Synthesis of high purity Tl1212 superconductor with ultrafine grains from coprecipitated Tl-free precursor route

In this study, high purity and fine-grained Tl1212 superconductor samples were successfully synthesized from Tl_0.8Bi_0.2Sr₂Ca_0.8Y_0.2Cu₂O₇ starting composition by a two-step solid-state reaction method using Tl-free precursor powder prepared from coprecipitation method. XRD pattern of the sample, which was sintered at 1,000 °C for 6 min essentially showed formation of high purity 1212 phase. The sample’s zero resistance critical temperature, T _{c zero} was 91 K and bulk critical current density, J _c measured at 40 K in zero magnetic field was 11.2 A/cm². SEM investigation on the sample revealed ultrafine homogeneous grains that are randomly orientated with grain sizes of approximately 0.5–1 μm. Resintering the sample did not affect its superconducting properties but induced clustering of grains as observed by SEM. It is suggested that the sample be used in specialized measurement techniques such as in ultrasonic studies where high purity and ultrafine-grained samples are required.     

Effect of polyacrylic acid (PAA) binder system on particle orientation during dry-pressing

Effect of polyacrylic acid (PAA) binder system on the development of particle orientation during uniaxial pressing is reported. Granules of different properties were compacted using uniaxial pressing at various pressure and their degree of particle orientation (DPO) was determined. The increment trend of DPO varies with granule strength and shows higher value for binder system of higher flexibility. Anisotropic shrinkage related to particle orientation is shown by compact of higher relative density (RD) and DPO; whereas anisotropic shrinkage related to non-uniform packing density is shown by compact of lower RD and DPO. Anisotropic shrinkage remains in the former compact while isotropic shrinkage was obtained for the latter compact at sintering temperature of 1600 °C. Subsequent cold isostatic pressing increases DPO and sintering shrinkage ratio of uniaxially pressed compacts.     

An ANFIS-based approach for predicting the bed load for moderately sized rivers

A total of 346 sets of bed-load data obtained from the Kinta River, Pari River, Kerayong River and Langat River were analyzed using four common bed-load equations. These assessments, based on the median sediment size (d₅₀), show that the existing equations were unable to predict the measured bed load accurately. All existing equations over-predicted the measured values, and none of the existing bed-load equations gave satisfactory performance when tested on local river data. Therefore, the present study applies a new soft computing technique, i.e. an adaptive neuro-fuzzy inference system (ANFIS), to better predict measured bed-load data. Validation of the developed network (ANFIS) was performed using a new set of bed-load data collected at Kulim River. The results show that the recommended network can more accurately predict the measured bed-load data when compared to an equation based on a regression method.     

Effect of nanoparticle shape on the heat transfer and thermodynamic performance of a shell and tube heat exchanger

Nanofluid is a heat transfer fluid that can improve the performance of heat exchanger systems. Different parameters such as particle size, shape, and volume concentration affect the performance of these systems. The objective of this paper is to study the effect of different nanoparticle shapes (such as cylindrical, bricks, blades, platelets, and spherical) on the performance of a shell and tube heat exchanger operating with nanofluid analytically. Boehmite alumina (γ-AlOOH) nanoparticles of different shapes were dispersed in a mixture of water/ethylene glycol as the nanofluid. The thermodynamic performance of the shell and tube heat exchanger that is used in a waste heat recovery system was analysed in terms of heat transfer rate and entropy generation. Established correlations were used to measure the thermal conductivity, heat transfer coefficient and rate and entropy generation of nanofluid. The results show an increase in both the heat transfer and thermodynamic performance of the system. However, among the five nanoparticle shapes, cylindrical shape exhibited better heat transfer characteristics and heat transfer rate. On the other hand, entropy generation for nanofluids containing cylindrical shaped nanoparticles was higher in comparison with the other nanoparticle shapes. However, the increased percentage of entropy was below 1%. Therefore, this greater entropy generation could be deemed negligible and cylindrical shaped nanoparticles are recommended to be utilized in heat exchanger systems working with nanofluids.     

THIN LAYER METHOD ANALYSIS OF SPOUTED BED DRIED MALAYSIAN PADDY – CHARACTERISTIC DRYING CURVES

A lab‐scale spouted bed dryer was used for the drying of paddy. The Malaysian grown paddy is a sample of Geldart's Group D particle. Drying was carried out in the dryer at two different internal configurations, namely with or without the installation of a draft tube, and at several drying temperatures (60–90C), air flow rates (1.14–1.45 m/s) and bed heights (30–45 cm). Drying kinetics of paddy in spouted bed showed only induction and falling rate periods, without constant drying rate period. Thin layer method analysis shows characteristic drying rate curves of linear and exponential functions for the first and second falling rate period, respectively, in conventional spouted bed drying. A single power function was observed in spouted bed drying with a draft tube, mainly as a result of a better tempering effect that gave a lower drying rate gradient.     

