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排序方式: 共有216条查询结果,搜索用时 15 毫秒
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Xue‐Gang Chen Dai‐Dai Wu Shuang‐Shuang Lv Lu Zhang Ying Ye Ji‐Peng Cheng 《应用聚合物科学杂志》2010,116(4):1977-1984
A novel layered double hydroxide/NaSb(OH)6‐based nanocomposite (Sb‐LDH) has been prepared via intercalation of thio‐antimonite (SbS33?) and reconstruction of LDH using Mg‐Al LDH as precursors. It is composed of LDH nanolayers with thickness of 25 nm and NaSb(OH)6 nanoparticles with diameter of 3–25 nm. The presence of NaSb(OH)6 will decrease the decomposition intensity and hinder the decomposition of Mg‐Al LDH because of the potential synergetic effect. When applied to poly(vinyl chloride) (PVC) composites, both Mg‐Al LDH and Sb‐LDH can enhance the thermal stability and increase the decomposition temperature of PVC. Compared with Mg‐Al LDH, Sb‐LDH results in higher decomposition temperatures and whiteness and higher initial and long‐term stabilities due to the presence of NaSb(OH)6, which can react with HCl and coordinate with Cl in the PVC chains. Because Mg‐Al LDH will accelerate the dehydrochlorination of PVC driving by the Lewis acid such as AlCl3, the thermal stability of PVC decreases with increasing nanofiller loading. When 1 wt % Sb‐LDH was added, the color change time and Congo red time of PVC composites are 140 min and 154 min, respectively. With enhanced thermal stabilization, this novel LDH nanocomposite could gain promising application in thermal stabilizer for PVC resins. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
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Removal of Arsenic (III) from groundwater applying a reusable Mg‐Fe‐Cl layered double hydroxide
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Mojtaba Abbasian 《应用聚合物科学杂志》2011,122(4):2573-2582
Well defined poly (styrene‐co‐methylstyrene) grafted polyaniline/organo‐modified MgAl layered double hydroxide (LDH) was produced through solution intercalation method. After LDH nanoparticles were modified by the anion exchange reaction of MgAl (Cl) LDH with sodium dodecyl benzene sulfonate, Poly (styrene‐co‐methylstyrene) copolymers were synthesized by “living” free radical polymerization and then brominated with N‐bromosuccinimide. Afterwards, 1,4‐phenylenediamine was linked to brominated copolymers and prepared functionalized copolymer with amine. Poly (St‐co‐MSt)‐g‐PANI, has been synthesized by adding solution of ammonium persulfate and p‐toluenesufonic acid in DMSO solvent. Finally, Poly (styrene‐co‐methylstyrene) grafted‐Polyaniline/LDH nanocomposites were prepared by solution intercalation method. Characterization of these well‐defined nanocomposites included FT‐IR, gel permeation chromatography, thermogravimetric analysis, differential scanning calorimeter, transmission electron microscopy, and X‐ray diffraction. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011. 相似文献
149.
牛磺酸复合饮料抗疲劳的实验研究 总被引:2,自引:0,他引:2
通过动物试验研究牛磺酸复合饮料的抗疲劳作用。将雄性SD大鼠按体重随机分为4组,即空白对照组、阳性对照组、低剂量和高剂量牛磺酸复合饮料组。在给予受试物30d后测定各组大鼠爬杆时间和负重游泳的持续时间。试验前及试验第35天,大鼠在水温25℃±1℃的水中游泳90min,测定乳酸脱氢酶(LDH)、血乳酸(LAC)、血尿素氮(BUN)和肝糖原等生化指标。结果显示牛磺酸复合饮料组大鼠爬杆、游泳时间明显长于对照组(P〈0.01);服用牛磺酸复合饮料的大鼠LDH活力、肝糖原均比对照组显著增加(P〈0.01),运动后血乳酸水平及BUN明显降低(P〈0.01)。由此可得出牛磺酸复合饮料具有抗疲劳作用。 相似文献
150.
Layer-by-layer self-assembly of polyimide precursor/layered double hydroxide ultrathin films 总被引:1,自引:0,他引:1
Dan Chen 《Thin solid films》2010,518(23):7081-7085
The layer-by-layer (LBL) self-assembly has been extensively used as a simple and effective method for the preparation of polyelectrolyte multilayer films. In this work, we utilized this unique method to prepare polyimide precursor/layered double hydroxide (LDH) ultrathin films. Well-crystallized Co-Al-CO3 LDH and subsequent anion exchanged Co-Al-NO3 LDH were prepared and characterized by scanning electron microscopy and X-ray diffraction (XRD). By vigorous shaking of the as-prepared Co-Al-NO3 LDH, positively charged and exfoliated LDH nanosheets were obtained. Atomic force microscopy and XRD investigations indicated the delamination of LDH nanosheets. The precursor of polyimide, poly(amic acid) tertiary amine salt (PAS) was prepared by the polycondensation of dianhydride and diamine, and subsequent amine salt formation. By using the LBL method, heterogeneous ultrathin films of PAS and LDH were prepared. The formation of the ordered nanostructured assemblies was confirmed by the progressive enhancement of UV absorbance and the XRD results. 相似文献