激光在材料中感生的瞬态光声波和光热波

研究了锁模激光在材料中产生频率达GHz的光声波和相应探测技术,用回波分析法无损坏测量了薄材料的厚度。研究了激光在材料中感生的光热波,热沉测量可用于解释材料的破坏机理。     

L波段窄脉宽500W固态功放组件的设计

介绍了作者研制的应用于固态雷达发射机上的L波段500W固态功放组件的工作原理、用途及其主要技术指标。描述了功放组件的设计过程和测试结果。该功放组件在窄脉宽条件下实现了快速上升沿,性能优良,工作稳定可靠。     

氮离子注入尼龙1010的摩擦学特性

用高能离子注入机对尼龙 10 10进行 N+注入改性 ,注入能量为 4 5 0 ke V,剂量分别为 5× 10 14 /cm2 、2 .5× 10 15/cm2 及 1.2 5× 10 16/cm2 。以 Zr O2 及 Si3N4 球为上球样 ,分别与注入尼龙 10 10下盘样组成摩擦副 ,在销盘摩擦试验机上评价它们在干摩擦条件下的摩擦磨损行为。结果表明 ,几种剂量的 N+注入均增强了尼龙 10 10的耐磨性。未注入样品的磨损主要表现为粘着、塑性变形、犁沟和疲劳脱层 ,注入样品的磨损主要为轻微的磨粒磨损。     

Flow stress of high density polyethylene and nylon 66 at high rates of strain

Measurement of the flow stress of high density polyethylene (HDPE) and nylon 66 at strain rates of 10³ s^?1 using a split Hopkinson pressure bar technique is discussed. The flow stress at a strain of 10% has been determined for both polymers at 20°C. The intrinsic errors involved in this technique are briefly reviewed. The results indicate that the flow stress of HDPE and nylon 66 were 50MPa and 150MPa, respectively, at strain rates of about 10³s^?1.     

Dispersion characterization in layered double hydroxide/Nylon 66 nanocomposites using FIB imaging

Layered double hydroxides (LDHs), a newly emerging 2D host material, consist of cationic brucite-like layers and exchangeable interlayer anions. In this work, the morphology and dispersion of LDH particles in LDH/Nylon 66 (salt) nanocomposites has been investigated using focused ion beam (FIB) techniques, transmission electron microscopy (TEM) and X-ray diffraction (XRD). The FIB images show that LDHs are present in the polymer phase dispersed to different degrees, with partial intercalation, exfoliation, and aggregation all being observed. The most even dispersion was achieved in nanocomposites with the lowest loading (0.5 wt % LDH). Residual tactoids and agglomerates were most common in the samples made with the highest concentration of LDHs studied here (5 wt %). The dispersion observed using FIB was consistent with TEM and XRD analysis, yet this technique had significant benefits in terms of time and simplicity over these “conventional” technologies. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Study of the effective parameters on mechanical and electrical properties of carbon black filled PP/PA6 microfibrillar composites

In this study the electrical and mechanical properties of microfibrillar polypropylene (PP)/polyamide6 (PA6) blend filled with super conductive carbon black (CB) have been investigated. In situ microfibrillar PP/PA6 composites filled with CB are produced using a single screw extruder equipped with a spinneret. Glycidyl methacrylate (GMA) grafted polypropylene (PP-g-GMA) is used as the compatibilizer. To investigate the effects of extensional flow on the microstructure, electrical and mechanical properties, three adaptors with various convergence angles were designed, prepared and applied between the extruder and the spinneret. To optimize the effects of processing and material parameters on the electrical and mechanical properties, the Taguchi method of experimental design is used. Material and processing factors which are studied include: concentration of PA6, compatibilizer level, CB concentration, drawing speed of melt spinning line, adaptor angle, order of mixing and temperature profile along the extruder. The results show an increase in DC conductivity of up to 10¹¹ times in comparison with pure PA6, by increasing the concentration of CB, drawing speed, adaptor angle and optimizing other parameters. By optimizing processing and material factors studied here, strength of microfibrillar structured composites is increased of up to 80% in comparison to pure PP.     

Compatibility between Polyamide 6 and Polycarbonate

Polyamide （PA6） and polycarbonate （PC） were prepared by a Brabender mixer （ PLV- 151） at 240℃ with 30 rpm for duration of 8 and 6 minutes respectively. The epoxy resin （E） addition can lead to substantial microstructural changes in the PA6/PC blends. Scanning electron microscope （SEM） was used to observe the mixtures characterized by the domains of clearly segregated homophases and voids between the two polymers. PA6/PC of polyamide 6 and polycarbonate with epoxy resin addition under the composition ratio of 20/80, 20/80/1, 40/60/1 and 40/60, were tested to verify the key role of epoxy in promoting the compatibility of PA6 with PC during blending.     

空间激光通信系统精跟踪单元PZT驱动电源的设计

压电陶瓷驱动电源是压电陶瓷微位移器应用中的关键部件。PA85是一种高电压、高功率MOSFET的带宽运算放大器,采用双电源供电,输出电流高达200mA,输出电压更可高达±215V。该文详细介绍了基于PA85的一种电源复合放大器的设计及仿真,通过对各项性能指标的仿真表明,该驱动电源具有精度高、分辨率高、稳定性好、纹波小和电路结构简单等优点。     

补强剂和共混工艺对PA/PVC/NBR三元共混弹性体性能的影响

在选择三元共聚尼龙（PA）、聚氯乙烯（PVC）、丁腈橡胶（NBR）为主体材料，制备PA／PVC／NBR（10／30／60）三元共混弹性体的工作基础上，进一步探讨了填料品种和用量，共混温度，加料顺序等因素PA／PVC／NBR三元共混弹性体的影响。试验结果表明：在PA／PVC／NBR（10／30／60）共混体系中，补强型填料的补强效果优于非补强型的填料，6种填料补强效果依次是：快压出炭黑＞半补强炭黑＞白炭黑＞活性重质，CaCO3＞陶土＞滑石粉，快压出炭黑的适宜用量是20－50份。在制备PA／PVC／NBR三元共混物时，适宜的共混温度是122－140℃，并且采用二段法混工艺制得的共混物性能优于采用一段法共混工艺。     

Studies on crystallization behaviors and crystal morphology of polyamide 66/clay nanocomposites

X‐ray diffraction methods, DSC thermal analysis, and polarized light microscopy (PLM) were used to investigate the structural changes of nylon 66/clay nanocomposites. PA 66/clay nanocomposites were prepared by the method of melt intercalation. The results indicate that the addition of the intercalated organo‐montmorillonite (OMMT) can induce generation of the β‐form crystal of PA 66 and substantially affect the arrangement of molecules in the α‐form crystal, although the crystallinity scarcely changes. Also, the DSC results indicate that the addition of OMMT in the PA 66 matrix leads to increases of crystallization temperatures and the full width at half maximum (FWHM) of the exothermic peaks. Moreover, the viscosity factor is the main influence on FWHM of the exothermic peaks of PA 66/clay nanocomposites. The results of nonisothermal crystallization kinetics show that OMMT has the effect of heterogeneous nucleation and leads to the decrease of the size of the spherocrystal. The heterogeneous nucleation effects of OMMTs influence the mechanism of crystallization and the growth mode of PA 66 crystals. PLM photographs verify that the size of spherocrystal is decreased and visually confirm the theory of crystallization kinetics. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 756–763, 2005