MgO─CeO2烧结助剂对常压烧结氮化硅陶瓷致密化和性能的影响

系统研究了ＭｇＯＣｅＯ２烧结助剂对常压烧结氮化硅陶瓷致密化过程及其性能的影响，发现ＭｇＯＣｅＯ２是一种非常有效的烧结助剂，其致密化效果比单独用ＭｇＯ或ＣｅＯ２要好得多，常压烧结的Ｓｉ３Ｎ４ＭｇＯＣｅＯ２陶瓷，相对密度为９８．５％，室温强度可达９４８ＭＰａ。     

用非晶态合金作中间层对Si3N4陶瓷进行扩散焊连接

研制了两种非晶态物质Ｃｕ５０Ｔｉ５０，Ｃｕ５０Ｔｉ５０Ｂ作为对Ｓｉ３Ｎ４扩散焊连接的中间层材料，研究结果表明，用非晶态作为中间层可改善工艺条件；降低扩散焊温度；非晶态中间层接头比其相应晶态中以接头的剪切强度有明显提高。其中硼对提高接头剪切强度贡献很大。用非晶态Ｃｕ５０Ｔｉ５０Ｂ作中间层时，接头强度最高可达３４０ＭＰａ。用晶态和非晶态Ｃｕ５０Ｔｉ５０，Ｃｕ５０Ｔｉ５０Ｂ作中间层对Ｓｉ３Ｎ４进行扩散焊     

TC4合金激光焊接工艺参数与接头组织性能研究

用OM、SEM等手段分析了不同激光焊接工艺参数下焊缝成形和其微观组织特征，并测试了焊缝的力学性能。结果表明：0．8mm厚钛合金板激光穿透焊离焦量范围约在-2mm～＋2mm之间，最佳离焦量为-0．5mm。随焊接线能量的增大，焊缝熔宽和背面宽度都呈增大趋势，且背面宽度的增加更为显著。TC4合金焊缝为针状马氏体α′组成的网篮组织。随着焊接热输入量的增加，马氏体的形态由平行的单相针转变为多相针，分布更加密集和散乱。不同焊接工艺参数下接头的强度均高于母材，塑性低于母材。     

高密度锂离子电池正极复合材料LiFePO4/C

以FeC2O4-2H2O、NH4H2PO4、Li2CO3和乙炔黑为原料,采用两步固相反应法制备了高密度LiFePO4/C正极复合材料.利用差热(DSC),热重(TGA)和X射线衍射(XRD)等分析手段具体探讨了第一步固相反应中可能存在的反应过程和中间产物.利用扫描电镜表征了复合材料LiFePO4/C中LiFePO4微粒形貌和接触状态.结果表明,乙炔黑的含量是影响LiFePO4微粒尺寸和微粒间接触界面的重要因素.在一次热处理的基础上,二次球磨和烧结有利于第二次固相反应过程中反应物质的接触和传质,较一步固相法提高了生成的LiFePO4的振实密度.当乙炔黑的含量(质量分数)为0.1%～1.5%时,两步固相法所制正极材料LiFePO4/C的振实密度可达到1.7 g/cm3,初次放电容量达到105 mA.h/g.     

扩散处理对Si3N4陶瓷与金属钎焊接头的强化作用

用扫描电子显微镜、能谱仪及X射线衍射仪分析和讨论了复合电镀Ni-Ti陶瓷与金属钎焊接头的强度、微观结构和其界面结合机制。试验表明：扩散处理对陶瓷与金属钎焊接头有强化作用。经辉光扩散处理后，Ti向陶瓷界面扩散，Ni-Ti层与陶瓷发生界面反应。     

