Electrospray deposition and characterization of cobalt oxide thin films

Cobalt oxide thin films were fabricated by means of electrospray deposition. The obtained films were characterized by Raman spectroscopy, X-ray diffraction and Scanning electron microscopy. The solution that was used gave the Co₃O₄ phase at different growth temperatures. The best granular surfaces were obtained at 250 °C as verified by all characterization techniques, while flaky surfaces were obtained at higher temperatures. The surface morphology is mostly granular except for high temperatures where the cobalt oxide is formed as flakes instead of grains.     

Syntheses and characterizations of two-dimensional polymers based on tetraimidazole tetraphenylethylene ligand with aggregation-induced emission property

Two new coordination polymers [Co(TIPE)(H₂O)₂]·Hbtc·CH₃CN·3H₂O (1) and [Cd(TIPE)_0.5(m-bdc)(H₂O)]·CH₃OH·H₂O (2) (TIPE = tetra(3-imidazoylphenyl)ethylene, H₃btc = 1,3,5-benzenetricarboxylate, m-H₂bdc = 1,3-benzenedicarboxylate) have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, elemental analysis, IR, TGA, and PXRD. Furthermore, the luminescent properties of complexes 1, 2 and TIPE ligand have also been investigated in the solid at room temperature.     

离子液体/盐双水相萃取分离锁阳中熊果酸

利用1-丁基-3-甲基咪唑氯([Bmim]Cl)和磷酸氢二钾(KH2PO4)双水相体系萃取分离锁阳中熊果酸,首先对[Bmim]Cl质量分数、KH2PO4质量分数、熊果酸粗提取液质量分数、NaCl质量分数、pH进行单因素研究,确定双水相体系组成为质量分数25%[Bmim]Cl-21%KH2PO4。然后,利用Box-Benhnken Design实验,对黄酮粗提取液质量分数、pH、NaCl质量分数进行了优化,结果表明:粗提液质量分数8.5%、NaCl质量分数1%、pH=4.7,熊果酸萃取率可达97.85%,与预测值98.3%接近。说明该优化工艺具有可行性。     

水菖蒲黄总酮的提取工艺及稳定性

在单因素试验的基础上,利用响应面分析法优化水菖蒲总黄酮的提取条件,并考察其稳定性。结果表明,水菖蒲总黄酮的最佳提取工艺为:提取温度81℃,料液比1∶25g/mL,提取时间118min,乙醇浓度67%。在此条件下总黄酮提取率的实测值为5.17mg/g,理论值为5.20mg/g。稳定性试验表明:水菖蒲总黄酮提取液在pH9.0左右稳定,温度超过70℃稳定性较差,光照会使总黄酮稳定性下降。山梨酸钾和Cu2+使总黄酮稳定性明显下降,苯甲酸、Zn2+和Fe3+对其下降不明显,NaCl、蔗糖、柠檬酸、Vc、K+、Na+和Al 3+对其基本无影响,Mg2+和Ca2+对总黄酮具有护色作用。     

网络测量及流量采集技术综述

对网络测量进行了定义,描述了网络测量的功能以及网络测量的方法,介绍了RFC中定义的网络性能度量值的概念,最后对网络流量测量中经常用到的流量采集技术进行了分析和比较.     

高校学生性别比例问题综述

高校学生性别比例问题原因很复杂,需要从社会学、心理学、教育学、人口学等角度,经过科学的调查统计分析来获得结论。目前不能仅仅以表面的观察和粗略的数据来判断是非。如果作为一个重大课题开展多学科的科学研究,必将为解决该问题提供相应的理论依据。     

Development of an automatic customer service system on the internet

Most existing network-based customer services heavily rely on manpower in replying e-mails or on-line requests from customers, which not only increases the service cost, but also delay the time for responding the service requests. To cope with these problems, this paper proposes a customer service system, which can automatically handle customer requests by analyzing the contents of the requests and finding the most feasible answers from the frequently asked question (FAQ) database. In the situation that a customer is not satisfied with the reply, the system will forward the request to the appropriate service personnel for further processing. An assistance mechanism has been developed to help the service personnel in finding potential answers from existing FAQ data or creating more appropriate answers. Experimental results on practical applications showed that over 87.3% of users were satisfied with the replies given by the system; therefore, we conclude that the system can significantly reduce the service cost and provide more efficient and effective customer service.     

Approximate controllability of partial neutral functional differential systems of fractional order with state-dependent delay

We prove the approximate controllability of control systems governed by a class of partial neutral functional differential systems of fractional order with state-dependent delay in an abstract space. Sufficient conditions for approximate controllability of the control systems are established provided the approximate controllability of the corresponding linear control systems. The results are obtained by using the Krasnoselskii–Schaefer type fixed point theorem with the fractional power of operators. An example is provided to illustrate the main results.     

刚性连体位置对非对称双塔连体结构动力可靠度的影响

考虑地震动的非平稳性,变化连体位置,对非对称双塔连体结构运用虚拟激励法进行非平稳随机激励下的动力可靠度研究。采用刚度退化的 Bouc-Wen 模型模拟塔楼各楼层的滞变特性,建立非线性化动力方程。运用混合精细积分法对每一时刻的响应进行求解,得到连体位置变化时非对称连体结构在非平稳随机激励下的时变方差。基于首次超越破坏准则与 Markov 假定,研究非平稳随机地震激励下连体结构的动力可靠度。运用上述理论,在8度罕遇地震作用下对某非对称双塔连体结构进行随机地震响应与动力可靠度分析。研究结果表明,地震作用下结构的层间位移响应呈现强烈的非平稳性,变化连体位置对连体结构的随机地震响应与动力可靠度将产生显著影响。     

水杨醛缩取代芳基Schiff碱制备及其光致变色性能研究

制备了水杨醛缩邻(对)氨基苯甲酸Schiff碱,利用红外(IR)、核磁(1H NMR)光谱和元素分析仪(EMS)对化合物结构进行了表征。利用紫外-可见光谱(UV-Vis)研究了两种Schiff碱在乙醇溶液中的光致变色性能。结果表明,两种Schiff碱都具有良好的光致变色性能,其变色过程是由烯醇式结构向酮式结构转变,不存在其它形式的光分解副反应。该类化合物与金属铜离子(Cu2+)能形成稳定配合物,且配合物也具有较好光致变色性能。