Improved fish migration optimization method to identify PEMFC parameters

In a worldwide environment context where the emergency need to decrease pollutant emissions is an important issue, the research for solutions is increasing. Fuel cell technology is anticipated to become a practicable approach for solving the problem of pollution due to its environmentally friendly characteristics. In this work, a novel problem formulation is suggested for the efficient recognition of PEMFC parameters which the solving is by using the Improved Fish Migration Optimizer (IFMO) technique. After coding the steps of the algorithm in MATLAB, the objective function is resolved for the fuel cell. Comprehensive simulations evaluate the formulation performance with the suggested and traditional objective functions; then, the outcomes are compared. To confirm the suggested formulation ascendancy compared to the traditional curve-fitting method, a complete assessment based on convergence rate, the value of the objective function, and the value of absolute voltage error are performed. The achieved value of the objective function, absolute voltage error, and average time of computation is 0.005, 0.4, and 1.63, respectively. Environmentally, the combustion of hydrogen and its use in PEMFC produce no carbon dioxide.     

Properties of controlled low-strength materials incorporating cement kiln dust and slag

This research evaluated the potential use of cement kiln dust (CKD) together with slag to replace the use of cement in the production of controlled low-strength material (CLSM). The low strength requirements of CLSM compared to conventional concrete enable the use of industrial by-products for the production of CLSM. In this study, the workability-related fresh properties of CLSM mixtures were observed through slump flow diameter, V-funnel flow time and filling capacity. Setting times, temperature rise, air content and unit weight of CLSM mixtures were also determined as part of fresh properties. The hardened properties that were monitored for 28 days included the unconfined compressive strength. The test results presented herein show that a combination of less than 50 kg/m³ slag and up to 300 kg/m³ CKD provides a good mix that satisfies the requirements of a CLSM with similar or better properties to that of CKD-based CLSM mix containing Portland cement. Suitable CLSM mixtures with reasonable fresh and hardened properties could also be developed by using CKD alone. However, reduced strength in such CLSM mixtures may limit their field application. The slag significantly assisted in increasing compressive strength of CKD-based CLSM mixtures. A CLSM mix containing a combination of slag and CKD was shown to have excellent characteristics for flowable backfill and excavatable base material. Therefore, producing CKD/slag based CLSM through the use of co-generated products from the cement and iron manufacturing processes can provide leadership for the construction industry in the transition for sustainable development.     

Understanding the stability of a sputtered Al buffer layer for single-walled carbon nanotube forest synthesis

We have clarified the reason that aluminum (Al) buffer layers prepared by sputtering on catalytic substrates are stable for single-walled carbon nanotube forest synthesis on chemical vapor deposition. We have focused on the difference between thermal evaporation and sputtering as the method for the preparation of the buffer layers and have analyzed the Al layers using X-ray photoelectron spectroscopy and transmission electron microscopy. Al layers produced by sputtering strongly suggest the formation of γ-alumina by aluminum hydroxides while those from thermal evaporation contain metallic Al. As a result a drastic structural change occurs during thermal annealing, making the buffer layer unstable.     

Oriented growth of ZnO nanostructures on different substrates via a hydrothermal method

Well-oriented ZnO nanorod arrays are successfully fabricated on different substrates. They are formed on different substrates at low temperature via a hydrothermal method, without adding any catalysts or templates. This approach is convenient and inexpensive. The morphologies of ZnO crystals could be controlled and transformed to other morphologies successfully by using different substrates. The effects of the substrates on the ZnO nanorod arrays have been systematically studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The characterizations of XRD and scanning electron microscopy (SEM) reveal that these products are pure single-crystal and the structure is uniform. The photoluminescence property has been detected by photoluminescence (PL) spectrum and Raman spectrum. Photoluminescence measurements show that each spectrum consists of the ultraviolet (UV) band and a relative broad visible light emission peak. But substrates play roles in the intensity of ultraviolet and visible light emission peak. The green emission in Raman measurement may be related to the surface states.     

Biomass accumulation in rapidly growing loblolly pine and sweetgum

Loblolly pine (Pinus taeda) and sweetgum (Liquidambar styraciflua) trees, growing in International Paper Company's study of intensive management on marginal agricultural land near Bainbridge GA, were destructively sampled at the end of the sixth growing season. All trees were single family blocks of genetically superior trees planted 2.5 m apart on sub-soiled rows 3.6 m apart and grown with complete competition control. Management treatments were: control, irrigation, irrigation plus fertilization, and irrigation plus fertilization plus pest control. Tree measures were basal diameter, DBH, height of live crown, diameter at base of live crown, and total height. Twenty trees of each species were destructively sampled. Stems were sectioned at 1 m intervals, stem diameter determined at each end and sections were weighed green. Branches were removed and height, basal diameter, and length were measured on each branch. Branches were separated into foliated and unfoliated segments and weighed green. A stem disk and branch from each meter were returned to the lab to determine dry weight: green weight ratio. Foliated limb: foliage ratios were also determined from sub-sampled branches. Intensive culture resulted in larger growth differences for sweetgum (most intensive treatment 9.5 m tall, 13.1 cm DBH; control trees 5.0 m tall, 6.3 cm DBH) than in pine (most intensive treatment 10.3 m tall, 17.7 cm DBH; control, 7.6 m tall, 13.4 cm DBH). The pipe model of tree development explained dimensions of the upper 5 m of crown with leaf biomass highly correlated to branch basal area (r² from 0.697 to 0.947). There was a constant ratio of leaf biomass to branch basal area (50 gm/cm² for pine, 30 gm/cm² for sweetgum). We also found a constant ratio of bole basal area to cumulative branch basal area throughout the crowns. Rapidly growing pines produced about 49 Mg ha⁻¹ of stem biomass, 11 Mg ha⁻¹ of dead branch biomass, and 17 Mg ha⁻¹ of unfoliated branch biomass at the end of six years.