Structure and Properties Characterization of Ceramic Coatings Produced on Steel Using a Combined Technique

STEEL is the most widely used material in engineering,but unfortunately,steel exhibits poor wear resistanceand obvious contact corrosion.For decades,researchersprepared coatings on steel to improve its properties;ceramic is one of these coatings.To obtain ceramiccoatings on steel,many researchers use techniques suchas plasma spraying,laser cladding,etc.,but some ofthem are too expensive,some of them have a deep heataffected zone in the substrate,and some of them cannot bond well with the subs…     

STUDY ON THE VARIATION MECHANISM OF CARBON CONTENT OF LIQUID IRON IN MELTING GASIFIER

This paper studied the changing principles of carbon content in direct reduction iron (DRI) and liquid iron in the COREX melting gasifier. Under the normal working conditions of experimental equipment, liquid nitrogen was poured into the melting gasifier from its tuyere to cool down quickly. And then seven cross sections were made to study the carburization reaction and its characteristics of the solid iron and the liquid iron, and also the reaction of carbon between the slag and the metal. According to the results, the influences of the thickness of the semi-coke layer and the temperature on the carbon content of liquid iron in the COREX melting gasifier were confirmed.     

基于时序特征的发电机转子故障诊断方法

提出了一种利用时序特征进行发电机转子的故障诊断方法.利用时间序列法中的AR或ARMA模型得到的脉冲传递函数的特点,并根据不同故障类别振动信号的格林函数变化的规律性,提出了利用格林函数的统计量特征作为故障诊断的特征参数进行故障诊断的方法.     

Nickel-Carnosine complex:A new carrier for enzymes immobilization by affinity adsorption

Immobilization is an effective method to promote the application of enzyme industry for improving the stability and realizing recovery of enzyme.To some extent,the performance of immobilized enzyme depends on the choice of carrier material.Therefore,the development of new carrier materials has been one of the key issues concerned by enzyme immobilization researchers.In this work,a novel organic-inorganic hybrid material,nickel-carnosine complex (NiCar),was synthesized for the first time by solvothermal method.The obtained NiCar exhibits spherical morphology,hierarchical porosity and abun-dant unsaturated coordination nickel ions,which provide excellent anchoring sites for the immobiliza-tion of proteins.His-tagged organophosphate-degrading enzyme (OpdA) and ω-transaminase (ω-TA)were used as model enzymes to evaluate the performance of NiCar as a carrier.By a simple adsorption process,the enzyme molecules can be fixed on the particles of NiCar,and the stability and reusability are significantly improved.The analysis of protein adsorption on NiCar verified that the affinity adsorp-tion between the imidazole functional group on the protein and the unsaturated coordination nickel ions on NiCar was the main force in the immobilization process,which provided an idea way for the develop-ment of new enzyme immobilization carriers.     

HZSM5分子筛膜复合二氧化锡对甲烷的气敏性能研究

采用液相氧化法制备二氧化锡纳米颗粒,并利用浸渍法制备Pd负载二氧化锡纳米材料,通过丝网印刷得到气敏传感膜并在其表面印刷分子筛层。基于动态气敏测试系统探究传感器对甲烷气体的灵敏度及其在CO和乙醇干扰气体下的选择性。研究结果表明,在Pd-SnO₂敏感层表面印刷Pd-HZSM5层后,传感器对甲烷的响应能力显著提高,并且在体积分数为5×10^-4的CO存在时,对甲烷的选择性也得到明显的提升。同样,在质量分数为2×10^-5乙醇的存在下,传感器对甲烷的响应也没有受到干扰。通过对分子筛进行表征和催化分析,发现Pd-HZSM5对CO的催化效率可达100%,使得CO在扩散过程中被催化氧化,这可能是印刷Pd-HZSM5分子筛膜从而提高传感器选择性的主要原因。同时研究还表明,在敏感层表面印刷分子筛层并不会影响传感器的响应和恢复速率。     

