Reduction of residual stress in montmorillonite/epoxy compounds

An epoxy resin was cured while in intimate contact with small amounts of epoxyphilic montmorillonites. It was determined that cured epoxy exists within the montmorillonite interlayer by the observation of very high interlayer spacings, even greater than 8 nm, Generally, epoxy compounds containing montmorillonites that had been swollen in the curing agent prior to curing exhibited larger interlayer spacings, especially among the non-dispersed montmorillonite layers. The maximum observed residual stress was reduced by greater than 50% in the epoxyphilic montmorillonite/epoxy compounds over that of the pure epoxy. The epoxyphilic montmorillonite/epoxy compounds generally exhibited higher values of glass transition temperature, flexural modulus, and ultimate flexural strength than the pure epoxy. The tyramine-montmorillonite compounds typically had the highest values overall.     

Synthesis and characterization of antioxidants and detergent dispersant based on some polyisobutylene copolymers

Polyisobutylene succinic anhydride-urea/polyamines (PIBSA) copolymers were synthesized as potential antioxidants and detergent dispersant agents for lubricating oils samples (SAE-30). Homogeneity, thermal stability and dispersancy of the solutions were determined. Fully soluble oil compounds that are thermally stable up to 250 °C were achieved. The oxidation stability of lube oil samples in the presence of four designed PIBSA additives (varying in the number of amine groups) was determined for a time period of up to 72 hours. The dependence of the additive efficiency on its concentration was studied to achieve maximum stability. Some PIBSA additives at concentration 3.0 · 10⁴ ppm exhibit the best results. Dispersivity values were measured at predetermined oxidation times. The results proved reliable dispersion capability as the nitrogen content of the additive is increased, i.e. the increase in the basic character of the additive leads to the increase in the neutralization capability. Moreover, the designed PIBSA additives retain their efficiency after long oxidation times, confirming their role as multifunctional nitrogen containing polymeric additive. Electronic Publication     

Dissolution of calcite crystals in the presence of some metal ions

A constant composition method has been used for the study of the kinetics of calcium carbonate (calcite) dissolution in which the activities of ionic species in relatively undersaturated solutions are maintained constant. Over a range of relative undersaturation (0.032–0.158) the dissolution reaction appears to be controlled by a bulk diffusion process. The suggestion of a predominantly diffusion-controlled process was supported by the observed low activation energy (2.09 kcal mol^–1). The influence of a number of metal ions on the reaction rate has been investigated. The retardation effect of these additives has been attributed to the blocking of active sites by adsorption of metal ions at the crystal surfaces. Inhibition of dissolution by metal ions can be interpreted in terms of a Langmuir isotherm.     

Electrical properties of tri-n-butyl tin acrylate-methylmethacrylate copolymers

The copolymerization of tri-n-butyl tin acrylate (TBTA) with methylmethacrylate (MMA) has been investigated in dioxane. The composition of these copolymers was determined quantitatively by ¹H nuclear magnetic resonance (NMR) spectroscopy. The tin contents were estimated by gravimetric as well as thermogravimetric techniques (TGA). The reactivity ratio of such copolymers was estimated by application of the Kelen-Tudos method. The dielectric properties of the copolymers have been studied over a frequency range of 100–50 kHz at different temperatures from 20 to 70°C. The electrical conductivity for such copolymers was also measured. The results are interpreted in terms of the tin content of the copolymers.     

Finishing of glass-ionomer cement (SEM study)

A total of 12 glass-ionomer cement specimens were utilized in the present study. The specimens were divided into two equal groups. The first group was used after 10 minutes from setting, while the second was utilized after 24 hours from setting. Each group was divided into three equal subgroups (2 specimens each). The first subgroups were finished under wet condition (wet finished). The second subgroups were dry finished. On the other hand, the third subgroups were kept undisturbed (as set) under mylar strips. The specimens surfaces were then examined by a Scanning Electron Microscope (SEM). It was found that, finishing of the specimens after 24 hours from setting demonstrated more acceptable surface topography either in wet or dry conditions than finishing after 10 minutes from setting. Moreover, the dry finished specimens displayed more acceptable surface topography than the wet finished specimens. On the other hand, the as set (undisturbed) specimens the most acceptable surface topography.     

Thickness-dependence of stoichiometry and microstructure characteristics in correlation with conductivity type of CdTe films

CdTe films were prepared by physical vapour deposition on a substrate at room temperature (RT) as well as on a cold (LT) one using low deposition rate. The thickness-dependence of stoichiometry revealed an abrupt decrease in the Cd/Te ratio as the thickness increases. Change of thickness did not affect the type of observed (111) crystallographic texture, only the degree of preferred orientation is enhanced as the film grows. The internal strain was negligible while the crystallite size increased rapidly at small thickness (up to 400 nm), and less thickness dependence was observed with further film growth. However, thickness dependence of lattice parameters showed a minimum and a maximum at approximately 300 nm in the case of RT and LT, respectively. The observed change in conductivity from n- to p-type and its vital correlation with the stoichiometry and structural characteristics were presented. Based on thickness dependence of stoichiometry and lattice parameters as well as the conductivity type, formation and annihilation of lattice defects were considered.     

