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排序方式: 共有10000条查询结果,搜索用时 921 毫秒
991.
992.
Fe-30Mo alloys containing up to 9.1 wt% Al were sulfidized at 0.01 atm sulfur vapor over the temperature range of 700–900°C. The sulfidation kinetics followed the parabolic rate law for all alloys at all temperatures. For alloys containing small and intermediate amounts of Al (<4.8 wt.%), a duplex sulfide scale formed. The outer layers of the scales were found to be relatively compact FeS in all cases; whereas the inner layers were composed of the layered compound MoS
2
(intercalated with iron), the Chevrel compound Fe
x
Mo
6
S
8,a spinel double sulfide Al
x
Mo
2
S
4,depending on the Al content of the alloy and the sulfidation temperature. Extremely thin scales were found on the alloys with higher Al contents. Accordingly, extremely slow sulfidation rates were observed—even slower than the sulfidation rate of pure Mo. The transition of the sulfidation kinetics from a high-rate active mode to a low-rate passive mode requires both a critical Al content in the alloy and a critical Mo content. Because of the two-phase nature of the alloys, the latter requirement implies a critical volume fraction of the intermetallic second-phase in the alloy, which has been known as the multiphase effect. Interestingly, the multiphase effect in these alloys was also a function of the Al content in the alloys. 相似文献
993.
弥散Gd_2O_3质点改性的新型复合铝化物涂层的氧化行为SCIEI 总被引:1,自引:0,他引:1
研究了Gd_2O_3质点及其添加量对涂层在空气中1100℃氧化行为的影响及作用机制。结果表明,NiAl涂层中加入Gd_2O_3质点后,极大地降低了涂层的氧化速率,显著提高了氧化膜的粘附性,比简单NiAl涂层具有更好的抗高温氧化性能。复合镀层经渗Al后,一部分Gd_2O_3质点仍弥散分布于涂层中,另一部分细小的亚微观质点在涂层/基体界面处富集,形成氧化物聚集带,聚集带具有扩散障作用。连续的聚集带更有效地抑制退化,提高涂层使用寿命。 相似文献
994.
995.
Highly conductive transparent aluminium-doped ZnO (ZnO:A1) films were successfully deposited by CW-CO2 laser-induced evaporation. Optimisation of evaporation parameters was based on laser power, substrate temperature, O2 partial pressure in the vacuum chamber and amount of Al in the ZnO source pellet. ZnO:A1 films with an electrical resistivity as low as 6.6 × 10−2Ω·cm and an optical transmission of 80% at 500nm were obtained at laser power of 15 W, substrate temperature of about 200°C, O2 partial pressure of 6—7 × 10−4 Torr and 5wt.% Al. Conductivity of ZnO films can be increased one order via Al-doping in ZnO films. The films obtained by laser-induced evaporation have compared quite favorably with the high quality films obtained by sputtering. 相似文献
996.
Sun Shuiyu Wang Dianzuo Li Bodan Central-South University of Technoloyy Changsha China 《中国有色金属学会会刊》1993,(3)
The adsorption mechanisms of HS~- ions existing in air-saturated alkaline solutions on sulphide minerals (including pyrite, arsenopyrite, chalcopyrite and galena) were investigated. The measurement of adsorption density, solvent extraction-chemical analysis of neutral sulphur at the surfaces, measurements of pulp potential and voltammogram, and flotation tests were done. Both the electrochemical and non-electrochemi cal adsorption models of HS~- ions were established. The former was observed and resulted in the formation of neutral sulphur (S°)when the pyrite and arsenopyrite were chosen, and hence renders the surfaces hy drophobic and induced the two minerals flotation. It is called Na_2S-induced flotation. On the other hand, the latter took place and did not produce S° when the chalcopyrite and galena were selected, and hence de presses the collectorless flotation of the two minerals. The adsorptions of HS~- ions were mainly influenced by potentials, pH and the electron structures of the mineral surfaces. 相似文献
997.
TiO_2直接电解还原过程的研究 总被引:4,自引:0,他引:4
采用SEM、EDS、XRD等方法对TiO2直接电化学还原产物进行分析,指出TiO2电极的还原是从外向内由高价到低价再到金属逐步进行的。对还原过程中电流、还原气相产物的分析结果表明:还原过程电流效率低,并且电流效率随电解时间延续而降低,阳极产物CO、CO2与阴极中间产物Ca发生副反应以及副反应产物炭黑造成电流短路是电流效率低的主要原因。提高电流效率的途径有两条:一是增大阴、阳极间距,减小副反应的发生;二是使电解池表面熔盐不断导出,或采取某一隔离措施,使副反应产生的炭黑在阴、阳极之间不造成电流短路。 相似文献
998.
研究了00Crl7Nil4M02不锈钢材料的机械性能、焊接性能和耐腐蚀性能,从用户和研究开发的角度探讨了其在压力容器、化工装置、化肥装置、海洋装置和建筑业等领域的应用。 相似文献
999.
1 Introduction Lithium manganese oxides are the most attractive cathode materials for rechargeable lithium-ion batteries because of their low-cost and less toxicity when compared with either cobaltates or nickelates[1?3]. Among these oxides, the spinel-fr… 相似文献
1000.