁻ tetrahedron monomer and dimer in the modified pastes hydrated for 3 d, but there appears three-tetrahedron polymer in the modified pastes hydrated for 28 d. The effect of low SBR dosage on the structure of aluminum-oxide and silicon-oxide polyhedron is slight. However, the combination of Al³⁺ with [SiO₄]⁴⁻ is restrained when P/C is above 15%, and the structure of Al³⁺ is changed obviously. Meantime, the polymerization of the [SiO₄]⁴⁻ tetrahedron in C-S-H gel is controlled.     

基于自记忆原理的深基坑位移预测方法

传统灰色GM(1,1)预测模型对非负递增时间序列有较好的预测精度,但对波动幅度较大的时间序列预测精度较低。为了提高预测精度,本文在趋势曲线模型和自记忆理论的基础上,建立趋势曲线-自记忆组合预测模型,将该模型应用于深基坑位移预测中,并与灰色GM(1,1)预测模型和趋势曲线预测模型比较,该模型具有较高的预测精度。     

高铁酸钾去除饮用水源中盐酸四环素试验研究

利用提纯后的次氯酸钠溶液、硝酸铁、氢氧化钾制备高铁酸钾。并采用高铁酸钾氧化去除水中盐酸四环素（TC）,初步探讨了高铁酸钾去除TC的效果,研究了高铁酸钾投加量、pH值、氧化时间等对去除效率的影响。结果表明,高铁酸钾可以有效快速地去除水中的TC,在一定范围内,高铁酸钾投加越多,TC去除率越高,反应越快。pH值对反应影响较大,最优pH值范围为9～10。降解反应主要发生在前60S,在之后的10-20min内高铁酸钾与TC持续反应,TC得到进一步的降解。当高铁酸钾与TC摩尔比为1：1和1：5时,反应60S后的TC去除率约为100％。但反应液TOC下降幅度不大,说明大部分的TC仅转化为中间产物,未得到彻底矿化。     

溴酸根在紫外和氯消毒联用工艺中的形成

以H2O-Br--Cl2/NH2Cl/ClO2为研究对象,考查UV作用下BrO3-产生的情况。结果表明：原水和去离子水背景下,Cl2/UVC联用可以氧化部分的Br-生成BrO3-;NH3可以有效的抑制BrO3-生成,并且NH2Cl/UVC作用时不生成BrO3-;ClO2/UV体系产生溴酸根能力明显弱于Cl2/UV;ClO2/UVC产生BrO3-的量高于ClO2/UVA。酸性条件同时促进BrO3-的产生和ClO2的分解,碱性条件正好相反。     

弦支穹顶结构施工技术及施工全过程模拟方法

弦支穹顶结构由于拉索的存在,其施工阶段的力学性能与其使用阶段不尽相同,其受力状态可能更为不利。通过系统研究弦支穹顶结构实际工程的施工工艺,提出包括施工顺序、预应力张拉施加方式、临时支撑系统和预应力张拉方式等4个关键施工参数,研究了弦支穹项结构张拉环索受力机理,并根据此张拉机理和所提关键施工参数建立了有限元分析的时变模型,编制了相应的计算程序。算例分析表明,应用该计算模型和方法,可以对弦支穹顶结构的施工过程进行精确控制,具有较强的适用性。     

配置高强钢筋的混凝土梁裂缝试验研究

采用两点对称集中的同步分级加载方式,对8根配置500MPa钢筋和4根配置400MPa细晶钢筋的混凝土梁进行静力加载试验,观测试件的裂缝发展过程,了解此类构件的裂缝特点,为工程中推广应用500MPa钢筋和400MPa细晶钢筋提供试验依据。试验结果表明,配置500MPa钢筋和400MPa细晶钢筋的受弯构件裂缝发展规律与普通钢筋混凝土受弯构件基本相同,但在正常使用状态下,按照现行混凝土结构设计规范对此类构件进行裂缝宽度验算,计算值均大于试验值。同时,结合其它67根配置高强钢筋的混凝土梁试验数据,评估了现行混凝土结构设计规范裂缝宽度公式的适用性,并在该规范的计算模式基础上,提出平均裂缝间距及短期最大裂缝宽度计算的修正公式,修正公式的计算结果与试验结果符合较好。     

几种特殊矩阵的Pareto特征值问题

Pareto特征值问题是定义在正卦限上一类锥约束问题,在许多领域有着深厚的背景。将讨论Pareto特征值的一些理论性质,包括给定矩阵Pareto特征值范围及个数上界。引进了一类新矩阵,讨论并给出它的部分理论性质,可直接计算其最大Pareto特征值。     

邻溴苯酚在高温碱水中的脱溴和降解动力学研究

利用间歇反应器研究了邻溴苯酚在250℃～350℃高温液态水中的降解行为,探讨了脱溴效率的影响因素和降解反应动力学。结果表明：升高温度和添加碱性物质能显著提高脱溴率;邻溴苯酚在0.1mol/L碳酸钠溶液中的降解符合表观一级反应动力学规律。GC-MS分析结果表明邻溴苯酚在高温碱水中降解的主要产物为苯酚和邻苯二酚,并由此推测出降解途径。     

低层建筑抗风设计方法比较与研究

土木工程设计中,最有影响和最易引起工程结构失败甚至破坏的首推风荷载.最近几年风灾严重,尤其是风灾导致的低层建筑损失更是惨重.而国际上发达国家的风荷载规范则在不断变化之中,尤其是对轻型钢结构的抗风设计.因此本文有必要对各国低层轻型钢结构抗风设计方法进行研究.本文分别对中国、日本、美国等国家关于抗风设计方法进行比较,并针对风压系数计算一个实例,最后与风洞试验结果进行对照,对中国抗风设计方法进行研究与探讨.