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991.
在p型(100)单晶Si基衬底上,利用磁控溅射设备完成直流溅射Mo/Ti布拉格反射层和射频反应溅射AlN压电层,用光刻微加工工艺设计了不同谐振面积与电极图案的Ti/Au上电极,在优化工艺条件下制备了氮化铝基体声波质量传感器,比较分析了不同电极图案和谐振面积对传感器性能的影响。研究表明,电极图案相同时,谐振面积为10 000(100×100)μm2的器件电学性能最好,谐振面积相同时,电极图案为圆形的损耗最小;内角为直角的正方形损耗最大,内角为钝角的五边形损耗居中。 相似文献
992.
《Ceramics International》2023,49(10):15689-15699
Three-dimensional (3D) printing based on digital light processing (DLP), for its great advantage in dealing with material and structural complexities, is being engaged for the fabrication of custom-designed silica optical fibre preforms. Resin preparation and printing are key processes critical to DLP fabrication of optical fibre preforms with high silica loading. In this work, the surfactant effect on preparation of resin and DLP printing of optical fibre preforms for higher silica loading is investigated. Based on our experimental studies of the rheological and photocuring properties of resins and the quality of printed silica fibre preforms, we find that, in the case where 2-phenoxyethanol (POE) is usually added as the surfactant, the resin has higher viscosity and results in poorer preform quality. By removing POE from resin ingredients and designing a multi-step resin processing with appropriate settling and degassing processes, fibre preforms with high silica loading up to 0.8 (w/w) have been successfully fabricated. 相似文献
993.
Shen-Ming Chung Ming-Der Shieh Tzi-Cker Chiueh 《International Journal of Communication Systems》2023,36(1):e4141
Searchable encryption (SE) is considered important as it provides both confidentiality and searchability for the data stored in semi-trusted environments such as cloud. However, it is rarely deployed because most SE schemes are not native to cloud services as they require database modifications. In this paper, we present an SE scheme called Frequency-Eliminated Trapdoor-Character Hopping (FETCH) that, based on novel common-conditioned-subsequence-preserving (CCSP) techniques, is able to work natively with off-the-shelf databases and supports wildcard-based pattern search on encrypted data thereof. In fact, with the CCSP techniques, we transform the problem of wildcard SE searching into a problem of subsequence searching, which is solved fast in most databases and thus fits well with cloud services in general. Although in our security analysis, CCSP removes the possibility of obtaining theoretical indistinguishability between indexed items, we show that FETCH does provide adequate confidentiality protection and fares much better than other existing wildcard SE schemes in terms of query performance, storage overhead, and deployment complexity. In particular, FETCH is able to efficiently handle data sets whose size is multiple orders of magnitude larger than those that existing schemes can comfortably support. 相似文献
994.
《International Journal of Hydrogen Energy》2023,48(29):10737-10754
Oxygen evolution reaction (OER) at the anode limits the efficiency of hydrogen production from water electrolysis substantially. A novel electrocatalyst of RuO2 decorating TiO2 nanowire arrays for OER was successfully prepared using a cyclic voltammetric method with electrodeposition of RuO2 nanoparticles on the TiO2 nanowire (TNW) arrays synthesized hydrothermally. Even though the electrodes with the composite electrocatalyst have a lower loading of RuO2, they have higher electrocatalytic activity and stability for acidic oxygen evolution than the Ti/RuO2 electrode prepared by conventional thermal decomposition method. The core-shell structure of the TNW@RuO2 electrocatalyst not only increases the specific surface area of the electrodes, but also inhibits the adverse effect of the poor conductivity of TiO2. This novel OER electrocatalyst can improve the efficiency and reduce the cost of hydrogen production from electrolytic water splitting. 相似文献
995.
《International Journal of Hydrogen Energy》2023,48(37):13902-13912
At present, the precious metal Pt is a common catalyst for large-scale hydrogen evolution reaction (HER) production of hydrogen, but due to its high price and scarcity, finding an innovative catalyst has become the key to electrocatalytic hydrogen evolution. Here, the HER electrocatalytic activity of Janus MoXTe (X = S, Se) monolayers was investigated through first-principles calculations. Mo vacancy, X vacancy and Te vacancy were introduced into 2H, 1T, and 1T’ phase respectively and their stability was studied. The results show that the introduction of vacancy can improve the electrocatalytic hydrogen evolution performance. Particularly, the Gibbs free energies (ΔGH) of Te vacancy of 2H phase MoSTe and MoSeTe are close to zero (ΔGH = 0.03, −0.05 eV, respectively), and has the highest exchange current density. We further find that the conductivity of 2H phase MoSTe and MoSeTe is enhanced after introducing Te vacancy. In details, H get 1.86 and 1.43 e on VTe in 2H phase MoSTe and MoSeTe. The bond between S and H is more stable, H is better adsorbed on the catalyst, and the performance is improved. Our research provides a strategy for designing MoXTe monolayer electrocatalysts, which are predicted to be employed in HER catalysts with low cost and high performance. 相似文献
996.
