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141.
原位聚合制备尼龙6/纳米SiO2复合材料研究 总被引:10,自引:0,他引:10
对原位聚合制备尼龙6/纳米SiO2进行研究。结果表明,无论是否对纳米SiO2复合材料进行偶联化处理,其表面均将在原位聚合过程中与尼龙6产生接枝;SiO2表面接枝物的生成,可在某种程度上造成体系结晶程度的降低,但复合体系的力学性能主要由SiO2粒子的分散程度、粒子和其体之间的相界面性质等因素决定;采用经偶联剂处理并具有较小粒径和较大比表面积的SiO2对尼龙6进行复合,可使复合体系的力学性能指标达到较高的水平,且硅烷偶联剂的最佳用是为SiO2的3%左右。 相似文献
142.
《Fuel》2003,82(2):147-151
The aim of this paper is to show how a cheap carbonaceous material such as low rank coal-based carbon (or char) can be used in the combined SO2/NO removal from exhaust gas at the linear gas velocity used in commercial systems (0.12 m s−1). Char is produced from carbonization and optionally activated with steam. This char is used in a first step to abate the SO2 concentration at the following conditions: 100 °C, space velocity of 3600 h−1, 6% O2, 10% H2O, 1000 ppmv SO2, 1000 ppmv NO and N2 as remainder. In a second step, when the SO2 concentration in the flue gas is low, NO is reduced to N2 and steam at the following experimental conditions: 150 °C, space velocity of 900 h−1, 6% O2, 10% H2O, 0-500 ppmv SO2, 1000 ppmv NO, 1000 ppmv NH3 and N2 as remainder.It has been shown that the presence of NO has no effect on SO2 abatement during the first step of combined SO2/NO removal system and that low SO2 inlet concentration has a negligible effect on NO reduction in the second step. Moreover, this char can be thermally regenerated after use for various cycles without loss of activity. On the other hand, this regenerated char shows the highest NO removal activity (compared to parent chars, either carbonized or steam activated) which can be attributed to the activating effect of the sulfuric acid formed during the first step of the combined SO2/NO removal system. 相似文献
143.
本文设计并实现了基于J2EE的高校教师业务管理系统.文章详细讨论了系统实现的业务模型、功能模型等需求分析过程,以及系统架构、通用查询框架、基于角色访问控制策略的“用户一角色.功能模块”的权限管理系统设计与实现等关键技术. 相似文献
144.
145.
D. Miceli F. Arena A. Parmaliana M. S. Scurrell V. Sokolovskii 《Catalysis Letters》1993,18(3):283-288
Precipitated silica catalysts loaded with either MoO3 (0.2–4.0 wt%) or V2O5 (0.2–5.3 wt%) have been studied in the selective partial oxidation of methane to formaldehyde with molecular oxygen at 520 °C. The functionality of the SiO2 surface towards the formation of HCHO is significantly promoted by V2O5, while it is depressed by the MoO3. 相似文献
146.
The present study investigates the decomposition of N-Methyl-2-Pyrolidone (NMP) using conventional ozonation (O3), ozonation in the presence of UV light (UV/O3), hydrogen peroxide (O3/H2O2), and UV/H2O2 processes under various experimental conditions. The influence of solution pH, ozone gas flow dosage, and H2O2 dosage on the degradation of NMP was studied. All ozone-based advanced oxidation processes (AOPs) were efficient in alkaline medium, whereas the UV/H2O2 process was efficient in acidic medium. Increasing ozone gas flow dosage would accelerate the degradation of NMP up to certain level beyond which no positive effect was observed in ozonation as well as UV light enhanced ozonation processes. Hydrogen peroxide dosage strongly influenced the degradation of NMP and a hydrogen peroxide dosage of 0.75 g/L and 0.5 g/L was found to be the optimum dosage in UV/H2O2 and O3/H2O2 processes, respectively. The UV/O3 process was most efficient in TOC removal. Overall it can be concluded that ozonation and ozone-based AOPs are promising processes for an efficient removal of NMP in wastewater. 相似文献
147.
PdOx/MnO2 has been examined as a catalyst for CO oxidation using a conventional flow reactor at reaction temperatures between 50 and 150°C. In the reaction conditions of GHSV (gashourlyspacevelocity) of 1.22 × 105/h and CO concentration of 2000 ppm, PdOx/MnO2 showed higher catalytic activity compared with PdOx/Mn2O3, which had been previously reported as an effective catalyst due to the cooperative action of Pd and Mn2O3 for this reaction. The reason for higher activity of PdOx/MnO2 than PdOx/Mn2O3 has been investigated using TPR (temperatureprogrammed reduction) and XPS studies. TPR showed that PdOx/MnO2 could be reduced by CO at much lower temperature than PdOx/Mn2O3. During the experiment of reduction and oxidation, XPS showed that the valence of Mn in the PdOx/MnO2 was between 4+ and 3+, which is higher than that of Mn in the PdOx/Mn2O3 catalyst of which the valence has been reported to be between 3+ and 2+. It is known that in this catalyst system the support supplies oxygen onto Pd, where the oxidation occurs with adsorbed CO, and the ability of the support to provide oxygen improves the performance of the catalyst. Therefore, it was concluded that the readiness of MnO2 to be reduced with maintaining a higher oxidation state showed higher CO oxidation activity than Mn2O3 as support for PdOx. 相似文献
148.
CeO2 particles confined within the pores of an SBA-15 mesoporous silica host were prepared by incipient wetness impregnation (IMP)
and deposition precipitation (DP) methods. The materials were characterized by XRD, N2-adsorption and temperature programmed reduction (TPR) to evaluate the structure, texture, and redox properties. The preparation
procedure had significant impact on the assembling mode of CeO2 inside the SBA-15 mesopores. A high dispersion of CeO2 particles was achieved via DP, whereas the dispersion of CeO2 prepared by IMP was found to be inhomogeneous and CeO2 partially blocked the pores. The CO conversion in the water-gas-shift reaction was enhanced over 1 wt% Pt supported on CeO2-modified SBA-15 obtained by DP. 相似文献
149.
张庆华 《数字社区&智能家居》2014,(7):4381-4383
该文介绍了基于B/S资料信息管理系统的设计和开发,重点阐述了资料信息管理系统的开发设计的难点和要点,同时提供了部分数据库表信息和代码。 相似文献
150.
周宇舸 《数字社区&智能家居》2014,(5):960-961,981
该文简单介绍了B/S网络应用开发架构,详细阐述了网页闹铃功能设计,并对原理进行了详细的讲解,对功能做了进一步的实现,展示了运行效果。 相似文献