δ掺杂样品中空穴态的新行为

用有效质量理论研究了δ掺杂势中电子和空穴的行为。发现能量接近于δ势垒峰的空穴穿越势垒时能产生一系列谐振态。这些状态中的空穴波函数汇聚在势垒峰周围而同量子限制在势阱中的电子波函数交叠,产生光跃迁。用MBE生长的δ掺杂样品进行光调制光谱测量,发现明显的带间跃迁峰。测得的光谱峰同理论计算的能级相吻合,证实了δ势垒中空穴的新行为。     

Dynamic-mechanical properties of polybutadiene rubbers

The dynamic properties of high-cis (98%) and cis-trans (42% cis) polybutadienes, crosslinked with 0.1 to 1.0% of crosslinking agent, have been studied using a torsion pendulum method over the temperature range ?170 to +20°C. For the high-cis rubber plots of damping factor (tan δ) against temperature showed the expected peak in the glass-transition region with an additional peak in the neighbourhood of 0°C attributable to crystallization. The cis-trans rubber showed two damping maxima in the transition region, separated by 30 to 40°C (depending on the degree of crosslinking), suggesting incipient phase separation of the component structures. The rebound resilience of the high-cis rubber at room temperature exceeded that of the cis-trans, reaching 92% at the highest crosslink density. Plots of resilience versus temperature for both rubbers showed a single minimum in the glass transition region.     

无磷助洗剂δ-层状二硅酸钠

分析了现用助洗剂三聚磷酸钠、4A沸石、偏硅酸钠存在的问题及禁磷的重要性,重点论述了δ-层状结晶二硅酸钠用作助洗剂的各种性能及效果,认为δ-层状结晶二硅酸钠是一种良好的无磷助洗剂,它具有其他助洗剂所不具备的优良性能;对δ-层状结晶二硅酸钠的制备工艺作了简要介绍,并作了市场及在国内工业化生产的可性行分析。     

中温固体电解质Ce_(0.8)Gd_(0.2-x)Y_xO_(2-δ)(x=0,0.05,0.10)的制备与性能研究

用溶胶-凝胶法合成了固体电解质Ce0.8Gd0.2-xYxO2-δ(x=0,0.05,0.10).用X射线衍射谱、拉曼光谱分析了样品的微观结构,用交流复阻抗谱研究了样品的电学性能.结果表明:800℃焙烧的所有样品均为具有氧缺位的单相立方萤石结构,晶胞参数随钇(Y)掺杂量增加而减小.钇掺杂量x=0.05的样品Ce0.8Gd0.15Y0.05O2-δ的电导率最高,导电活化能最小,(σ700℃=5.58×10-3S·cm-1,Eα=0.92 eV),高于未掺杂Y的Ce0.8Gd0.2O2-δ样品的电导率(σ700℃=5.38×10-3S·cm-1Eα=1.09 eV).说明适量双掺杂Y提高了Ce0.8Gd0.2-xYxO2-δ的电导率并且降低了其活化能.     

An inexact hybrid projection-proximal point algorithm for solving generalized mixed variational inequalities

In this paper, we investigate an inexact hybrid projection-proximal method for solving a class of generalized mixed variational inequalities in Hilbert spaces. We construct a general inexact hybrid projection-proximal point algorithm, in which an inexact relaxed proximal point step is followed by a suitable orthogonal projection onto a hyperplane. Under some suitable conditions concerned with the pseudomonotone set-valued mapping T, the nonsmooth convex function f and the step size λ_k, we prove the convergence of the inexact hybrid projection-proximal point algorithm for solving generalized mixed variational inequalities in Hilbert spaces.     

Fe掺杂LSCCF对中低温固体氧化物燃料电池ITSOFC短期输出性能的影响

柠檬酸盐法制备La0.7Sr0.15Ca0.15Co1-xFexO3-δ(x=0.2、0.4、0.6、0.8)阴极材料。该前驱体在900℃处理2h后,XRD证实已经形成完整的钙钛矿结构衍射峰。随Fe掺杂量增加,XRD谱图衍射峰的位置向小角度发生偏移,粉体的晶粒尺寸逐渐变大。SEM观察La0.7Sr0.15Ca0.15Co1-xFexO3-δ粉体其表面活性较高并出现了一定的团聚现象,颗粒尺寸约为5μm。以La0.7Sr0.15Ca0.15Co1-xFexO3-δ为阴极,在氢气/空气中研究了模压法制备的单电池性能,Fe掺杂量对开路电压的高低不起决定性作用,而最高功率密度随Fe掺杂量增加而降低,在650℃最高功率密度由x=0.2时的351.7mW/cm2降为x=0.8时的231.1mW/cm2。     

检测计算CVT电容量方法探讨

介绍对 CVT(电容式电压互感器 )电容量的测试方法及注意事项。由于计算 CVT电容量比较繁琐 ,本文简化计算方法 ,在现场实际应用较方便准确     

浅谈叶片钢中δ-铁素体含量的控制

以低压末级和次末级叶片用钢0Cr17Ni4Cu4Nb为例,重点分析了影响δ-铁素体形成的因素,采用了兼顾化学成分和热加工温度的方法来预测δ-铁素体的形成,证实了EδF由ECr和ET共同决定,控制低的ECr和ET可以有效限制EδF的含量,实验证明ECr的含量控制在8.5以下,锻造温度控制在1300℃以下可以保证低的EδF。通过降低铁素体形成元素的含量,提高奥氏体形成元素的含量,从而获得较低的铬当量,减少了δ-铁素体的形成,为新型叶片钢的开发设计、制造使用提供了可靠的参考数据。     

Preparation of La0.8Sr0.2Cr0.97V0.03O3 − δ films for solid oxide fuel cell application

La_0.8Sr_0.2Cr_0.97V_0.03O_3 − δ (LSC) is commonly studied as a ceramic interconnect material as well as a coating material for metallic interconnects for solid oxide fuel cell applications. However, it is difficult to sinter this type of material to high density. In order to overcome this problem and to study the material in form of a thin film we have used Pulsed Laser Deposition to obtain a dense, uniform film with the right stochiometry. Investigation of preparation-parameter dependence of the LSC films deposited on a stainless steel substrate during pulsed-laser deposition was carried out. The LSC films were deposited with KrF excimer laser (248 nm) on a stainless steel substrate at different oxygen pressure and substrate temperatures. The substrate temperature (873-1073 K) and the oxygen background pressure (5-20 Pa) were varied in order to obtain optimal growth conditions. The surface morphology and structural information of the films were obtained using scanning electron microscope (SEM) and X-ray diffraction, respectively. Under the optimal preparation-parameter conditions: substrate temperature of 1023 K and an oxygen pressure of 10 Pa the structure of the film agreed with the target structure and the SEM micrographs show that the surfaces are homogeneous, smooth, crack-free and dense.