Investigation of mass transport in gas diffusion layer at the air cathode of a PEMFC

In a polymer electrolyte membrane fuel cell (PEMFC), slow diffusion in the gas diffusion electrode may induce oxygen depletion when using air at the cathode. This work focuses on the behavior of a single PEMFC built with a Nafion^® based MEA and an E-TEK gas diffusion layer and fed at the cathode with nitrogen containing 5, 10 and 20% of oxygen and working at different cell temperatures and relative humidities. The purpose is to apply the experimental impedance technique to cells wherein transport limitations at the cathode are significant. In parallel, a model is proposed to interpret the polarization curves and the impedance diagrams of a single PEMFC. The model accounts for mass transport through the gas diffusion electrode. It allows us to qualitatively analyze the experimental polarization curves and the corresponding impedance spectra and highlights the intra-electrode processes and the influence of the gas diffusion layer.     

燃气涡轮发电机组虚拟评判系统研究

为更好地评判操作人员对燃气涡轮发电机组的操作训练,设计了一种虚拟评判系统.根据操作实际,制定了评判标准,建立了评判指标体系.考虑到指标之间的相互影响和反馈关系,解决指标权重分配问题,利用网络分析法(ANP)处理指标间的复杂关系,并采用三角模糊数和模糊优先规划方法(FPP)完成权重的计算,引入云理论确定隶属度,使用蚁群算法优化BP神经网络,结合模糊综合评判构造模糊蚁群神经网络评判模型.上述方法能够有效减少主观因素对权重的影响,弥补传统评判方法的不足.实际应用表明,改进的评判系统具有很强的实用性,是一种可行的评判系统.     

A reverse osmosis desalting plant operated by gas turbines

Power plants in Kuwait use gas turbines (GT) only for a few hours to produce power at peak load times. Peak loadoccurs in the summer due to the air-conditioning load. As an example, the average number of operating hours for six gas turbines in the Doha East power plant was 16 in the summer of 2001. There is little concern about efficiency of these GT since they work for a very short time during the year. However, a recent increase in desalted seawater demand suggests the use of these GT to operate reverse osmosis (RO) desalting systems all year around. The summer outside design temperature in Kuwait for air-conditioning calculations is 48°C dry bulb temperature (DBT), and 28°C wet bulb temperature (WBT); but the ambient temperature can easily reach 60°C. Gas turbine power output and efficiency are drastically reduced by the increase in temperature of intake air to the gas turbine's compressor, especially during harsh Kuwaiti summer conditions. Thus, it is essential to investigate cooling of air intake to the GT compressor. The performance of a typical GT unit and its ability to produce desalted waterby a RO desalting system at different ambient temperatures are presented. Calculation of needed capacities for the cooling of intake air to the GT compressor was performed for evaporative cooling, single and multiple mechanical vapor compression cycles, and combined indirect evaporation cooling with the refrigeration system. The improvements of power output and efficiency due to the cooling of air intake of the GT and the resulting increase in desalted water are also presented.     

Calculation of single adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms on activated carbon at high pressures

A method is developed for the calculation of single-component adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms at high pressures, at two temperatures and for different mole fractions of the gas phase. The adsorption of nitrogen/methane on active carbon Norit R1 is taken as an experimental example.     

Improvement in polyetherimide gas separation membranes through the incorporation of nanostructured metal complexes

Polyetherimide (PEI) gas separation membranes were tailored, at the molecular scale, by the incorporation of nanostructured metallic complexes into the PEI network. The influence of these additives on the micropore size distributions of the membranes produced and on their performance for oxygen/nitrogen separation was investigated. Changing the metal within the same ligand had a significant influence on the microporosity and gas separation performance of these membranes. Magnesium (II) phathalocyanine (MgPc) in PEI membranes was found to be an excellent additive to increase membrane performance for air separation. The performance of these membranes increases with increasing additive concentrations. Membranes with this additive also exhibit an improved stability as determined through the annealing process. Annealing these membranes caused a slight decrease in their gas permeance and total micropore volume but a significant increase in their gas selectivity. The results show that the properties of the nanophase additive and nanophase-polymer interactions play a pivotal role in stabilizing and determining membrane performance for air separation.     

气辅注射成型及设计要点

概述了气辅注射成型过程中材料的选择、气道及模具的设计     

四氢噻吩的生产技术与市场分析

四氢噻吩是城市燃气的首选加臭剂,随着我国西气东输等工程的建设成功,其市场前景广阔.文章介绍了四氢噻吩的生产工艺和市场情况,并对四氢噻吩的发展提出了良好建议.     

高分辨力地震是提高中国南方碳酸盐岩地震勘探效能的基础——一个由失败到成功的史例

南方碳酸盐岩复杂地区的地震工作经历了长期艰难曲折的道路,其中异常判别的经验教训极为深刻。本文从地震异常分析入手,揭示其实质,寻求问题的关键,探讨解决的办法,介绍高分辨率地震方法技术,展示高分辨率地震新成果,以得出有意义的结论和建议。     

Creep behaviour and constitutive model of coal filled with gas

Coal exhibits different creep behaviours when filled with different amounts of gas. Creep tests of coal filled with 0 and 0.5 MPa gas were performed, and strain under different axial stress was compared.The three creep constitutive models which were analysed using the method fitting experimental data for determining which creep model can reflect the creep process of the test best. The results show that the deformation of coal filled with 0.5 MPa gas is more higher than that of coal filled with 0 MPa gas under the same axial stress. Gas plays a positive effect on the deformation of coal process and will accelerate creep process. And gas will reduce coal intensity and change coal creep properties.Compared with Nishihara Model and Extensional Nishihara Model, Burgers Model can reflect the three stages of creep process of coal filled with gas better. The research results can contribute to reveal coal and gas outburst mechanism.     

Progress on the hydraulic measures for grid slotting and fracking to enhance coal seam permeability

A method of hydraulic grid slotting and hydraulic fracturing was proposed to enhance the permeability of low permeability coal seam in China. Micro-structural development and strength characteristics of coal were analysed to set up the failure criterion of coal containing water and gas, which could describe the destruction rule of coal containing gas under the hydraulic measures more accurately. Based on the theory of transient flow and fluid grid, the numerical calculation model of turbulence formed by high pressure oscillating water jet was used. With the high speed photography test, dynamic evolution and pulsation characteristics of water jet water analysed which laid a foundation for mechanism analysis of rock damage under water jet. Wave equation of oscillating water jet slotting was established and the mechanism of coal damage by the impact stress wave under oscillation jet was revealed. These provide a new method to study the mechanism of porosity and crack damage under high pressure jet.Fracture criterion by jet slotting was established and mechanism of crack development controlled by crack zone between slots was found. The fractures were induced to extend along pre-set direction,instead of being controlled by original stress field. The model of gas migration through coal seams after the hydraulic measures for grid slotting and fracking was established. The key technology and equipment for grid slotting and fracking with high-pressure oscillating jet were developed and applied to coal mines in Chongqing and Henan in China. The results show that the gas permeability of coal seam is enhanced by three orders of magnitude, efficiency of roadway excavation and mining is improved by more than 57%and the cost of gas control is reduced by 50%.