锌釉SiO2-Al2O3性状图的基础研究

研究了锌釉的SiO2-Al2O3性状图。该实验是在确定锌釉的塞格尔式和SiO2、Al2O3变化图的情况下进行，即固定塞格尔式中碱性成分的摩尔量，而按照SiO2、Al2O3变化图有规律的改变SiO2、Al2O3的含量。分别在1100℃、1150℃、1200℃三个温度下，采用氧化气氛烧成制得样品。用肉眼法对样品进行表观效果分析，从而得到相应条件下的锌釉SiO2-Al2O3性状图。     

BaTiO3系PTC热敏电阻用施主加入物的研究

阐述了常用的施主加入物、施主加入量、影响施主加入量的主要因素及各施主加入物的特点。研究了常用的施主加入物的理化指标对ＰＴＣ热敏电阻性能的影响，并据此提出了其技术标准。     

添加剂在固相法制备三氧化二铬中作用的研究

研究了在固相法制备三氧化二铬中多种添加剂对三氧化二铬性能，特别是六价铬残留量和表面性质的影响。     

沉降及外部荷载作用下益阳管廊防护效果分析

地下管廊常因填土沉降和外部荷载等原因造成管廊结构崩溃、接口错位、脱节、管身裂缝、破损等结构损伤。针对填土沉降和外部荷载作用下管廊出现的问题,结合益阳管廊项目,利用FLAC3D有限差分方法模拟土工布对填土沉降的防护以及土工格栅的构造因素对外部荷载作用下的管廊防护进行研究,模拟结果表明:益阳管廊底部铺设土工布可以有效控制填土沉降;管廊上部铺设3层,宽度为12 m的土工格栅有效减轻、分散外部荷载对管廊的作用力。     

框架逆作深基坑变形特性三维数值分析

对基坑的变形特性进行数值分析在基坑设计中至关重要。结合实际工程框架逆作法超大基坑,选用Z Soil数值分析软件建立了全框架基坑模型并进行了数值模拟。由于需要考虑连续墙和土体之间的接触问题,土体则采用能够反映土体硬化特性的Hardening-Soil模型。为了更深刻的认识框架逆作法基坑变形的规律,并为设计者提供更好的参考,对影响框架逆作法基坑变形的一些主要参数进行了系统研究,包括框架梁截面尺寸、框架梁水平支撑竖向间距以及围护桩桩径等。结果表明:改变框架梁水平支撑竖向间距对围护墙的最大侧移、地表最大沉降有较大影响。增大围护桩桩径或框架梁的截面尺寸可以在一定程度上减小围护墙体变形,但超过某一定值时,其减小变形的效果将大大降低。     

载锰氮化碳催化臭氧法降解水中草酸研究

草酸是废水中多种有机物氧化降解的中间产物,与臭氧反应速率很低,难以直接氧化去除。本研究通过热解法煅烧不同摩尔比例的三聚氰胺与醋酸锰(Ⅲ)二水合物,制备出不同负载量的载锰氮化碳催化剂,并研究了不同条件下载锰氮化碳催化臭氧法对草酸的降解效果,考察三聚氰胺与醋酸锰摩尔比、催化剂投加量、p H值、臭氧浓度等因素以及叔丁醇对草酸去除效果的影响。实验结果表明:相对于单独臭氧氧化而言,载锰氮化碳催化臭氧法可以极大的提高草酸的去除率,在投加0.15 g/L三聚氰胺与醋酸锰20∶1的催化剂后,草酸在60 min的TOC去除率可达到89.1%。叔丁醇加入对草酸的去除率影响较小,表明·OH在载锰氮化碳催化氧化草酸的过程中起作用但不是唯一因素。     

Performance of solvothermally prepared Ga2O3-Al2O3 catalysts for SCR of NO with methane

The solvothermal reaction of mixtures of aluminum isopropoxide (AIP) and gallium acetylacetonate (Ga(acac)₃) directly yielded the mixed oxides of γ-Ga₂O₃-Al₂O₃. In the solvothermal synthesis, the crystal structure of mixed oxides was controlled by the initial formation of γ-Ga₂O₃ nuclei. The mixed oxides prepared in diethylenetriamine have extremely high activities for selective catalytic reduction (SCR) of NO with methane as a reducing agent. With increasing crystallite size of the spinel structure, the catalytic activity increased. The ratio of the amount of methane consumed by combustion to total methane conversion was proportional to the density of acid sites on the surface of the mixed oxides. The mixed oxide catalysts prepared in diethylenetriamine had lower densities of acid sites and showed a higher methane-efficiency for CH₄-SCR than those prepared in other solvents. These catalysts maintained their high activity even when the reaction was carried out under the severe conditions (i.e., high space velocity and low NO concentration).     

甲基丙烯酰胺丙基二甲基胺的合成与应用述评

介绍了甲基丙烯酰胺丙基二甲基胺（DMAPMA）的合成工艺路线,重点阐述了该产品在水处理行业、日化行业、造纸加工业、医药行业等中的实际应用.     

1-苯基-3-甲基-5-吡唑啉酮的合成工艺研究

在无水乙醇的存在下，乙酰乙酸乙酯和苯肼为原料合成标题化合物、采用单因素实验法，得到最佳配比为乙酰乙酸乙酯：苯肼=1.05(摩尔比)，无水乙醇50m，反应温度70℃，反应2小时，再回流7小时，收率90．9％，产品纯度99.0％以上。     

3D fingerprint reconstruction system using feature correspondences and prior estimated finger model

The paper studies a 3D fingerprint reconstruction technique based on multi-view touchless fingerprint images. This technique offers a solution for 3D fingerprint image generation and application when only multi-view 2D images are available. However, the difficulties and stresses of 3D fingerprint reconstruction are the establishment of feature correspondences based on 2D touchless fingerprint images and the estimation of the finger shape model. In this paper, several popular used features, such as scale invariant feature transformation (SIFT) feature, ridge feature and minutiae, are employed for correspondences establishment. To extract these fingerprint features accurately, an improved fingerprint enhancement method has been proposed by polishing orientation and ridge frequency maps according to the characteristics of 2D touchless fingerprint images. Therefore, correspondences can be established by adopting hierarchical fingerprint matching approaches. Through an analysis of 440 3D point cloud finger data (220 fingers, 2 pictures each) collected by a 3D scanning technique, i.e., the structured light illumination (SLI) method, the finger shape model is estimated. It is found that the binary quadratic function is more suitable for the finger shape model than the other mixed model tested in this paper. In our experiments, the reconstruction accuracy is illustrated by constructing a cylinder. Furthermore, results obtained from different fingerprint feature correspondences are analyzed and compared to show which features are more suitable for 3D fingerprint images generation.