Multi-User MIMO Mobile CDMA Uplink System Employing Turbo Coding and Joint Detection Through a Multipath Rayleigh Fading Channel

In this paper, a generalized multiple-input multiple-output (MIMO) antenna system that can be fitted to the uplink of a wireless communication system is considered for the general case of multi-user. At the transmitter, the information bits are Turbo coded, then interleaved and passed through a serial-to-parallel converter. The channel is assumed bad urban suffering from multipath Rayleigh fading resulting in inter-symbol and multiple access interferences (ISI and MAI). At the front-end of the receiver, a number of receiving antennas are used followed by a joint multi-user estimator based on the Minimum Mean Square Error Block Linear Equalizer (MMSE-BLE).Computer simulations demonstrate a significant performance improvement in both single user and multi-user cases.This paper depends in parts on that presented at the 11th European Wireless Conference, Cyprus, Nicosia, pp. 187–192, April 2005. Yasmine A. Fahmy was born in Guiza, Egypt, on June 4, 1976. She received the B.Sc., M.Sc. and Ph.D. degrees in Communication and Electronics engineering from Cairo University, Egypt on 1999, 2001 and 2005 respectively. She is presently an assistant professor at Cairo University, Egypt. Her current field of interest is wireless communication and channel estimation. Hebat-Allah M. Mourad received her B.Sc., M. Sc. and Ph.D. degrees in electrical communication engineering from Cairo University, Egypt, in 1983, 1987 and 1994 respectively. Since 1983, she has been with the Department of Electronics and Communications, Faculty of Engineering, Cairo University, and is currently associate professor there. Her research interests include optical fiber communications, mobile and satellite communications. Emad K. Al-Hussaini received his B.Sc degree in Electrical Communication Engineering from Ain-Shams University, Cairo, Egypt, in 1964 and his M.Sc and Ph.D. degrees from Cairo University, Giza, Egypt, in 1974 and 1977, respectively. From 1964 to 1970, he was with the General Egyptian Aeroorganization. Since 1970, he has been with the Department of Electronics and Communications, Faculty of Engineering, Cairo University, and is currently professor there. He was a research fellow at Imperial College, London, UK, and at the Moore School of Electrical Engineering, University of Pennsylvania, Philadelphia, PA, USA, in the academic years 1976/1977 and 1981/1982, respectively. In 1990, he received the Egyptian national encouragement award for outstanding engineering research. He has written several papers for technical international journals and conferences. His research interests include signal processing, fading channel communication, modulation, and cellular mobile radio systems. Dr Al-Hussaini is a senior member of IEEE. He is listed in Marquis Whos Who in the World and in the IBC (International Biographical Center, Cambridge) for outstanding people of the 20th century.     

Blast resistance of FRP composites and polymer strengthened concrete and masonry structures – A state-of-the-art review

Recent world events such as bombings in London, Madrid and Istanbul have highlighted the susceptibility of many civilian structures to terrorist attack. Explosives directed towards vulnerable structures may cause considerable damage and loss of life. As a result, there is now a desire to increase the blast resistance of many types of existing structures. This has led to experimental and finite element (FE) research in retrofitting concrete and masonry structures with fibre reinforced polymer (FRP) composites for blast protection. This paper presents a review of the publicly available literature and highlights areas where research is lacking.     

Optical,infrared and electrical conductivity of glasses in the TeO2-B2O3 system

Infrared (IR) and optical absorption spectra were measured in order to study the structure of some tellurite glasses containing boric oxide. The compositions (mol%) were (100-X) TeO₂,XB₂O₃ whereX=5, 10, 20, 25, 30. The optical spectra were measured at room temperature in the wavelength range 350–450 nm, and the results show that the fundamental absorption edge is a function of composition, with the optical absorption due to indirect transitions. The optical band gap increases with increasing B₂O₃ content. The validity of the Urbach rule was investigated. The IR results prove the distribution of the TeO₄ polyhedra which determines the network and the basic oscillations of the building units in the tellurite glasses. The IR results also prove the distribution of the boroxal group. The electrical conductivity was measured as a function of temperature in the temperature range (300–573 K). Both the conductivity and activation energy were found to be a function of added oxide type.     

Pyramid collaborative filtering technique for an intelligent autonomous guide agent

This article presents an autonomous guide agent that can observe a community of learners on the web, interpret the learners' inputs, and then assess their sharing. The goal of this agent is to find a reliable helper (tutor or other learner) to assist a learner in solving his task. Despite the growing number of Internet users, the ability to find helpers is still a challenging and important problem. Although helpers could have much useful information about courses to be taught, many learners fail to understand their presentations. For that, the agent must be able to deal autonomously with the following challenges: Do helpers have information that the learners need? Will helpers present information that learners can understand? And can we guarantee that these helpers will collaborate effectively with learners? We have developed a new filtering framework, called a pyramid collaborative filtering model, to whittle the number of helpers down to just one. We have proposed four levels for the pyramid. Moving from one level to another depends on three filtering techniques: domain model filtering, user model filtering, and credibility model filtering. A new technique is filtering according to helpers' credibilities. Our experiments show that this method greatly improves filtering effectiveness. © 2007 Wiley Periodicals, Inc. Int J Int Syst 22: 1065–1082, 2007.