Quaternary Ammonium Salts (QAS) Modified Polysiloxane Biocide Supported on Silica Materials

Three types of silica particles modified with vinyl groups were obtained: (i) xerogel formed by hydrolytic polycondensation of the mixture of tetramethoxysilane (TMOS) and 1,1,1,7−tetramethoxy-3,5,7-trimethyl-3,5,7-trivinyltetrasiloxane, (ii) mesoporous silica obtained from the same precursors in the presence of the cetyltrimethylammonium bromide (CTAB), and (iii) commercial Fluka silica gel 60A with a vinyltriethoxysilane-treated surface. Vinyl groups on these silica materials were transformed into silyl chloride by hydrosilylation with HMe₂SiCl. These groups were used to graft living polysiloxane that was synthesized by anionic ring-opening polymerization of 2,4,6-tri(3-chloropropyl)-2,4,6-trimethylcyclotrisiloxane and initiated by BuLi. Chloropropyl groups on the grafted polymer were used to quaternize N,N-dimethyl-n-octylamine. Silica particles with grafted polysiloxane having quaternary ammonium salt (QAS) groups pendant to polymer chains were obtained. Silica material with QAS groups directly attached to the surface were generated by the action of N,N-dimethyl-n-octylamine on particles obtained by the sol–gel process involving tetraethoxysilane (TEOS) with 3-chloropropyltriethoxysilane. The bacteriocidal properties of all these materials were tested in water suspension against five representative strains for Gram-positive and Gram-negative bacteria. Some of the silica–polysiloxane hybrid materials have good antibacterial properties against Gram-positive strains, but not as good as the non-tethered QAS-substituted polysiloxane in water solution. The QAS groups that are directly bonded to the silica material surface are inactive.     

Corrosion of amorphous and nanocrystalline Fe-based alloys and its influence on their magnetic behavior

Nanocrystalline soft magnetic materials with low coercivity, high saturation magnetization and high permeability are commonly used as cores in transformers and generators in stress and field sensors. The influence of factors connected with corrosion is almost impossible to eliminate. In the present work, a comparative study of the electrochemical behavior of Fe₇₈Si₁₃B₉ and Fe_73.5Si_13.5B₉Nb₃Cu₁ amorphous and nanocrystallized alloys, tested in 0.5 M NaCl solution, has been performed by linear polarization and electrochemical impedance spectroscopy methods. Changes of magnetic properties including coercivity, induction and magnetic retentivity were analyzed. These properties were investigated as a function of the structure of primary amorphous ribbons and as a function of corrosion environment type, in which longitudinally and transversely cut ribbon specimens were exposed for 15 days. The best magnetic properties were found for the Fe₇₈Si₉B₁₃ ribbon after a structural relaxation at a temperature of 350 °C for an hour and for the Fe_73.5Si_13.5B₉Nb₃Cu₁ ribbon after a primary crystallization at a temperature of 550 °C for an hour. Corrosion did not cause the direct degradation of the magnetic properties of the Fe₇₈Si₉B₁₃ and Fe_73.5Si_13.5B₉Nb₃Cu₁ alloys. The corrosion processes occurring on the surface of the Fe_73.5Si_13.5B₉Nb₃Cu₁ alloy ribbon with the amorphous structures improve induction B_s. Most probably it is connected with the decrease of undesirable stresses blocking a motion of magnetic domain walls on the ribbon surface. Changes of corrosion mechanism depending on structure and applied solution were analyzed. The electrochemical impedance experiment were performed at open circuit potential for amorphous and nanocrystalline specimens. Two electrochemical corrosion mechanisms of Fe_73.5Si_13.5B₉Nb₃Cu₁ alloy in 0.5 M NaCl solution were found. Charge transfer control mechanism is typical for amorphous (as received) alloys. Mixed mechanism-mass transport and charge transfer controlled was observed for nanocrystalline Fe_73.5Si_13.5B₉Nb₃Cu₁ alloy.     

用厚度阈值法改善深拉延冲压件坯料形状预测精度

将作者首次提出的厚度阈值法应用到基于逆有限元原理的坯料形状预测算法中,有效地改进了深拉延冲压件坯料形状预测的精度,并以某汽车油底壳拉延件为实际算例,分别用改进前和改进后的算法,对其坯料形状进行预测,预测结果与实际坯料形状的对比结果验证了本文方法的有效性。     

Mode III fracture of a magnetoelectroelastic layer: exact solution and discussion of the crack face electromagnetic boundary conditions

This paper develops a closed-form solution for anti-plane mechanical and in plane electric and magnetic fields in a magnetoelectroelastic layer of finite thickness. Explicit expressions for the stresses, electric fields, and magnetic fields, together with their intensity factors are obtained for the extreme cases for impermeable and permeable cracks. Solutions for some special cases, such as a magnetoelectroelastic layer with infinite thickness, are also obtained. Applicability of the crack face electromagnetic boundary conditions is discussed. It is found that the crack profile is important in obtaining the correct electromagnetic fields and their intensity factors. The stress intensity factor, however, does not depend on the crack face electromagnetic boundary condition assumptions.     

