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121.
《Journal of the European Ceramic Society》2005,25(5):695-702
Results are presented for the reaction of aluminium metal with zirconia ceramics under (reducing) sintering conditions. During hot-pressing the principal phase formed is zirconium monoxide which is shown to have a rock-salt cubic structure and a unit-cell dimension of 0.46258 nm.When pressureless sintered or hot-pressed using a yttria partially-stabilised zirconia, composite structures of ZrO, alumina and cubic zirconia are produced which are the result of reduction reactions which proceed through the liquid metal phase. The results are interpreted through X-ray diffraction, microstructural and phase equilibria considerations which show that the sintering gas also plays a role in reaction through the oxygen partial pressure.The results allow calculation of an approximate value of the free energy of formation of zirconium monoxide (−294,500 J mol−1) which is consistent with the reported values for the monatomic carbide and nitride of zirconium and with other similar transition metal carbide, nitride and monoxide series. 相似文献
122.
采用溶胶-凝胶法制备了Yb掺杂TiO2纳米光催化剂,并通过XRD和BET等手段进行了表征.以对苯二甲酸作为探针分子,结合化学荧光技术研究了光催化剂表面羟基自由基的生成;并以苯酚为光催化降解反应模型化合物,考察了光催化剂的活性.测定了苯酚在TiO2和Yb掺杂TiO2光催化剂上的吸附常数.结果表明:Yb掺杂使TiO2的粒径减小,比表面积增大,同时导致羟基自由基的生成速率增大.Yb掺杂有利于反应底物在催化剂表面的吸附,Yb的最佳掺入量为Yb/Ti摩尔比=0.8%. 相似文献
123.
《Composites Part A》2007,38(2):323-336
In this paper, a new simple metallic z-rod model is proposed to study the bending effect of the metallic z-rods on mode II delamination toughness of laminated composites. A new transverse shear force–deformation relationship for a metallic z-rod is obtained by using the classical beam theory and modeling its surrounding matrix as linearly elastic, rigid–perfectly plastic or linearly elastic–perfectly plastic springs. The bridging traction provided by a metallic z-rod to the mode II delamination toughness is assumed to be only the shear force carried by a z-rod created by the relative slippage between two substrate beams in an end-notched flexure (ENF) specimen, whereas the longitudinal sliding friction is assumed to make negligible contribution to the bridging traction. Mode II strain energy release rate (SERR) is employed to evaluate the influence of the metallic z-rods on the interlaminar fracture toughness of end-notched flexure (ENF) specimens. A parametric study of ENF specimens reinforced with the z-rods is conducted to demonstrate the effect of the new bridging mechanism by the metallic z-rods on the mode II delamination toughness. 相似文献
124.
Fabrication of multi-walled carbon nanotube reinforced polyelectrolyte hollow nanofibers by electrospinning 总被引:1,自引:0,他引:1
Hybrid hollow multi-walled carbon nanotubes (MWCNTs)/polyelectrolytes (PE) nanofibers were prepared by a combination of the electrospinning method and layer-by-layer (LbL) technique. The mixed polystyrene (PS)/MWCNTs nanofibers were obtained by electrospinning method, which were employed as templates to self-assembly multilayered polyelectrolytes by LbL technique. Hollow MWCNTs/PE nanofibers were obtained by selectively removed part of the template: PS, which is confirmed by Raman spectra, transmission electron microscopy (TEM) and scanning electron microscopy (SEM). 相似文献
125.
Influence of coal forced oxidation on technological properties of cokes produced at laboratory scale
《Fuel Processing Technology》2005,87(1):1-10
The effect of coal oxidation in air at 140 °C on the technological properties of cokes obtained at laboratory scale from two medium volatile bituminous coals has been studied. The proximate and ultimate analyses do not show important changes with coal oxidation time. However oxidation clearly has a strong effect on the plastic properties of the coals in view of the fact that the Gieseler fluidity eventually disappears. From this point variations in plastic properties can still be detected by FSI. Other changes, such as a shortening of the length of the saturated fragments of the aliphatic chains, a decrease in the aliphatic hydrogen content and an increase in the oxygen-containing groups are detected by PA-FTIR. It was also found that the main coke quality indices (mechanical strength and reactivity to CO2) of both coke series are impaired with coal oxidation. A close relationship between reactivity to CO2 and the micropore specific surface area of the cokes has been corroborated. 相似文献
126.
