Rational Designs for Lithium-Sulfur Batteries with Low Electrolyte/Sulfur Ratio

Lithium-sulfur batteries (LSBs) are considered a promising next-generation energy storage device owing to their high theoretical energy density. However, their overall performance is limited by several critical issues such as lithium polysulfide (PS) shuttles, low sulfur utilization, and unstable Li metal anodes. Despite recent huge progress, the electrolyte/sulfur ratio (E/S) used is usually very high (≥20 µL mg⁻¹), which greatly reduces the practical energy density of devices. To push forward LSBs from the lab to the industry, considerable attention is devoted to reducing E/S while ensuring the electrochemical performance. To date, however, few reviews have comprehensively elucidated the possible strategies to achieve that purpose. In this review, recent advances in low E/S cathodes and anodes based on the issues resulting from low E/S and the corresponding solutions are summarized. These will be beneficial for a systematic understanding of the rational design ideas and research trends of low E/S LSBs. In particular, three strategies are proposed for cathodes: preventing PS formation/aggregation to avoid inadequate dissolution, designing multifunctional macroporous networks to address incomplete infiltration, and utilizing an imprison strategy to relieve the adsorption dependence on specific surface area. Finally, the challenges and future prospects for low E/S LSBs are discussed.     

Probing the degenerate pattern growth of {100}<011> orientation in a directionally solidified Al-4.5 wt% Cu alloy

Degenerate pattern is a seemingly disordered morphology but it exhibits the inherently ordered crystal connected with tip-splitting and limited stability which makes it difficult to observe in the metallic system. Here we employ (100)[011] orientated planar-front seeds using directional solidification and reveal the fundamental origins of the degenerate pattern growth in an Al-4.5 wt% Cu alloy. We find that the spacing of the tip-splitting (λ) in the degenerate of the alloys followed a power law, λ∝V^−0.5, and the frequency (f) of the splitting was related to the growth velocity (V) by ƒ∝V^1.5. The dimensionless growth direction (θ/θ₀) increased monotonously and approached 0.6 with faster velocity, attributed to its anisotropy in the interface kinetics. Once growth velocity exceeded a threshold, two types of pattern transitions from degenerate to regular dendrites were proposed. One of them exhibited a random and chaotic mode and the other underwent a rotation in growth direction.     

Geometry of 3D MAT and its application to moulding surfaces

This paper investigates the differential geometry of 3D MAT (medial axis transform) using the moving frame and differential form. After constructing the mapping relation and moving frames around both the MA (medial axis) point and the associated boundary points, various curves are defined to serve as carriers for the study. Based on analysis of the infinitesimal translation and rotation of the moving frames, the relations of distance differentials, rotation vectors and differential invariants are derived. Furthermore, a special case in the 3D MAT, the normal form, is defined for the moulding surfaces, where the 3D problem can be converted into a 2D one.     

以用户为中心的可见光通信协作传输中训练资源分配算法

以用户为中心的可见光通信协作传输是近年来出现的新架构,这导致虚拟小区之间出现重叠。为避免导频污染问题,每个虚拟小区中的光接入点(AP)或者虚拟小区中选择相同AP的用户发送的训练序列应该是正交的。针对可见光通信中以用户为中心的协作网络,研究训练资源的正交分配问题,提出了一种新的导频分配算法,联合导频分配和用户选择问题,以期最大限度地增加虚拟小区内可被接入的用户数。分析和仿真结果表明,该导频分配方案可以有效改善导频污染问题,提高训练资源利用率,并且相比已有的导频分配方案,性能有所改进。     

Ultrasmall rhodium nanoclusters anchored on nitrogen-doped carbon nanotubes with embedded nickel nanoparticles as magnetically recyclable catalysts for efficient ammonia-borane hydrolysis

Facile yet efficient synthesis of high-performance nanocatalysts for hydrogen evolution from ammonia-borane (AB) hydrolysis is paramount. Here, we reported a novel hybrid nanocatalyst comprised of Rh nanoclusters (1.56 nm in diameters) anchored on nitrogen (N)-doped carbon nanotubes with embedded Ni nanoparticles (Ni@NCNTs), which was fabricated through adsorption of Rh ions on Ni@NCNTs. The achieved hybrid of Rh/Ni@NCNTs displayed excellent catalytic property (Turnover frequency: 959 min⁻¹) toward AB hydrolysis, higher than many prior developed Rh-based catalysts. Note that this hybrid could be reused for at least nine runs with complete AB conversion to hydrogen. Rh nanoclusters with small size exhibiting high atom utilization and the synergetic effect between Ni and Rh are responsible for the excellent catalytic property of Rh/Ni@NCNTs toward AB hydrolysis. This work highlights the importance of utilization of magnetically recyclable Ni@NCNTs as support and synergetic component for efficient hydrolysis of AB.     

Strength and chemical resistance of mortars containing brick manufacturing clays subjected to different treatments

This paper presents the results of an investigation of the properties of mortar in which a calcined clay was employed as a pozzolan. Mortars were prepared using either heat treated clay or ground waste clay bricks (from the same clay subjected to 1000 °C calcining) as a pozzolanic partial replacement for cement at replacement levels of 10%, 20% and 30%. The compressive strengths of the mortars were monitored up to 90 days and the resistance to sodium sulphate solution and synthetic seawater was monitored up to 300 days. The specimens were also monitored for weight changes. Partially replacing cement by ground brick or heat-treated brick clay gives early strengths that are lower than that of the control. At 90 days, however, the strengths are the same as or are greater than that of the control. Heat-treated clay is effective in reducing expansion during exposure of the mortar to sulphate solution and synthetic seawater. The rapidly cooled clay gives better performance, in terms of strength development and resistance to harmful solutions, than the slow cooled clay.     

专用超大规模集成电路在LED显示系统中的应用

自1976年蒙特利尔奥运会采用了第一块黑白视频显示屏以来，各种大屏幕特别是LED显示屏得到了迅猛发展，在现代信息社会中更是随处可见。在这些显示系统中，应用了大量的不同种类的集成电路作为驱动芯片。本文叙述了运用于LED显示系统中的超大规模集成电路的强大功能。     

电视节目包装中的文字设计艺术

文字是电视节目包装中的重要元素之一,除了传达信息的基本功能外,经常起到决定整体效果的关键作用。节目包装文字设计应突出本台文化和本土文化,文字的设计必须与节目相匹配,形成统一整体。     

基于神经网络的特征分析在烟叶分级中的应用。

通过数字图像技术可以自动提取烟叶的颜色和形状特征,而不同特征值对分部位、颜色和等级的决定程度不同,文章结合广义回归神经网络定性分析各种不同特征对部位或颜色分级的影响,分别得到对分部位、颜色和等级有决定影响的特征量,通过建立不同神经网络得到最终等级。