挤压温度对Mg-9Gd-4Y-0.6Zr合金组织与力学性能的影响

为提高Mg-9Gd-4Y-0.6Zr合金的强度,研究了不同温度下的挤压组织对合金力学性能的影响。结果表明,随着挤压温度从500℃降低到400℃,其晶粒度也从126μm细化到7.4μm,抗拉强度和延伸率分别从200.1MPa和2.93%提高到312.4 MPa和5.6%。通过力学性能和晶粒尺寸之间的关系计算出该合金的Hall-Petch常数Ky为327.6 MPa.μm1/2,明显高于纯镁及常规镁合金的Ky。大量稀土元素的固溶及其第二相粒子对晶界和位错运动的阻碍作用是合金Ky值较高的主要原因。     

4Cr5MoSiV1钢热轧辊的热处理工艺试验研究

从提高4Cr5MoSiV1钢热轧辊的辊面硬度的角度出发,对于4Cr5MoSiV1钢的热处理工艺进行试验研究,分析了4Cr5MoSiV1钢热处理工艺参数对其性能的影响,所得到的工艺使轧辊辊面硬度和机械性能得到改善,在生产过程中使用良好。     

Mg含量对不同热处理的6000系合金成形性及烤漆硬化性的影响

通过硬度、力学性能及成形性试验,研究了Mg含量对不同热处理的6000系铝合金成形性及烤漆硬化性能的影响.结果表明:T4态合金无论是否模拟酸碱洗加热,进行170℃人工时效后,其时效初期的硬度均呈下降趋势,而元素Mg含量的变化影响不大.固溶淬火态和T4P(5min)态合金在模拟烤漆过程中均未出现软化现象.合金的热处理方式对烤漆硬化性的提高比元素Mg的作用更有效.Mg元素的作用主要改变合金的固溶淬火、T4和T4P态的硬度.随Mg含量增加,固溶淬火态硬度单调升高,而T4和T4P态硬度在Mg含量达到1.7%时降低.Mg对T4和T4P(5min)态合金的力学性能和成形性的影响规律是:增加Mg含量,有利于提高合金的强度,但不利于合金的冲压成形.     

Crystallization and microstructure evolution of amorphous Al85Y4Nd4Ni7 alloy

The mixture model of Al85Y4Nd4Ni7 alloy in which a partially crystallized amorphous alloy is regarded as a nanocomposite of an Al nanoparticle and a remaining amorphous matrix is presented. Its evolution in the process of crystallization has been investigated by differential scanning calorimetry (DSC), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Mainly amorphous structure with α-Al nanocrystals embedded in the amorphous matrix has been revealed by melt spining the alloy. Crystallization is showed to occur in three stages: (I) crystallization of amorphous alloy and formation of A1NiY, A1NdNi and unknown crystalline phases, (2) formation of Al3Y and Al3Nd, and (3) formation of Al3Ni.     

Mechanical properties and microstructure of Ti-6Al-4V compacts by metal injection molding

Ti-6Al-4V compacts were fabricated by metal injection molding(MIM). Influence of vacuum sintering time on mechanical properties and microstructure of the sintered compacts at 1 260 ℃ were investigated. The experimental results show that the compacts sintered at 1 260 ℃ for 3 -6 h, which was made from hydrogenation-dehydrogenation(HDH) powder(average particles size is 45 μm), have a relative density of 95.6%- 96.7%, ultimate tensile strength of 648 - 686MPa and 0.2% yield strength of 526 - 615MPa; but a lower elongation(＜4%) and that the compacts sintered at 1 260 ℃ for 2 - 6 h, which was made from 90% gas-atomized powder(average particles size is 32.5 μm) and 10 % HDH powder, have higher relative density(＞95 %), ultimate tensile strength of 800 -848MPa,0.2% yield strength of 712 - 762MPa and high elongation (7.4%- 9.5%). When the sintering time is increased,porosity decreases and microstructure of sintered products changes from equiaxed to typical Widmanstatten, the average sizes of prior β grains, α colonies and α phase thickness in the β grains increase accordingly. After HIP treatment,pores obviously become less, microstructure of alloy is refined and mechanical properties are greatly improved.