高纯铝箔通常通过电化学扩面后用作铝电解电容器的阳极材料。利用铝箔(100)面隧道孔制备纳米模板。这种纳米模板的特点是制作简单、模板面积大,纳米阵列材料形状可控性强。还利用两步电化学侵蚀铝箔的特殊工艺,研制出纵横交错的TiO2纳米有序阵列材料。 相似文献
127.
Junwei Fu Zhengbiao Zhang Zhenping Cheng Jian Zhu Wei Zhang Xiulin Zhu 《Polymer Bulletin》2008,61(3):287-297
A novel reversible addition-fragmentation chain transfer (RAFT) reagent bearing triphenylamine (TPA)
group, 4-diphenylamino-dithiobenzoic acid benzyl ester (DDABE), was designed and synthesized. It was used
in the RAFT polymerizations of styrene (St) and methyl acrylate (MA) to prepare end-functionalized polymers.
The results of the polymerization showed that the RAFT polymerizations could be well controlled using DDABE
as the RAFT agent. Number-average molecular weight (Mn,GPC) increased linearly
with monomer conversion, and molecular weight distributions were relatively narrow (PDI<
1.50). The results of chain-extension reaction, 1H NMR spectra and UV/Vis
spectra confirmed that most of the polymers chains were end-capped by the functional triphenylamine
(TPA) groups. The effect of feed molar ratios of St/DDABE/AIBN on polymerization was investigated. 相似文献
128.
《Applied Energy》2005,81(3):322-333
The separation of useful chemicals, such as indole from coal tar, is an important subject of research in the field of fossil energy, renewable energy, and utilization of byproducts and waste materials. High-pressure crystallization is one of the proposed separation methods. To understand the process requires detailed knowledge of solid–liquid phase behaviors. Solid–liquid phase equilibrium data of various binary mixtures of indole have been reported in the literature. In the present report, we analyze some of the experimental data with our unified solid–liquid–vapor equation-of-state to see whether our model can be useful for the calculation of solid–liquid equilibria in these organic systems. Good correlations of the data and predictions of phase behavior, at very high pressures, are demonstrated. 相似文献
129.
Transglutaminase (TGase) was separated from the culture broth of an isolated strain of Streptoverticillium mobaraense. The crude enzyme was prepared by centrifugation, ultrafiltration, precipitation by alcohol, centrifugation and freeze‐drying. The yield after these processes was 65–70%. Then the enzyme was purified to homogeneity by chromatography on CM‐cellulose and Sephadex G‐75 on which the yields were about 70% and 80%, respectively; the purified folds reached 2.5–4.7 and 1.08–2.06, respectively. The molecular weight of this TGase was 39,500–40,100 Da by gel filtration chromatography. Optimum enzyme activity was observed in the pH range of 5.0–7.0, and it was maintained stable at 20–40C. The optimal temperature and pH was 52C and 6.0, respectively. At 1 mM and 5 mM metal ion or inhibitors concentration, TGase activity was strongly inhibited by Zn2+ and NEM, and not affected obviously by Ba2+, Ca2+, Co2+, Cu2+, Fe2+, Fe3+, Mg2+, Mn2+, Na+ as well as PMSF and EDTA. The effects of these additions on this TGase were compared with those of other microbial TGases. 相似文献
130.
《International Communications in Heat and Mass Transfer》2005,32(1-2):27-31
Pool boiling heat transfer from nano-porous surface immersed in a saturated FC-72 dielectric fluid has been experimentally studied at atmospheric pressure (101 kPa). The data obtained from nano-porous surface (Anodisc 25) of thickness about 70 μm made from aluminum oxide (Al2O3) obtained from Whatman, were compared to that of a plain surface (aluminum) of thickness about 105 μm. From the experimental data obtained it was evident that there is a reduction of about 30% in the incipient superheat for the applied power for nano-porous surface over plain surface. SEM photographs of the nano-porous coating were taken for determining the size of the pores. 相似文献