The optical flow problem is reduced to an optimal control problem governed by a linear parabolic equation having the unknown velocity field (the optical flow) as drift term. This model is derived from a new assumption, that is, the brightness intensity is conserved on a moving pattern driven by a Gaussian stochastic process. The optimality conditions are deduced by a passage to the limit technique in an approximating optimal control problem introduced for a regularization purpose. Finally, the controller uniqueness is addressed. 相似文献
The best performing non-precious metal based catalysts for polymer electrolyte membrane fuel cells are manufactured by incorporation of nitrogen into a carbon structure in the presence of iron and cobalt. Herein, density functional theory (DFT) calculations have been performed to investigate the oxygen reduction reaction on catalyst active sites modelled as transition metal macrocycles with iron, cobalt or manganese central atoms. The effects of the transition metal and macrocycle structure have been investigated. The structure of the most promising active sites has been proposed, and the detailed potential energy profiles of the oxygen reduction reaction have been obtained over the active sites, including all intermediate steps with corresponding activation barriers. The efficiency of the active sites depends primarily on the transition metal nature, and the central iron atom accounts for the higher catalytic activity than cobalt and manganese. The central manganese atom can favour the two-electron oxygen reduction pathway and thus yielding hydrogen peroxide. 相似文献
Carbon Fiber Reinforced Polymers (CFRPs) have been increasingly employed for structural strengthening, and are attached to structures using bonding adhesives. The aim of this work is to characterize defects in the bond between CFRP and concrete (after they are located by pulse infrared thermography), and assign the defects a “numerical value” (ranging from 0 for a complete air–gap to 1 for a fully glued bond). Quantitative characterization is performed by measuring the thermal impedance, and then identifying the thermophysical parameters of the system through fitting the measured impedance to a theoretical model. An inversion procedure is carried out to estimate the unknown parameters, without prior knowledge of sample properties. In particular, it is possible to estimate more accurately both the amount of glue within a defect and the thermal contact resistance. 相似文献
Thermo-optical properties of cadmium zinc sulfide (CdZnS) nanoparticle colloids are investigated by interferometry technique. The nanoparticle colloids are synthesized by an improved co-precipitation method. Transmission electron microscopy, UV–vis spectrometry and X-ray diffraction analysis are used to characterize the CdZnS nanocrystals. The thermo-optic coefficient of the colloids has been determined using a Fizeau interferometer. For this purpose, the interference patterns are deformed by a photothermal phase shift which is locally induced in the sample by the focused pump laser beam. The change in the refractive index at this region imposes a shift on the phase of the fringe patterns. Fourier analysis performed on the interference patterns allows us to estimate the values of the thermo-optic coefficient and nonlinear refractive index of the sample. It is shown that the CdZnS nanoparticle colloids enhance the absorption of the laser light and induce high rise in the temperature of the sample, which leads to the nonlinear phase shift. 相似文献
Multicolor emissive carbon dots (M-CDs) have tremendous potential applications in manifold fields of bioimaging, biomedicine and light-emitting devices. Until now, it is still difficult to produce fluorescence tunable CDs with high quantum yield across the entire visible spectra. In this work, a type of M-CDs with concentration-tunable fluorescence and solvent-affected aggregation states was synthesized by solvothermal treatment of citric acid (CA) and 1-(2-pyridylazo)-2-naphthol (PAN) and the formation mechanism was monitored by different reaction time and raw material ratio. The fluorescence spectra of M-CDs in organic solvents can range from 350 to 750 nm by adjusting the concentration. M-CDs possess different aggregation states in water and organic solvents, accompanied by different fluorescence emission, which is attributed to the different surface states of various component CDs in M-CDs. Moreover, the obtained products can be uniformly dispersed into polymethylmethacrylate (PMMA) solutions as well as epoxy resins to fabricate transparent CDs/PMMA films and CDs/epoxy composites, which can effectively prevent the aggregation and produce multicolor and white light-emitting diodes (WLED). In addition, the prepared WLED with Commission Internationale de L’Eclairage (CIE) of (0.29, 0.31) by using M-CDs/epoxy resin as packages, demonstrating the M-CDs exhibit potential applications for light-emitting devices.
Dietary intake of probiotic bacteria has been shown to impart health effects, however, maintaining viable cells in foods and during passage of the adverse conditions in the upper gastro-intestinal tract is often a problem. The objective of this research was to develop and characterize novel food-grade phase-separated gelatin–maltodextrin (G-MD) microspheres, where the gelatin was cross-linked with transglutaminase (TGase), to determine if encapsulated probiotic lactic acid bacteria were protected during exposure to simulated upper gastro-intestinal tract conditions. The stability, size, structure and protective ability of G-MD microspheres as a function of different TGase concentrations and gelatin bloom strengths were tested. The G-MD microspheres made with gelatin A 300 bloom and a TGase concentration of 10 U/g prevented pepsin-induced degradation of the microspheres in simulated gastric juice (pH 2.0, 2 h, 37 °C), resulting in significantly (p < 0.05) higher numbers of survivors due to the buffering effect of intact microspheres (average diameter 46 μm). After sequential incubation in simulated gastric (1 h) and intestinal juices (pH 7.4, 4 h, 37 °C), survivor levels of each of the three encapsulated Lactobacillus sp. (3C2–10, 21C2–10 and 21C2–12) were reduced by 0.2–1 log(CFU/g) as compared to 3–4 log(CFU/g) for the free non-encapsulated cells. This study presents a new protein based microencapsulation method, which using all food-grade ingredients protects probiotic lactic acid bacteria during exposure to adverse environmental conditions. 相似文献