Exergoeconomic and exergoenvironmental evaluation of power plants including CO2 capture

CO₂ capture from power plants, combined with CO₂ storage, is a potential means for limiting the impact of fossil fuel use on the climate. In this paper, three oxy-fuel plants with incorporated CO₂ capture are evaluated from an economic and environmental perspective. The oxy-fuel plants, a plant with chemical looping combustion with near 100% CO₂ capture and two advanced zero emission plants with 100% and 85% CO₂ capture are evaluated and compared to a similarly structured reference plant without CO₂ capture. To complete the comparison, the reference plant is also considered with CO₂ capture incorporating chemical absorption with monoethanolamine. Two exergy-based methods, the exergoeconomic and the exergoenvironmental analyses, are used to determine the cost-related and the environmental impacts of the plants, respectively, and to reveal options for improving their overall effectiveness.For the considered oxy-fuel plants, the investment cost is estimated to be almost double that of the reference plant, mainly due to the equipment used for oxygen production and CO₂ compression. Furthermore, the exergoeconomic analysis reveals an increase in the cost of electricity with respect to the reference plant by more than 20%, with the advanced zero emission plant with 85% CO₂ capture being the most economical choice. On the other hand, a life cycle assessment reveals a decrease in the environmental impact of the plants with CO₂ capture, due to the CO₂ and NO_x emission control. This leads to a reduction in the overall environmental impact of the plants by more than 20% with respect to the reference plant. The most environmentally friendly concept is the plant with chemical looping combustion.     

HP20大孔吸附树脂对L-苯丙氨酸吸附条件的研究

文章研究了HP20大孔吸附树脂对L-苯丙氨酸的吸附性能.通过实验,确定了HP20大孔吸附树脂对L-苯丙氨酸吸附的最佳工艺条件.在事温下,采用2 g/L L-Phe和0.5～0.75 mol/L NH<,4><'+>、pH为6.0的溶液作为上柱液,在2.0BV/h吸附流速下经过HP20大孔吸附树脂柱,99%L-Phe被吸...     

芳烃馏分C10点火稳燃技术在煤粉锅炉上的应用

介绍了上海石化煤粉锅炉在点火和稳燃过程中燃烧芳烃馏分C10、相对于燃烧轻柴油所产生的问题,提出了相应的燃烧器改进措施,经试验后获得应用,取得良好的收效.     

高压氨泵机械密封泄漏原因及预防措施

分析高压氨泵使用过程中机械密封泄漏对装置运行的影响,针对造成机械密封泄漏的原因,从工艺操作、设备管理上提出预防措施,同时建议使用质量好的滤袋,确保生产装置稳定运行。     

高压涡轮动叶前缘新型几何特征对流场结构影响研究

本文提出一种前缘前伸内凹且根部叶片略厚的新型动叶片设计方法,旨在通过这种新型叶片控制前缘马蹄涡的生成和发展,通过根部叶片较厚到中间区域叶片厚度略低的三维设计和积叠方法,实现动叶片的弯叶片效果。论文以某高压涡轮叶片为研究对象,从能量损失系数、型面压力分布、旋涡沿流向变化对比分析了新型叶片与原型叶片对流场结构的影响。研究表明叶型前缘新的几何特征使马蹄涡得到控制,流场内流动得到改善。     

超超临界二次再热高压缸流热耦合特性研究

为满足大型核电汽轮机高压缸的开发要求,采用耦合流动计算和共轭传热的数值方法研究了超超临界二次再热高压缸的流热耦合,给出了高压缸排汽腔室和抽汽腔室流体域的流动特性、外缸和内缸固体部件的温度场分布特性。研究结果表明:抽汽腔室进口重量流量不均匀,靠近抽汽管道的进口质量流量整体偏高;双分流波整体内缸的表面强化与排汽腔室的对流换热承受了高压缸几乎全部的温差应力,因此外缸温度场比内缸的温度场相对要更加均匀。研究结果为研发超超临界二次再热高压缸提供理论支持。     

利用高分溶解平衡核算加氢装置物料平衡的探索

针对目前实验室测定装置物料平衡方法中存在的高分各种低分子烃类溶解度不同对物料平衡的影响,改变测定装置物料平衡的流程,利用反应物料在高分溶解后废氢中低分子烃类含量,结合HYSYS软件中Adjust功能,较为准确核算装置物料平衡,还原加氢反应本身的反应结果。     

常压化学气相沉积SiO2涂层的制备及其性能研究

    以正硅酸乙酯(TEOS)为源物质,空气为载气和稀释气,采用常压化学气相沉积法(APCVD)在HP40钢表面制备了SiO₂涂层.采用光学显微镜、扫描电子显微镜、能量色散能谱仪、D＼MAX-C型X射线衍射仪、显微硬度仪等,研究了SiO₂涂层的组织结构、表面形貌、物相组成和显微硬度;并用热震实验法和剥离实验法研究了涂层与HP40基体的结合强度.结果表明,所制备的SiO₂涂层厚度约为1 μm,由细小颗粒组成,颗粒比较均匀、大部分颗粒的粒径均在1 μm以下;涂层无明显孔隙,与基体的结合强度较高;其显微硬度明显高于HP40基体.