321-52M-690异种金属焊接接头的应力腐蚀开裂行为研究

采用慢应变速率拉伸(SSRT)和高温电化学相结合的方法,研究了外加电位对321-52M-690异种金属焊接接头在含Cl-高温高压水中应力腐蚀开裂(SCC)倾向的影响规律。结果表明,在300℃、50ppm Cl-环境下,焊接接头的SCC敏感性随电极电位(-700~+100mV)的升高而增大,且存在一个介于0~+50mV(vs.SHE)之间的临界电位Ecrit。当电极电位低于Ecrit时,焊接接头的SCC敏感性较小,SCC敏感性指数ISSRT基本在40%左右,断裂形式为外力主导的塑性开裂;当电极电位高于Ecrit时,ISSRT急剧增加至70%以上,断裂形式为腐蚀主导的脆性开裂。试样断裂位置均位于硬度最低的321母材处,表明在321/690异种金属焊接接头中321母材对SCC最为敏感,故进一步探讨了321不锈钢的应力腐蚀开裂行为和机理。     

Process and mechanical properties of carbon/carbon–silicon carbide composite reinforced with carbon nanotubes grown in situ

A hierarchical C_f/C–SiC composite was fabricated via in situ growth of carbon nanotubes (CNTs) on fiber cloths following polymer impregnation and pyrolysis process. The effects of CNTs grown in situ on mechanical properties of the composite, such as flexural strength, fracture toughness, crack propagation behavior and interfacial bonding strength, were evaluated. Fiber push-out test showed that the interfacial bonding strength between fiber and matrix was enhanced by CNTs grown in situ. The propagation of cracks into and in fiber bundles was impeded, which results in decreased crack density and a “pull-out of fiber bundle” failure mode. The flexural strength was increased while the fracture toughness was not improved significantly due to the decreased crack density and few interfacial debonding between fiber and matrix, although the local toughness can be improved by the pull-out of CNTs.     

温轧FeCrAl钢退火组织演变对力学性能的影响

摘要：研究采用电子背散射衍射技术（EBSD）对温轧及退火态Fe-13Cr-4.5Al-2.2Mo-1.1Nb（质量分数,%）钢的织构、晶界类型和Laves相进行了表征,并讨论了对力学性能的影响。结果表明,300℃温轧变形,70% 的样品出现显著的变形不均匀组织,利用Taylor因子解释了不均匀变形特征,晶粒取向以变形织构α、γ和<100>//ND为主,比例分别为43.3%、39.0%和17.1%,屈服强度和抗拉强度为1298.1MPa和1371.6MPa,伸长率4%。750～800℃退火30～60min后,再结晶晶粒尺寸小于10μm,γ织构比例减少至11.9%～15.5%,此时屈服强度为790～860MPa,抗拉强度为840～890MPa,伸长率为20%左右。1000℃退火5min后再结晶晶粒明显长大,γ织构增加至39.1%,此时屈服强度、抗拉强度和伸长率分别为567.7MPa、800.7MPa和25.6%。1000℃时随退火时间增加,γ织构增加至50%以上,Laves相的钉扎是γ织构增加的原因。600℃温轧的微观组织和300℃温轧的类似,但屈服强度和抗拉强度略有下降,伸长率增加。     

Nodular Corrosion of Zr–0.85Sn–0.16Nb–0.37Fe–0.18Cr Alloy in 500 °C Steam Caused by High-temperature Processing

Oxidation of Metals - Zr–0.85Sn–0.16Nb–0.37Fe–0.18Cr alloy samples prepared by low-temperature process&nbsp;(LTP) and high-temperature process (HTP) show different...     

Effect of Ni interlayer on partial transient liquid phase bonding of Zr–Sn–Nb alloy and 304 stainless steel

Zr–Sn–Nb alloy and 304 stainless steel were joined by means of partial transient liquid phase bonding. The effects of Ni interlayer on the microstructure and properties of the joints were investigated. The reaction layers are formed in both joints and which are mainly composed of σ-FeCr layer, Zr(Cr, Fe)₂ + α-Zr layer and α-Zr + Zr₂(Ni, Fe) layer. The intermetallic compounds are compact relatively and cracks are formed in the reaction layer of the direct bonded joint. In the joint with Ni interlayer, many α-Zr phases dispersedly exist in the reaction layer and the thickness of the reaction layer is distinctly larger than that without Ni interlayer. As a result of lower residual stresses and wider crack-free reaction layer, the bonding strength of the joint increases by using Ni interlayer.     

