Effect of polyacrylic acid (PAA) binder system on particle orientation during dry-pressing

Effect of polyacrylic acid (PAA) binder system on the development of particle orientation during uniaxial pressing is reported. Granules of different properties were compacted using uniaxial pressing at various pressure and their degree of particle orientation (DPO) was determined. The increment trend of DPO varies with granule strength and shows higher value for binder system of higher flexibility. Anisotropic shrinkage related to particle orientation is shown by compact of higher relative density (RD) and DPO; whereas anisotropic shrinkage related to non-uniform packing density is shown by compact of lower RD and DPO. Anisotropic shrinkage remains in the former compact while isotropic shrinkage was obtained for the latter compact at sintering temperature of 1600 °C. Subsequent cold isostatic pressing increases DPO and sintering shrinkage ratio of uniaxially pressed compacts.     

Role of microporosity and surface functionality of activated carbon in methylene blue dye removal from water

Activated carbons have been prepared from jute stick by both chemical and physical activation methods using zinc chloride and steam, respectively. They were characterized by evaluating surface area, iodine number, pore size distribution, and concentration of surface functional groups. The chemically activated carbon largely featured micropore structure, while the physically activated carbon mainly featured macropore structure. The specific surface area of chemically and physically activated carbons was 2,325 and 723 m ² /g, while the iodine number was 2,105 and 815mg/g, respectively. The concentration of surface functional groups was determined by Boehm titration method, which suggested that different types of surface functional groups are randomly distributed on chemical activated carbons, while it is limited for physical activated carbon. The microporosity along with surface functional groups provided a unique property to chemically activated carbon to adsorb Methylene Blue dye to a large extent. The adsorption of dye was also affected by the adsorption parameters such as adsorption time, temperature and pH. Comparatively, higher temperature and pH significantly facilitated dye adsorption on chemically activated carbon.     

A size-dependent thermodynamic model for coke crystallites: The carbon–hydrogen system up to 2500 K

The development is presented of a model of the thermodynamic functions of enthalpy, entropy and Gibbs energy for the elements carbon and hydrogen in coke crystallites. It is applicable to varying degrees of graphitization, described by the crystallite length L_a and the crystallite height L_c. The model parameters are derived from known properties such as bond enthalpies and entropies of formation. Good agreement has been obtained between the predicted thermal dehydrogenation of petroleum cokes and experimental data. The removal of hydrogen from idealized coke crystallites is predicted to occur mostly between 1100 and 1300 K. Agreement has also been found in the comparison of the predicted thermodynamic stability of coke relative to graphite, in a previous experimental study. This stability has been determined as at ≈900 J g⁻¹ at temperatures between 950 and 1250 K and for L_a = 10 nm. The current predictive capacity of the present model is valid for temperatures up to 2500 K.     

Productivity enhancements of compound parabolic concentrator tubular solar stills

The performance of compound parabolic concentrator assisted tubular solar still (CPC-TSS) and compound parabolic concentrator-concentric tubular solar still (CPC-CTSS) (to allow cooling water) with different augmentation systems were studied. A rectangular saline water trough of dimension 2 m × 0.03 m × 0.025 m was designed and fabricated. The effective collector area of the still is 2 m × 1 m with five sets of tubular still – CPC collectors placed horizontally with north-south orientation. Hot water taken from the CPC-CTSS was integrated to a pyramid type and single slope solar still. Diurnal variations of water temperature, air temperature, cover temperature and distillate yield were recorded. The results showed that, the productivity of the un-augmented CPC-TSS and CPC-CTSS were 3710 ml/day and 4960 ml/day, respectively. With the heat extraction technique, the productivity of CPC-CTSS with a single slope solar still and CPC-CTSS with a pyramid solar still were found as 6460 ml/day and 7770 ml/day, respectively. The process integration with different systems cost was found slightly higher but the overall efficiency and the produced distilled water yield was found augmented.