Reaction Coupling of Ethylbenzene Dehydrogenation with Nitrobenzene Hydrogenation

The chemical equilibrium for the coupling of ethylbenzene dehydrogenation with nitrobenzene hydrogenation, to produce styrene and aniline simultaneously, has been calculated on the basis of the Soave–Redlich–Kwong equation of state. The dehydrogenation of ethylbenzene in the presence of nitrobenzene over the catalysts -Al₂O₃, ZSM-5, activated carbon and platinum supported on activated carbon has been carried out at 400 °C. The effects of Pt loading and the pretreatment of the catalysts have been investigated. It has been revealed that the conversion of ethylbenzene can be greatly improved by the reaction coupling due to the elimination of the hydrogen produced in the reaction by the hydrogenation of nitrobenzene. Platinum supported on the activated carbon has been suggested as a suitable catalyst. The best results with ethylbenzene conversion of 33.8% and styrene selectivity of 99.2% were obtained over Pt(0.02 wt%)/AC at 400 °C. Moreover, such process is also energetically favored since the necessary process heat to drive the ethylbenzene dehydrogenation can be provided by the coupling with the exothermic nitrobenzene hydrogenation reaction.     

A study of PtRuO2 catalysts thermally formed on titanium mesh for methanol oxidation

Platinum-based catalysts, for the electro-oxidation of methanol, have been made by thermal decomposition of chloride precursors onto titanium mesh. The catalysed electrodes were successfully operated in acidic methanol electrolytes. Electrochemical characterisation has been carried out using cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic polarisations. A complete analysis of the electrochemical results showed that the preliminary performance of the catalysed titanium mesh was comparable to that achieved with carbon-supported PtRu catalysts. The catalysts formed on titanium mesh by thermal decomposition also exhibited dimensional stability. Catalysed titanium mesh therefore appears to be a promising alternative to carbon-supported catalysts for certain fuel cell applications.     

一种32位浮点型处理器的励磁控制器设计

针对同步发电机励磁控制系统在控制精度和控制稳定性方面存在的不足,通过对国内外励磁控制系统发展状况的分析,提出了一种基于32位浮点型处理器的数字式励磁控制系统.该系统通过将先进的交流采样算法和DSP的优异性能相结合,实现了励磁控制器的深度数字化;通过对同步发电机系统关键模拟量的采集与计算,得出适用于当前工况下触发脉冲角度α.试验验证了该设计能很好地解决发电机励磁控制系统中的稳定性问题.     

15%恶霉灵防治水稻立枯病药效试验

田间试验表明，15％恶霉灵水剂6～8ml／m^2，对水稻立枯病的防效可达82.3％，病指防效可达89.4％，明显好于对照药剂。而且对水稻安全，能够提高秧苗素质。     

卧螺离心机共直流母线双电机双变频驱动

介绍了卧螺离心机差转速自动控制共直流母线变频调速系统的结构,分析了工作原理和节能效果,介绍了直流母线的两种并接方法。     

Measurement of AC conductivity and dielectric properties of flexible conductive styrene–butadiene rubber‐carbon black composites

Flexible conductive polymer composites were prepared using styrene–butadiene rubber (SBR) as a matrix and conductive carbon black as filler. The filler loading was varied from 10 to 60 phr. The effect of frequency, filler loading, temperature, and applied pressure on the AC conductivity, permittivity, and loss factor of the composites was studied. The AC conductivity of low and high loaded composites was found to be frequency dependent and independent respectively. The permittivity and the loss factor were continuously decreasing with increasing frequency. The increase in filler loading increased the AC conductivity, dielectric constant, and loss factor of the composites. Increase in temperature imposed increase in conductivity and permittivity of the composites. With increasing applied pressure the properties showed exponential increase. The effect of time under a constant compressive stress was studied and dielectric relaxation times were evaluated. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 986–995, 2007     

一种交流调速的高精度采样系统设计

基于TMS320F2812内部自带ADC模块的优缺点分析,探讨扩展ADS8365的高精度采样系统设计,以求提高整个系统的测量和控制精度,实现数字化变频调速系统中对多路电压、电流、转速等信号的高精度采样.讨论了影响TMS320F2812芯片A/D转换器精度的原因,给出了ADS8365芯片进行电流信号采样的电路设计,并通过仿真和实际电路实验说明了电路设计的有效性.相比于TMS320F2812的单端采样,基于ADS8365的采样电路具有采样精度高、速度快、同步性好、失真小、抗干扰强,同时能够较好的抑制温漂和热噪声等明显优势.将该采样电路应用于本交流调速系统中,不仅可以大大提高系统的采样精度,增加系统的抗干扰性,也便于系统工况的实时分析,进行合理控制及实时保护.     

4U节能灯电路工作原理分析及工作参数测试

设计了一种4U节能灯电路,系统论述了电路工作原理,测试了电路的主要工作参数,分析了几种常见电路故障产生的原因.实验证明本节能灯电路具有低电压启辉、无频闪、无噪音、高效节能、开灯瞬间即亮、使用寿命长、保护措施较完善等优点.     

微小型工业汽轮机智能交流伺服调节系统研究

为了解决微小型工业汽轮机组调节控制系统设备简陋,动态响应和稳态精确度差的问题,提出了一种采用交流伺服电机和模糊PID控制的自动调节系统．在对调节系统部件特性数据进行分析的基础上,应用机理分析法建立了工业汽轮机交流伺服调节系统的数学模型,建立了以模糊PID控制和常规PID为主的控制器仿真模型,并利用MATLAB（SIMULINK）进行了动态仿真．结果表明,采用交流伺服电机作为执行器比传统的机械式调节系统具有更优良的动态和稳态性;采用模糊PID控制策略的调节系统在减少调节时间、改善动态品质方面均好于常规PID调节器．为工业汽轮机交流伺服调节系统的进一步研究提供了理论基础．     

基于DPI的流量识别系统的研究

随着网络应用的多样化,各种网络流量不断复杂化、多样化,各种网络安全事故频发.网络流量的分布不均匀以及网络安全状况的复杂使得互联网急需管理和维护,网络流量的监控问题变得尤为重要.流量识别作为一种能够自动、实时保障网络监控的技术,成为防火墙一类静态安全设备的必要补充,越来越受到人们的重视.深度包监测（DPI）技术以其识别的准确性成为应用越来越广泛的识别技术.然而单纯的软件实现系统监测速度较慢,不能满足网络高速数据包处理的吞吐量要求.单纯的硬件识别知识库会占用大量内存,一般的硬件内存达不到要求.单纯的软件识别效率又不能满足越来越大的网络吞吐量需求.这种情况下,文章研究了一种基于正则表达式的软硬件结合系统实现方法,该方法的主要思想是硬件识别网络常见协议,软件识别复杂的网络协议,且两者都支持正则表达式.这种方法兼具软件与硬件实现的优点,与传统的软件实现相比,在识别效率方面有明显提高.