Characterization of Microstructure and Stress Corrosion Cracking Susceptibility in a Multi-pass Austenitic Stainless Steel Weld Joint by Narrow-Gap TIG

Metallurgical and Materials Transactions A - In the present study, correlation of the microstructure and stress corrosion cracking (SCC) susceptibility in the top, middle and root regions of a...     

Characterization and Interpretation of the Multiple Crystallographic Features of ε′ Precipitates in an Ag-Containing Mg-Sn Alloy

Metallurgical and Materials Transactions A - A novel orientation relationship (OR) between the ε′ precipitates and Mg matrix has been characterized in a Mg-Sn-Ag-Zn-Mn alloy. This OR is...     

Sn含量对N36锆合金在LiOH水溶液中耐腐蚀性能的影响

比较了N36(Zr-1Sn-1Nb-0.3Fe)及低锡N36 (Zr-0.8Sn-1Nb-0.3Fe)锆合金样品在360 ℃/18.6 MPa/0.03 mol/L LiOH 水溶液中的耐腐蚀性能,发现N36提前发生腐蚀转折,转折后腐蚀增重远高于低锡N36。观察了腐蚀转折后合金样品氧化膜形貌及物相特征,发现在氧化膜断面上形成平行于氧化膜／金属界面的裂纹,而界面氧化膜呈"菜花"状生长;与N36相比,低锡N36氧化膜形貌显示断面裂纹相对较少,界面生长的氧化膜较为平整;随腐蚀速率的增加,断面裂纹增多,界面膜呈"菜花"状凸起越严重;氧化膜中产生的裂纹与四方相的转变有关。讨论了Sn对N36合金耐腐蚀性能影响的机理,认为固溶在α-Zr中的Sn含量是引起耐腐蚀性能差别的主要原因。     

Stress and Defect Characteristics in Oxide Films and Corrosion Resistance of Zr-1Nb Alloy

Two approaches to testing corrosion in autoclave with different time intervals for heating and cooling were carried out to investigate the corrosion resistance of Zr-1Nb alloy in the 0.01 mol/L LiOH aqueous solution at 360 °C/18.6 MPa, the stress, and defect density in the oxide film. The stress and defect density in oxide film were measured by a curl method and the Ion Migration Method (IMM), respectively. Results showed that the stress level and defect density in the oxide film in the shorter interval corrosion tests were lower than that in the longer interval corrosion tests at the initial stage of corrosion with the weight gain less than 34.37 mg/dm2. The corrosion resistance in the subsequent stages of corrosion was better in the shorter interval corrosion tests. It indicates that at the initial stage of corrosion the weight gain shows no obvious difference between the two approaches of corrosion tests in autoclave under different time intervals for heating and cooling. However, the stress level and defect density in the oxide film exhibit noticeable differences, which leads to two distinct microstructural evolution rates of the oxide film. The distinct microstructural evolution rates cause different corrosion resistance in the subsequent corrosion stages.     

Study on α-alumina precursors prepared using different ammonium salt precipitants

Nano-sized α-Al₂O₃ platelets have been produced by the precipitation method employing the starting material of Al(NO₃)₃·9H₂O and ammonium salt precipitants, such as the NH₄OH, (NH₄)₂CO₃ and NH₄HCO₃. The effects of chemical composition of ammonium salt precipitants and aging time of precipitated product on the formation of precursor and final product of α-Al₂O₃ particles were studied. The precursors with different crystal structures were formed depending on the chemical composition of precipitant and the agglomeration of final α-Al₂O₃ particles was found to be greatly affected by the precipitant. The aging time of precipitated precursor also influenced the agglomeration of final α-alumina particles.