运用BP网络分析尿素合成塔CO_2转化率

采用BP神经网络模型预测尿素合成塔CO_2 转化率 ,分析了氨碳比和水碳比与转化率之间的关系。详细介绍了建模过程并对隐含层神经元数和迭代次数对网络性能的影响进行了讨论。分析结果表明 :所建模型能准确地对CO_2 转化率进行预测 ,平均相对误差在 1 0 %以内 ;CO_2 转化率随氨碳比的增大而显著增加 ,水碳比的影响则相对较小。     

氨合成塔触媒升温还原中水汽浓度分析方法改进

采用电石转化氢焰色谱法,用TDX-01固定相为分离柱,分析氨合成塔触媒升温还原中水汽浓度。     

基于BIM数据的建筑抗震弹塑性分析建模技术

针对建筑信息模型(Building Information Model,BIM)的共享数据标准为IFC标准,但现有软件导出的IFC格式模型缺少关键数据,不能满足结构非线性抗震分析数据需求的问题,提出建筑抗震弹塑性分析数据基于IFC标准的表达方法,编写C++转换程序将BIM包含的数据正确地转换成不同软件(如Marc和OpenSees等)的模型,从而可以使用不同的结构分析软件实现建筑抗震弹塑性分析.该方法为基于BIM数据实现建筑抗震弹塑性分析提供参考.     

Catalytic conversion of methane to benzene over Mo/ZSM-5

Dehydroaromatization of methane to benzene occurs over a 2 wt% Mo/ZSM-5 catalyst at 700C under non-oxidizing conditions. Following an initial induction period, during which CH₄ reactant reduces the original Mo⁶⁺ ions in the zeolite to Mo₂C and deposition of coke occurs, a benzene selectivity of 70% at a CH₄ conversion of 8–10% could be sustained for more than 16 h. X-ray photoelectron spectroscopy and X-ray powder diffraction measurements indicate that the reduced Mo is highly dispersed in the channels of the zeolite. Initial activation of CH₄ reactant occurs on Mo₂C sites, leading to the formation of C₂H₄ as the primary product. The latter then undergoes subsequent oligomerization reactions on acidic sites of the zeolite to form aromatic products.     

降低全低变工艺阻力的措施

将变换流程改为全低变工艺后,吨氨蒸汽消耗明显下降,但触媒床层阻力迅速上升.通过采取增设焦炭过滤器、更换触媒、改进蒸汽分布器等一系列措施,不仅保证了正常的生产指标,而且还使变换炉的阻力有了明显下降,取得了满意的效果.     

Kinetic modelling of the catalytic conversion of synthesis gas

A kinetic study for the one-step conversion of synthesis gas to gasoline on a ZnO–Cr₂O₃–ZSM-5 catalyst is described. On this catalyst, three reactions are involved in the overall transformation of synthesis gas: the methanol synthesis, the conversion of methanol to hydrocarbons and the water–gas shift reaction. Under the operating conditions selected for the study, it was found that the water–gas shift was at equilibrium and the methanol was completely converted to hydrocarbons. Consequently, it was postulated that the kinetics of the limiting reaction step, the methanol synthesis on the ZnO–Cr₂O₃ component, was the one that controls the overall reaction rate. Three kinetic model equations describing the rate of synthesis gas conversion on the bifunctional catalyst, were considered to fit the data of the experimental runs performed in a Berty well-mixed reactor. Those equations were derived under very special conditions where the methanol decomposition term could be neglected. It was also observed that in the kinetic equations a term involving the fugacity of CO₂ was required to predict the rate properly. The catalyst deactivation was also taken into account in the analysis.     

作物秸秆能源转化技术研究进展

利用作物秸秆生产可再生能源是解决秸秆环境污染和开辟新的能量资源的重要途径之一。作物秸秆能源转化技术主要有热解气化、厌氧消化、液化、乙醇化、直接燃烧和固化等。简要介绍了我国作物秸秆的资源量及利用现状,着重对国内外作物秸秆能源转化技术的发展、研究现状及工业化应用情况进行了详细介绍。通过对各技术特点和存在问题的分析,探讨了未来发展趋势。建议加强作物秸秆液化与乙醇化技术的系统性研究以及工艺过程的开发。     

塔里木河干流人工与天然绿洲转化及适宜比例研究

利用1990,2000,2010年3期Landsat TM/ETM遥感影像,基于RS/GIS技术,分别提取土地利用/覆被类型信息,分析1990~2010年塔里木河流域人工绿洲和天然绿洲的变化规律及其比例,探讨该区人工绿洲和天然绿洲的适宜配比。研究结果表明:(1)1990~2010年,研究区域人工绿洲呈不断扩张,天然绿洲面积不断缩小,人工绿洲替代天然绿洲的趋势。(2)1990~2010年,人工与天然绿洲总面积几乎无差异,面积变化主要是人工绿洲与天然绿洲之间的相互转换。具体表现为:天然草地、林地等向人工绿洲中的耕地、建筑用地转化;同时植被长势衰退:高覆盖草地向中、低覆盖草地转化,中覆盖草地向低覆盖草地转化,灌木林地逐渐退化为草地,低覆盖草地向沙漠转化。(3)人工与天然绿洲面积比例在近20 a呈增加的趋势,在1990,2000,2010年,人工与天然绿洲面积比值分别是1∶9,2∶8,3∶7。     

快速高效隔膜压滤机在鹤壁四矿选煤厂的应用

介绍了快速高效隔膜压滤机的主要性能参数和特点 ;分析了压滤机在煤泥水处理系统中的应用情况和运行结果 ;应用快速高效隔膜压滤机对煤泥水处理系统进行改造后获得了较好的经济及社会效益     

Conversion of methane to syngas in a solid oxide fuel cell with Ni-SDC anode and LSGM electrolyte

A solid oxide fuel cell constructed from Ni-SDC anode and LSGM electrolyte was applied to the partial oxidation of methane to syngas (CO+H₂) at 700-800 °C with the merits of co-generation of electricity and controllable O₂ supply. It was found that the co-generated syngas at H₂/CO ratio of 1.4-2.0 varied with applied current densities, CH₄ flow rates and operating temperatures. The cell voltage at 100 mA cm⁻² and 800 °C was 0.90 V, i.e. about 90 mW cm⁻² power density could be obtained. The cell operating at 50 mA cm⁻² for 24 h almost showed no degradation of the cell performance. The observed carbon deposition seemed mainly taking place by CH₄ cracking reaction.