基于氧化物冶金的微合金化研究

介绍了国内外氧化物冶金技术的进展情况;分析了微合金体系中各元素的协同及交互作用以及夹杂物、第二相粒子析出、演变对钢的相变、组织结构和性能的影响规律;阐述了冶炼、凝固过程中“有益”夹杂物析出的热力学、动力学研究现状,分析了夹杂物性质、尺寸、分布等对诱发晶内铁素体形核的影响;综述了热加工和焊接过程对组织演化、晶粒细化、晶内铁素体优先析出及提高母材钢和焊接热影响区强韧性机制。总结了氧化物冶金研究工作进展及存在的问题,结合课题组研究的成果,提出了基于氧化物冶金的微合金化思想并比较了其与传统微合金化的异同;展望了基于氧化物冶金的微合金化理论方面需要进一步开展的研究工作。      

In-situ generation of platinum nanoparticles on LaCoO3 matrix for soot oxidation

The LaCo_0.94Pt_0.06O₃ catalyst is reduced under 5% H₂/Ar at different temperatures to get Pt/LaCoO₃ with high catalytic activity for soot oxidation. Transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller method (BET), X-ray photoelectron spectroscopy (XPS), H₂-temperature programmed reduction (H₂-TPR), O₂-temperature programmed desorption (O₂-TPD) and thermogravimetric analysis (TGA) were used to study the physicochemical properties of the catalyst. SEM and TEM results indicate that Pt nanoparticles (<10 nm) are grown homogeneously on the surface of the LaCoO₃ matrix after in-situ reduction. XRD shows that the reduced catalyst has a high symmetrical structure. TGA results indicate that all reduced catalysts exhibit an excellent activity, especially the catalyst reduced at 350 °C (T₁₀ = 338 °C, T₅₀ = 393 °C, T₉₀ = 427 °C). And perovskite is the primary active component. According to XPS study, the high symmetrical structure benefits the mobility of oxygen vacancy, and Pt nanoparticles induce the oxygen vacancy to move to its adjacent situation, resulting in more adsorbed oxygen on the surface of the reduced catalyst and increasing the activity. The possible reaction principle is also proposed.     

含Sr、Y和Nd的AM60B镁合金浇注与性能研究

为了提高镁合金的抗高温蠕变性能,把元素Sr和稀土元素Y、Nd加入到AM60B中,采用覆盖剂保护熔炼制备较为致密的AM60B及AM60B (Sr,Y,Nd)合金试样.Sr和稀土元素Y、Nd使AM60B的室温力学性能得到改善.     

半固态A356合金微观组织特征对充型能力的影响

采用电磁搅拌法制备了具有不同微观组织特征的半固态A356合金浆料,用图像分析软件对浇注前浆料金相试样的初生相微观组织特征进行了测定,利用间接挤压铸造方法铸造阿基米德螺旋线试样,以挤压成形后的螺旋线试样长度衡量充型能力,通过多元回归,建立了半固态A356合金初生相微观组织特征与充型长度之间的数学表达式。结果表明:半固态浆料充型能力不仅与初生相微观组织特征参数有关,微观组织特征参数的交互作用对充型能力的影响也较大。利用该表达式可以对半固态浆料充型能力进行预测,进而指导半固态浆料制备参数设计、间接挤压铸造工艺设计和缺陷预测。     

基于LM算法的宽板V型自由弯曲参数的实时识别

在弯曲成形智能化控制过程的4个要素中，材料性能参数的实时识别占有极其重要的地位。为提高实时识别的精度和效率，根据宽板V型自由弯曲成形的特点，建立了宽板V型自由弯曲成形智能化控制过程材料性能参数实时识别的LM神经网络模型。训练结果表明，与改进的BP网络模型比较，LM网络模型的收敛精度和收敛速度均有明显的提高，为实现弯曲成形过程的智能化控制奠定了基础。