Crosslinked quaternized poly(arylene ether sulfone) copolymer membrane applied in an electric double-layer capacitor for high energy density

The low energy density of supercapacitors, especially supercapacitors based on aqueous electrolytes, is the main factor limiting their application, and the energy density is closely related to the operating potential window of the supercapacitor. The polymer electrolyte is the main contributor to the safe operation and good ion conductivity of the supercapacitor. In this study, a crosslinked quaternized poly(arylene ether sulfone) (PAES) membrane was prepared via crosslinking during membrane formation with a thermal-only treatment and applied in an electric double-layer capacitor (EDLC). The pre-prepared PAES membrane formed a polymer electrolyte with 1 mol/L Li₂SO₄ and was then fabricated into an EDLC single cell. The properties of both the membrane and ELDC were investigated. The preferred cPAES-N-0.2 polymer electrolyte showed an ionic conductivity of 1.18 mS/cm. The optimized EDLC exhibited a single-electrode gravimetric capacitance of 104.92 F/g at a current density of 1.0 A/g and a high operating potential window (1.5 V); it, thereby, achieved a high energy density of 8.20 W h/kg. The EDLC also exhibited excellent cycling properties over 3000 charge–discharge cycles. The crosslinked structures promoted the tensile strength and thermal stability of the PAES membranes; this was accompanied by a slight decrease in the ionic conductivity. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47759.     

Annealing and doping-dependent magnetoresistance in single layer poly(3-hexyl-thiophene) organic semiconductor device

We compare the current density–voltage (J–V) and magnetoconductance (MC) response of a poly(3-hexyl-thiophene) (P3HT) device (Au/P3HT(350 nm)/Al) before and after annealing above the glass transition temperature of 150 °C under vacuum. There is a decrease of more than 3 orders of magnitude in current density due to an increase of the charge injection barriers after de-doping through annealing. An increase, approaching 1 order of magnitude, in the negative MC response after annealing can be explained by a shift in the Fermi level due to de-doping, according to the bipolaron mechanism. We successfully tune the charge injection barrier through re-doping by photo-oxidation. This leads to the charge injection and transport transitioning from unipolar to ambipolar, as the bias increases, and we model the MC response using a combination of bipolaron and triplet-polaron interaction mechanisms.     

Fabrication and frequency response of a complex ultrasonic transducer for multilayer evaluation

To characterize the thickness of a corrosive fluid system's coated facilities, such as pipes, tubes, tanks, and structural members, a complex ultrasonic transducer capable of measuring multilayered parts was fabricated and the time and frequency responses were evaluated. The target transducer was constructed with two active dual elements made from tape-cast PbNb₂O₆ sheets and an additional thin-film active element made from sol–gel spin-coated Pb(Zr_0.52Ti_0.48)O₃ films. After adjusting the properties of each active element, a complex transducer was assembled after matching the impedance of each element and considering the minimal interference between the active layers. The impulse response of the assembled complex transducer shows excellent characteristics. Moreover, the assembled transducer's capability of accurately measuring the thickness assures that it can be directly applied to related industries.     

基于显微视觉的宏/微双重驱动微动台的自动标定

提出了基于压电技术的微操作系统的自动标定方法,采用混合式步进电机直接驱动的宏动平台,实现系统大行程宏动定位,安装在宏动平台上的压电陶瓷驱动的微动平台和精密光栅,实现亚微米级的分辨率和定位精度,通过以上两部分实现定位机构的全闭环反馈控制,采用显微视觉反馈获取微动台操作器在图像中的位置信息进行标定。实验结果表明:系统的动态和稳定性能良好,自动标定运算速度快,运行速度达到11 frame/s,实现了对系统的精确标定,标定精度达到0.1μm。     

Modelling of heat transfer in an infiltrated granular bed in view of the difference of phase temperatures

Physically substantiated boundary conditions for problems of heat transfer in infiltrated granular beds based on the two-temperature model which allow for the absence of interphase heat transfer on boundaries are formulated. It is shown that classical Dankwerts conditions would be applicable for gas. The problem of porous cooling at the boundary conditions of the 2nd and 3rd kind on the outer boundary is solved in a new formulation.     

Cooperative Effect Radiation Loss of Optical Pump Solid Laser

1 Introduction For increasing the output energy of laser, the pumping power must be enhanced. But the cooperative effect will arise and cause spontaneous radiation light in laser medium sample when the pumping power is high e- nough without the resonator. The spontaneous radiation light is coherent light between laser and fluorescent. It will compete the upper energy level population with ex- cited radiation, and the loss increase. In solid laser medium, such as Nd∶YAG, the Nd ion densityi…     

利用Hilbert-Huang变换提取地震信号瞬时参数

 通过Hilbert变换求取的信号瞬时参数并非对任何信号都有物理意义，此法通常要求被分析信号是窄带或平稳的，而且对噪声很敏感。而实际地震信号既非平稳又含有噪声，若在实际应用中不加考虑地对地震信号进行Hilbert变换以求取瞬时参数，这种情况下求取的瞬时参数将缺乏物理意义甚至失真。Hilbert-Huang变换是一种新的分析非平稳非线性信号的方法，它先将信号进行经验模态分解（EMD），形成有限个固有模态函数（IMF）之和，再对固有模态函数作Hilbert变换求取时频谱，求取的时频谱在时域和频域都具有较高的分辨率。本文将Hilbert-Huang变换应用于地震瞬时参数的提取，实例表明，对地震剖面做EMD可以得到不同时间尺度上的特征，Hilbert谱比传统的时频谱在时间和频率域上的分辨率都要高，强反射层在第1阶IMF瞬时频率剖面上比原瞬时频率剖面上表现得更为明显。     

Fabrication of the supersaturated solid solution of carbon in copper by mechanical alloying

Mechanical alloying of powder mixtures of copper and graphite was performed in a high energy ball mill. The as-milled powder was characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy, respectively. These investigations indicated that high energy ball milling could largely extend the solid solubility of carbon in copper and the 4 wt.% C was dissolved in Cu. It was ascribed to the decrease of the grain size and the increase of the lattice strain. Nanostructures, amorphous carbon and lamellar graphite were observed in the as-milled powder after milling for 24 h.     

Job-shop Scheduling问题的研究

本文研究了Job-Shop类型矛性制造系统的调度问题，建立了数学模型，并用遗传算法进行求解。实践表明，该算法具有较好的实用性和可行性。