《International Journal of Hydrogen Energy》2023,48(37):13864-13876
Here, hybrid kaolin-g-C3N4 heterostructure particles were fabricated by calcination in the first step, followed by hydrothermal phosphoric acid activation in the second step, and phosphorus (P) and oxygen (O) doped kaolin-g-C3N4 metal-free catalyst was synthesized. This hybrid metal-free catalyst was used for the first time for the production of effective hydrogen (H2) from sodium borohydride (NaBH4) methanolysis. The hydrogen generation rate (HGR) value of 5500 ml min−1g−1 was obtained with the P and O doped kaolin-g-C3N4 catalyst. The activation energy (Ea) of 31.90 kJ mol−1 by P and O doped kaolin-g-C3N4 for the production of H2 was obtained. The kaolin-g-C3N4 and P and O doped kaolin-g-C3N4 metal-free catalysts were systematically characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), and Fourier-transform infrared spectroscopy (FTIR). Based on the results obtained, the mechanism of P and O-doped kaolin-g-C3N4 catalyst on H2 production from NaBH4 methanolysis was also proposed. 相似文献
997.
《International Journal of Hydrogen Energy》2023,48(64):25171-25184
A two-stage hydrogen purification process based on pressure swing adsorption (PSA) and CO selective methanation (CO-SMET) is proposed to meet the stringent requirements of H2-rich fuel for kW-scale skid-mounted or distributed proton exchange membrane fuel cell systems. The reforming gas is purified using dynamic adsorption model of PSA with activated carbon for initial purification and then kinetic model of CO-SMET with 50 wt% Ni/Al2O3 for CO deep removal. Sensitive analyses of the gas hourly space velocity, adsorption time and adsorption pressure etc. are studied. The results show that excellent H2 purity and CO concentration below 1000 ppm for the initial target using the three-bed and four-bed PSA system at shorter adsorption time and higher pressure, and then CO concentration below 10 ppm with H2 purity over 99.94% on CO-SMET. This work provides a small-scale and hydrogen-saving process for hydrogen purification can be achieved by the two-stage process. 相似文献
998.
《International Journal of Hydrogen Energy》2023,48(45):17216-17229
Two-dimensional (2D) carbon-based (C-based) and carbon-nitrogen (C–N) materials have great potential in the energy harvest and storage fields. We investigate a novel carbon biphenylene (C468) consisting of four-, six- and eight-membered rings of sp2 carbon atoms (Fan et al., Science, 372:852-6 (2021)) for hydrogen storage. Using first-principles based Density functional theory calculations, we study the geometrical and electronic properties of C468 and N-doped C468. Lithium (Li) atoms were symmetrically adsorbed on both sides of the substrate, and their adsorption positions were determined. The maximum gravimetric density of hydrogen (H2) adsorbed symmetrically on both sides of Li atom was studied within the scope of physical adsorption process (−0.2 eV/H2 ∼ −0.6 eV/H2). Li-decorated C468 can adsorb 8 upper hydrogen molecules and 8 lower hydrogen molecules, and Li-decorated N-doped C468 can adsorb 9 upper hydrogen molecules and 9 lower hydrogen molecules. The gravimetric densities of Li-decorated C468 and Li-decorated N-doped C468 can reach 9.581 wt% and 10.588 wt%, respectively. Our findings suggest significant insights for using Li-decorated C468 and Li-decorated N-doped C468 as hydrogen storage candidates and effectively expand the application scope of C-based materials and C–N materials. 相似文献
999.
Recommender Systems (RSs) have played an important role in online retailing portals and customers’ decision-making processes. Recommender systems that are based on the conventional Collaborative Filtering (CF) approach rely on single customers’ ratings on retailing websites. Multi-criteria CF (MCCF) approaches that rely on multi-aspects of the products have provided more reliable and effective recommendations on retailing websites. However, these approaches should be improved in terms of accuracy by solving sparsity issues and incorporating criteria ratings. In addition, most of the recommendation agents that are based on MCCF cannot learn automatically from the features of the products to model customers’ preferences and generate accurate recommendations on retailing websites. Besides, although previous studies have utilized single and multi-criteria ratings in recommendation agents of tourism websites, still, if there is a lack of ratings of items, most of these systems will fail to generate accurate recommendations to users. In this research, we develop a new recommendation agent based on a MCCF approach to effectively improve the performance of previous recommendation systems for tourism websites. The results demonstrated that the method can predict the most relevant products to users, particularly when the dataset is sparse. 相似文献
1000.
Relaxor ferroelectric perovskites have experienced a revival of interest in recent years accompanying the deeply exploration of the fine local structure of polar nanoregions, which are thought to be the structure root for unique electrical properties. Interestingly, a new type of low-tolerance relaxor ferroelectric, which exhibits both cation displacement and large oxygen octahedral tilt, exhibiting anomalous microdomains were found in NaNbO3-based lead-free perovskites, breaking through the limits of the relaxor ferroelectric models proposed from classical relaxors. Atomic-scale annular bright-field scanning transmission electron microscopy images indicate that the microdomains are formed by long-range ordered oxygen octahedral tilt. At the same time, substructure of randomly embedded nanoregions with inhomogeneous polarization vectors can be mapped, being the main reason for relaxor behavior. Based on this special ferroelectric-improper ferroelastic state, delayed polarization saturation can be obtained under strong electric field, providing an opportunity for generating excellent energy storage properties. The results found in this work not only open up a new kind of relaxor ferroelectrics but also will lead to the reconstruction of relaxor models and theories built for more than half a century. 相似文献