Studies on the structural and ionic transport properties at elevated temperatures of La1−xMnO3±δ synthesized by a wet chemical method

Structural transformation and ionic transport properties are investigated on wet-chemically synthesized La_1−xMnO₃ (x=0.0–0.18) compositions. Powders annealed in oxygen/air at 1000–1080 K exhibit cubic symmetry and transform to rhombohedral on annealing at 1173–1573 K in air/oxygen. Annealing above 1773 K in air or in argon/helium at 1473 K stabilized distorted rhombohedral or orthorhombic symmetry. Structural transformations are confirmed from XRD and TEM studies. The total conductivity of sintered disks, measured by four-probe technique, ranges from 5 S cm⁻¹ at 298 K to 105 S cm⁻¹ at 1273 K. The ionic conductivity measured by blocking electrode technique ranges from 1.0×10⁻⁶ S cm⁻¹ at 700 K to 2.0×10⁻³ S cm⁻¹ at 1273 K. The ionic transference number of these compositions ranges from 3.0×10⁻⁵ to 5.0×10⁻⁵ at 1273 K. The activation energy deduced from experimental data for ionic conduction and ionic migration is 1.03–1.10 and 0.80–1.00 eV, respectively. The activation energy of formation, association and migration of vacancies ranges from 1.07 to 1.44 eV.     

Enantioselective extraction of mandelic acid enantiomers based on chiral ligand exchange

Based on the chiral ligand exchange, the distribution behavior of mandelic acid enantiomers, and the partition of Cu^2 at different pH values were studied in a water/alcohol two-phase system containing Cu^2 and N-ndodecyl-L-proline(A). The influences of the solvent sort, the pH value, the concentrations of Cu^2 and chiral ligand on the partition coefficient(K) and separation factor(α) were discussed. The experimental results show that the A formed has more stable ternary complex with D-mandelic acid enantiomer than with L-mandelic acid enantiomer. There is an important influence of the pH value on K and a. When the pH values are less than 3.5, the formation of binary complexes is thermodynamically unfavourable. K and a become maximum when pH values are above 3.5 and the molar ratio of the chiral ligand to Cu^2 is 2:1.     

中加高等职业技术教育合作初探

本介绍了加拿大社区学院及加拿大社区学院协会的概况，并就中加职业技术学院的教育合作的有效途径作了初步探析。     

在玻璃衬底上制作K~+离子交换掩埋波导的新工艺

本文报道用不同离子两步交换技术,在玻璃衬底上制作K~+离子交换掩埋波导的新工艺,它不要求施加外电场。用X射线能谱(XES)分析技术测试了K~+离子的浓度分布,证明所制出的样品是掩埋波导。     

关于离子注入中温升的探讨

本文在理论和试验两个方面探讨了离子注入中的热效应和温升现象。注入样品的温升对离子注入层的性能有直接影响。分析了理论计算注入样品温升的一些情况。给出了实际测量注入样品温升的几种试验方法。阐明了控制注入样品温升的若干可能途径。     

铵离子交换处理负硬水供锅炉应用技术

本文论述了负硬水只用氯化铵再生时离子交换器的运行过程及离子交换软化除碱的方法,并阐述了控制出水中残留碱的简便方法。经研究证明,此方法可达到除碱度、除硬度、除盐、延长锅炉使用寿命、减少腐蚀、减少排污量、节约燃煤等效果。经济效益十分显著。     

无锡市运河实验中学改扩建设计随感

通过对无锡市运河实验中学改扩建项目的回顾,阐述如何发掘原有校园空间环境的价值,并且通过借鉴中国古典园林的设计手法,使得老校园焕发出新生机。