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121.
含钛高炉渣作为固体废弃物,国内存量巨大,且其中的钛组元难以提取,导致含钛高炉渣综合利用一直没有得到有效解决。针对当前含钛高炉渣利用率低、附加值低等问题,基于含钛高炉渣成分特点,通过选择性析晶(CaTiO3优势析出)、碱激发,制备出CaTiO3-多孔地质聚合物的复合材料。试验结果表明,析晶温度1 400 ℃、保温1 h能够促进CaTiO3的优势析出,而剩余氧化物以玻璃相形式存在。制备出的CaTiO3-多孔地质聚合物材料结合了CaTiO3高光催化活性与多孔地质聚合物比表面积大的优点,对亚甲基蓝具有优异的吸附效果,最大吸附量可达60.4 mg/g。在投加量为50 mg,2 h吸附、3 h光降解条件下,对亚甲基蓝去除率可达94.5%,在治理有机污染领域有良好的应用前景。 相似文献
122.
123.
以柠檬酸、乳酸及金属盐为原料,采用有机凝胶-热分解法制备了微细氧化镁、 α-氧化铝和尖晶石结构铝酸镁纤维。所得纤维结构致密、晶粒细小,直径可小于1μm,长径比大。通过FTIR,XRD,DSC及SEM对纤维前驱体凝胶的结构、热分解过程及热处理产物的形貌进行了表征。凝胶的可纺性与组成凝胶的羧酸盐分子结构、羧酸和金属离子的摩尔比等因素有关。柠檬酸和乳酸中的羧基分别以单齿配位于Mg^2+和Al^3+可能形成线性分子[(C6H6O7)2Mg3],[(C3H5O3)3Al]和[(C6H6O7)4MgAl2],由这些线性分子组成的凝胶显示出了良好的可纺性。 相似文献
124.
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126.
通过显微硬度测试、拉伸试验、能谱分析、SEM及TEM观察,研究了少量Ag对低Cu/Mg比的Al-Mg-Cu-Li合金微观组织与性能的影响。实验结果表明:Ag的添加提高了该合金的硬度和强度,同时改善了其塑性,并延缓了过时效的发生。微观组织观察表明:Ag的添加促进Z相的均匀弥散析出,同时抑制了S'相在缺陷处非均匀析出;并且Ag的添加还促使了时效初期合金中δ’相的细化和弥散分布,延缓了δ’相的长大。同时分析了析出相种类对合金塑性的影响。 相似文献
127.
Mercury transformation across particulate control devices in six power plants of China: The co-effect of chlorine and ash composition 总被引:2,自引:0,他引:2
This paper presents the results of field measurements on mercury speciation in six power plants of China by applying the Ontario hydro method. During the tests, flue gas was sampled simultaneously before and after particulate control devices (electrostatic precipitator and fabric filter baghouse) along with the pulverized coal, bottom ash and fly ash sampling. The amount of oxidized mercury in gas phase before and after ESP/FF suggests that mercury oxidation after combustion is a kinetically controlled process. The comparison of mercury speciation in different power plant indicates a clear relationship with coal type, especially the chlorine concentration and the basic ash compositions in coal. Both of the factors are analyzed quantitatively in this study. A new parameter C (ratio of chlorine in coal to base/acid ratio) has been introduced to evaluate the co-effect of the two factors above on mercury speciation. 相似文献
128.
Summary Homopolymers of 2-(dimethylamino)ethyl methacrylate (DMAEMA) have been synthesized directly in aqueous media by reversible addition-fragmentation chain transfer polymerization (RAFT) using 4,4-azobis(4-cyanopentanoic acid) (V501) as a water-soluble azo initiator and 4-cyanopentanoic acid dithiobenzoate (CPADB) as a chain transfer agent. The resulting polymers were controlled in the range of narrow molecular weight distributions, with
lower than 1.3. Using the produced dithioester-capped DMAEMA homopolymer as a macro chain transfer agent, miniemulsion RAFT polymerization of methyl methacrylate and styrene were carried out, respectively. 1H NMR analysis showed that the diblock copolymer PDMAEMA-b-PMMA in the form of stable latices was obtained as expected. This revised version was published online at the end of November 2004. Unfortunately, the received date was incorrect due to a technical problem. 相似文献
129.
《Fuel Processing Technology》2006,87(3):247-258
Results from a 1-dimensional and semirigorous model for atmospheric and circulating fluidized bed biomass gasifiers (CFBBGs), presented in the (previous) paper by Corella and Sanz [J. Corella, A. Sanz, Modeling circulating fluidized bed biomass gasifiers. A pseudo-rigorous model for stationary state. Fuel Process. Technol. 86 (2005) 1021–1053], are shown here. Process variables predicted by the model are gas composition (H2, CO, CO2, CH4, C2Hn, H2O and O2 contents), gas yield, tar content in the flue gas and char concentration in the solids. Both axial profiles in the riser and values at the gasifier exit are calculated from the model and are shown here for some selected sets of process variables. Variables analyzed in depth are: total air flow (used as equivalence ratio, ER), percentage of secondary air flow, height (location) of the secondary air flow, biomass moisture and biomass flow rate, expressed as the biomass weight hourly space velocity in the gasifier. All the results from the model agree both with known published data and with some tests made to check the model. 相似文献
130.
《Diamond and Related Materials》2006,15(9):1378-1382
To explore the work function of a typical amorphous-CN film containing a nitrogen concentration of 23.5 at.%, surface potential images were acquired using Kelvin probe force microscopy. Based on the Fermi level of the n-type Si and the contact potential difference between the amorphous-CN film and the n-Si substrate, the work function of the amorphous-CN film was estimated to be 5.2 ± 0.2 eV below its vacuum level. Using the surface potential depth profile for an etched amorphous-CN film, energy diagrams of the amorphous-CN/SiO2/n-Si interface were constructed based on the positional relationship of the Fermi level. These band diagrams showed that band bending occurred at the amorphous-CN/SiO2/n-Si interface despite the Fermi level pinning effect of surface trapping due to the SiO2 insulator layer. 相似文献