氧化还原引发降解天然橡胶与丙烯酸酯共聚的研究

研究了降解天然橡胶胶乳与丙烯酸甲酯、丙烯酸丁酯的聚合，以过氧化苯甲酰—N，N—三甲基苯胺(BP0—DMA)为氧化还原引发剂，考察了不同反应温度、引发剂配比、乳化剂用量及加料方式对单体转化率和接枝率的影响；用红外光谱对共聚物进行了表征。结果表明，采用乳化还原引发剂可使聚合反应低温快速进行，过量还原剂起阻聚作用，采用复合乳化剂可提高聚合反应速度和乳液稳定性，补加料可提高接技率。     

热管省煤器在120 kt/a硫磺制酸系统中的应用

介绍120kt／a硫磺制酸装置转化工段两台热管省煤器的结构特点和应用情况。转化器第三段出口冷换热器后的省煤器为水箱式热管省煤器，锅炉给水在水箱内与热管内工质换热；五段出口省煤器为夹套式热管省煤器，锅炉给水在套管与热管的间隙内被工质加热：两台热管省煤器的蒸发段与放热段之间均由管板隔离，以防止烟气对水侧管壁面的腐蚀，热管省煤器具有运行费用低、操作安全稳定等优点。通过严格控制锅炉给水质量和正确的开停车操作，近两年来热管省煤器运行良好，未发生泄漏故障：     

基于三电平逆变的开关磁阻发电系统的研究

新型开关磁阻发电机具有发电容量大、效率高、起动和发电组合容易等优点,三电平逆变器具有能减少开关损耗和滤波电感损耗并有降低开关应力等特点。利用三电平逆变器转换效率高的优势,结合新型开关磁阻发电机低风速发电特点,降低开关损耗和开关器件电压应力,提高装置可靠性。仿真实验结果表明:用三电平逆变器能够很好的实现开关磁阻发电机的逆变要求。     

基于ACS712的直流电机电流监测系统的设计

设计了直流电机运行电流的硬件采集电路,解决了高速下电枢绕组电流的采集问题。利用霍尔电流传感器ACS712通过AD转换将采集到的绕组电流数据,通过串口和上位机进行通信,实现了本机LCD液晶显示和基于LabVIEW的软件界面显示电流数据,具有实际的工程意义。     

PLC控制电梯教学模型的设计

根据电梯系统的结构特点及控制要求,设计了基于PLC控制的电梯教学模型。详细阐述了模型电梯系统的硬件构成和软件实现方法。试验表明,该实验装置提高了PLC实验课的教学质量。     

CMOS图像传感器中分段电容DAC非理想因素研究

CMOS图像传感器信号处理中通常采用分段电容DAC产生斜坡参考电压。研究了分段电容DAC精确的电容失配及寄生与其转换精度的关系式。基于对分段电容DAC工作原理的研究,导出了电容失配及寄生模型;针对其分数桥接电容失配、各二进制电容间的失配及寄生电容问题进行了理论分析;对分段电容DAC进行非理想因素仿真,设计了一个采用分段电容DAC的10位单斜ADC并对其进行测试,仿真和测试结果均验证了理论分析的正确性。上述理论分析结果可作为分段电容DAC的设计指导。     

Mechanosynthesis of complex oxides and preparation of mixed conducting nanocomposites for catalytic membrane reactors

Nanopowders of LaGaO₃- and LaMnO₃-based complex perovskites (P) and ceria-based fluorites (F) were prepared by mechanosynthesis. Compatible nanocomposites F + P and P + P with mixed ion and electron conducting (MIEC) properties were prepared and sintered at moderate temperatures up to dense ceramics. The obtained materials were studied by means of XRD, SEM, TEM, electrical conductivity measurements, temperature programmed (TP) reduction/oxidation and preliminary estimations of permeability were obtained. A new strategy based on the advantages of the mechanochemical ceramic approach is proposed to design multilayer ceramic membranes for CMR. Casting technology and one-step sintering were used for the production of thin film membranes with MIEC properties on porous substrates. The coarse fraction of as-milled powders from agglomerates with density 70% was used for the porous substrate, and fine fractions of aggregates with sizes <1 μm were used in preparation of composites for thin dense films. Ceria-based composites prepared by the Pechini route and/or mechanochemical method are proposed as materials for protecting thin films.     

低CO2选择性的合成气制轻烯烃双功能催化剂

为开发高活性、高收率的合成气制低碳烯烃（STO）双功能催化剂，通过共沉淀法制备非化学计量尖晶石Zn-Cr-Al氧化物，对其织构性质、晶体结构、形貌特征以及表面电荷性质等进行研究。结果表明添加过量锌能够促进晶体粒径减小，表面氧空位增多。其中Zn/(Cr+Al)摩尔比为1.25时锌含量较为适宜，将其与SAPO-34沸石分子筛结合为双功能催化剂用于STO性能研究。在进气n(H2):n(CO)=2:1，3000 mL/(gcat·h)，3.2 MPa，400 ℃反应条件下，实现46.9% CO转化率，C2-4烯烃收率高达15.9%，高于大部分已有文献报道（8~14%），特别是副产物CO2选择性仅29.2%，低于普遍报道的40~50% CO2选择性。并且催化剂运行100 h后活性良好，稳定的催化性能使其具有工业应用价值。     

Color recovery of black-and-white halftoned images via categorized color-embedding look-up tables

A new method of recovering the original colors of black-and-white (B&W) halftoned images with homogeneous dot patterns is proposed. The conventional inverse halftoning method, which uses a look-up table (LUT), can establish the relation between the halftoned patterns and the corresponding gray levels, while the conventional reversible color to gray conversion method can recover the original colors from a given color-embedded gray image. To accomplish our goal of original color recovery from B&W halftoned patterns, an approach of combining the conventional inverse halftoning and reversible color to gray conversion is presented in this paper. Differently from the conventional method of inverse halftoning via LUT, four LUTs categorized according to the red, green, blue, and gray reference colors are designed to more accurately map a specific B&W halftone pattern into the corresponding color-embedded gray level based on the observation that the shapes of the halftone patterns depend on input colors, thereby increasing the color recovery accuracy. Also, a color mapping method based on a linear regression which models the relation between the recovered colors and the original colors is introduced to adjust the initially recovered colors more closely to the original colors. Experimental results show that unknown original colors can be recovered from B&W halftoned images via the proposed method.     

双NIOSⅡ软核系统在潮流能发电中的应用

开发海洋潮流能对缓解能源危机具有重要意义,电力变换系统是潮流能发电系统的关键技术之一。提出了一种利用SOPC技术实现潮流能发电电力变换控制系统的设计方法,采用单片高性能FPGA芯片构建双NIOSⅡ软核系统,其中一个NIOSⅡ处理器负责系统任务调度和能量管理,一个NIOSⅡ处理器负责电力变换控制和异常诊断。针对电力变换系统的信息数据特点,提出了基于RAM、FIFO、GPIO的双NIOSⅡ处理器握手机制,并给出了系统的具体设计实现。该双NIOSⅡ处理器系统提高了系统的任务调度灵活性、控制算法处理速度和应急处理能力。