Meshless local Petrov-Galerkin method for continuously nonhomogeneous linear viscoelastic solids

A meshless method based on the local Petrov-Galerkin approach is proposed for the solution of quasi-static and transient dynamic problems in two-dimensional (2-D) nonhomogeneous linear viscoelastic media. A unit step function is used as the test functions in the local weak form. It is leading to local boundary integral equations (LBIEs) involving only a domain-integral in the case of transient dynamic problems. The correspondence principle is applied to such nonhomogeneous linear viscoelastic solids where relaxation moduli are separable in space and time variables. Then, the LBIEs are formulated for the Laplace-transformed viscoelastic problem. The analyzed domain is covered by small subdomains with a simple geometry such as circles in 2-D problems. The moving least squares (MLS) method is used for approximation of physical quantities in LBIEs.     

纳米技术的杰作——纳米吸波材料

纳米吸波材料作为一种有着巨大发展前景的高技术功能材料，成为未来吸波材料的发展方向。本文从介绍纳米吸波材料的结构特征和吸波特点出发，说明了纳米吸波材料的独特吸波性能，同时对几种蚋米吸波材料进行了介绍。通过对现阶段国内外纳米吸波材料研究进展的评速与讨论，总结出其宽频化、复合化、低维化和智能化的未来发展趋势。     

Base Pressure Measurements under a Scale Model Stockpile

The ability of a granular bulk material to transmit internal shear stress is a fundamental property that is often overlooked or underestimated, yet it is this ability that allows many observed physical phenomena to occur. One such area that continues to be a focus for numerical, theoreticals and experimental researchers is the pressure that a stockpile of granular material places on the supporting surface. While appearing to be a simple problem, the ability of granular materials to transmit shear stress makes this an extremely complex problem. This article presents high-quality data collected under a 2 m high stockpile and full details of the experimental facilities used in the collection of the data.

The work presented is of significant value, having a much greater scale than previous studies (Jotaki & Moriyama, 1979; Lee & Herington, 1971; Smid & Novosad, 1981), and the deliberate inclusion of a central reclaim channel offers insight into stress changes during gravity reclaim and refilling. The results of this work have shown that the so-called 'M' pressure does exist under larger stockpiles both with and without reclaim hoppers; of more significance is the reemergence of the M pressure upon refilling of an emptied stockpile. This clearly illustrates that the M pressure is a robust and natural pressure distribution for a conical stockpile.     

Rapid additive manufacturing of functionally graded structures using simultaneous wire and powder laser deposition

Laser additive fabrication allows the manufacturing of functionally graded structures that are not possible using conventional subtractive manufacturing. Laser deposition of injected powders with varying compositions, layer-by-layer, is often used for the building up of functionally graded fully dense structures or materials. This approach, however, has some drawbacks: the un-used powders (normally 60-80%) cannot be recycled as they will be contaminated by the powder mixture. In addition, multiple passes are needed to develop functionally graded structures. This paper reports the feasibility and characteristics of using simultaneous powder and wire feeding laser deposition to produce functionally graded structures in a single step. This approach has been shown to eliminate the above problems associated with powder feed laser deposition. In this work, copper powder and nickel wire have been used to deposit functionally grated copper/nickel/iron structures on H13 tool steel. A 1.5-kW diode laser is used for the build-up process. Electron probe microanalysis (EPMA), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD) and optical microscopy are used to analyse the deposited materials in terms of morphology, composition distributions, microstructures and phases formed. Successful deposition of functionally graded Cu-Ni-Fe structures has been demonstrated. Comparisons are made with the dual powder feed deposition process, which shows the inclusion of un-melted Ni powders in the Cu layer as a result of melting temperature difference of the two materials.     

Active damping of rotating composite thin-walled beams using MFC actuators and PVDF sensors

The object of this research is to enhance the damping performance for vibration suppression of rotating composite thin-walled beams using MFC actuators and PVDF sensors. The formulation is based on single cell composite beam including a warping function, centrifugal force, Coriolis acceleration and piezoelectric effect. Adaptive capability of the beam is acquired through the use of a negative velocity feedback control algorithm. Numerical analysis is performed using finite element method and Newmark time integration method is used to calculate the time response of the model. It is observed that the feedback control gain has an effect on damping performance. The paper continues with an investigation into influences of parameters such as the rotating speed and the fiber orientation in host structures. Also, it is confirmed that effective damping performance is achievable through the suitable arrangement and distributed size of sensor and actuator pair using case study.     

Thermal fracture analysis of orthotropic functionally graded materials using an equivalent domain integral approach

A new computational method based on the equivalent domain integral (EDI) is developed for mode I fracture analysis of orthotropic functionally graded materials (FGMs) subjected to thermal stresses. By using the constitutive relations of plane orthotropic thermoelasticity, generalized definition of the J-integral is converted to an equivalent domain integral to calculate the thermal stress intensity factor. In the formulation of the EDI approach, all the required thermomechanical properties are assumed to have continuous spatial variations through the functionally graded medium. Developed methodology is integrated into a fracture mechanics research finite element code FRAC2D using graded finite elements that possess cubic interpolation. Steady-state and transient temperature distribution profiles in orthotropic FGMs are computed using the finite elements based heat transfer analysis software HEAT2D. EDI method is validated and domain independence is demonstrated by comparing the numerical results obtained using EDI to those calculated by an enriched finite element method and to those available in the literature. Single and periodic edge crack problems in orthotropic FGMs are examined in order to study the influences of principal thermal expansion coefficient and thermal conductivity components, relative crack length and crack periodicity on the thermal stress intensity factors. Numerical results show that among the three principal thermal expansion coefficient components, the in-plane component perpendicular to the crack axis has the most significant influence on the mode I stress intensity factor. Gradation profile of the thermal expansion coefficient parallel to the crack axis is shown to have no effect on the outcome of the fracture analysis.