The effect of ion exchange conditions, such as Si/Al ratio, precursor copper salt, pH and concentration of the solution, on the catalytic activity in SCR of NO by propane and on the electronic state of copper ions in Cu-ZSM-5 has been studied. The NO conversion in NO SCR by C3H8 has been found to reach a maximum value at Cu/Al ratio about 0.37–0.4 and remain constant at higher Cu/Al.
ESR and UV–vis DR spectroscopy have been used to elucidate stabilization conditions of copper ions in Cu-ZSM-5 zeolites as isolated Cu2+ ions, chain copper oxide structures and square-plain oxide clusters. The ability of copper ions for reduction and reoxidation in the chain structures may be responsible for the catalytic activity of Cu-ZSM-5. These transformations of copper ions are accompanied by the observation of intervalence transitions Cu2+–Cu+ and CTLM of the chain structures in the UV–vis spectra. 相似文献
A model has been proposed to explain the failure of the original BMS10-39 epoxy paint on upper vertical surfaces in B-52 fuel tanks. The model involves interaction of the paint with DIEGME, a fuel system ice inhibitor (FSII) in jet fuel, that is distilled from the liquid fuel. In this communication, distillation experiments used to support the model are refined to better match the mass transfer of vapor from fuel in a B-52 fuel tank at close to room temperature. The interaction of these lower temperature distillates with the paint affirms the earlier model. On the basis of these experiments it is proposed that paint failure may be controlled or eliminated by reducing the level of DIEGME in the fuel. Proposed changes in military jet fuel composition are detailed. 相似文献
The dehydroalkylation of toluene with ethane to the isomeric ethyltoluenes was studied on 0.4Pt/H-ZSM-5 at varying contact
times (1/WHSV). At a high contact time of 1.0 h, toluene disproportionation and hydrogenolysis reactions dominate, resulting
in low selectivity to the desired ethyltoluenes via the alkylation reaction. However, at a low contact time of 0.12 h side
reactions are eliminated, resulting in maximum selectivities to the kinetically favored ethyltoluenes and hydrogen. Results
at high selectivities to ethyltoluenes provide significant insight into reaction pathways. 相似文献
The density functional theory (DFT/B3LYP) calculations were applied to investigate the interaction of a Pt6 particle with the ZSM-5 zeolite framework. The electronic structure of the metal particle is strongly affected by the interaction with basic framework oxygens and acid sites of the zeolite support. Adsorption on basic sites (Eads = 6 kcal/mol) favors the formation of the electron enriched metal cluster. Interaction of the platinum cluster with the acid site characterized by stabilization energy of 47 kcal/mol results in oxidation of the metal particle and suppression of Brønsted acidity of the support. The hypothesis is put forward that the oxidized platinum particle can function as an active site for the alkane isomerisation on platinum supported high silica zeolites. 相似文献
Formation of aluminium titanate (AT) has been achieved at low temperature through sol-gel process using boehmite and titanium hydroxide as precursors by controlling the particle size at nanoscale followed by in-situ peptisation. The formations of AT phase, particle size distributions, sintering and thermal expansion characteristics, and microstructural features have been reported. DTA and XRD analysis have been performed to confirm the formation of AT. A 94% relative density was obtained for aluminium titanate sintered at 1550 °C with controlled grain size in the range of 2-3 μm. 相似文献
1. 1. System design optimization and validation for single-speed heat pump by S.K. Fischer and C.K. Rice, Oak Ridge National Laboratories.
2. 2. Analysis of on/off cycling for an air-to-air heat pump operating in the heating mode by W.A. Miller, Oak Ridge National Laboratories.
3. 3. Field measured cycling, frosting and defrosting losses for a high efficiency air source heat pump by V.D. Baxter and J.C. Moyers, Oak Ridge National Laboratories.
4. 4. Design and available energy analysis of a heating-only residential heat pump for the Western Pacific Northwest by D.E. Elger, C.M. Reistad and S. Lang, Oregon State University.
5. 5. A study of heat pump service life by Nance C. Lovvorn, Alabama Power Company and Carl C. Hiller, Electric Power Research.
Résumé
1. 1. Optimisation de la conception des systèmes et application à la pompe à chaleur à une seule vitesse;
2. 2. analyse du cycle par tout ou rien d'une pompe à chaleur air-air fonctionnant en mode de chauffage;
3. 3. pertes en fonctionnement cyclique, par givrage et dégivrage mesurées sur place pour une pompe à chaleur de grand rendement dont la source est l'air;
4. 4. conception et analyse de l'énergie disponible d'une pompe à chaleur uniquement pour le chauffage de locaux résidentiels sur la côte du Pacifique nord-ouest occidental;
5. 5. étude de la durée de vie d'une pompe à chaleur.
Les noms et les addresses des auteurs se trouvent dans le sommaire anglais. 相似文献