Molecular Adsorption-Induced Interfacial Solvation Regulation to Stabilize Graphite Anode in Ethylene Carbonate-Free Electrolytes

Many organic solvents have excellent solution properties, but fail to serve as lithium-ion batteries (LIBs) electrolyte solvents, due to their electrochemical incompatibility with graphite anodes. Herein, a new strategy is proposed to address this issue by introducing a surface-adsorbed molecular layer to regulate the interfacial solvation structure without the alteration of electrolyte composition and properties. As a proof-of-concept study, it is demonstrated for the first time that the intrinsically incompatible propylene carbonate (PC)-based electrolyte becomes completely compatible with graphite anodes by introducing a layer of adsorbed hexafluorobenzene (HFB) molecules to weaken the Li⁺-PC coordination strength and facilitate the interfacial desolvation process. As a consequence, the graphite/ NCM811 pouch cells using the PC-based electrolyte containing only 1 vol.% HFB demonstrate excellent long-term cycling stabilities over 1150 cycles. This strategy is also proved to be applicable to other ethylene carbonate (EC)–free electrolytes, thus providing a new avenue for developing advanced LIB electrolytes.     

一种宽电源电压带隙基准源的设计

提出一种可在宽电源电压范围下工作的带隙基准源设计.由于采用了一些新的结构,使得其电源抑制比和温度稳定性有明显提高.为支持电源管理芯片的休眠工作模式以降低待机功耗,电路中专门设置了一个辅助的微功耗基准,在正常模式下为电路提供偏置,在休眠模式中替代主基准以节省功耗.仿真结果表明,该基准源提供的1.27V基准电压在-20至120℃范围内的最大温漂为3.5mV.当供电电压由3V变化至40V时,基准电压的变化为56μV.在低于10kHz的频率范围内基准源具有大于100dB的电源抑制比.芯片采用1.5μm BCD(Bipolar-CMOS-DMOS)工艺设计与实现.实验结果证实上述设计目标已基本实现.     

Metal–Organic Framework Assisted and Tumor Microenvironment Modulated Synergistic Image‐Guided Photo‐Chemo Therapy

The complex tumor microenvironment (TME) and nonspecific drug targeting limit the clinical efficacy of photodynamic therapy in combination with chemotherapy. Herein, a metal–organic framework (MOF) assisted strategy is reported that modulates TME by reducing tumor hypoxia and intracellular glutathione (GSH) and offers targeted delivery and controlled release of the trapped chemodrug. Platinum(IV)‐diazido complex (Pt(IV)) is loaded inside a Cu(II) carboxylate‐based MOF, MOF‐199, and an aggregation‐induced‐emission photosensitizer, TBD, is conjugated to polyethylene glycol for encapsulating Pt(IV)‐loaded MOF‐199. Once the fabricated TBD‐Pt(IV)@MOF‐199 nanoparticles are internalized by cancer cells, MOF‐199 consumes intracellular GSH and decomposes to fragments to release Pt(IV). Upon light irradiation, the released Pt(IV) generates O₂ that relieves hypoxia and produces Pt(II)‐based chemodrug inside cancer cells. Concomitantly, efficient reactive oxygen species generation and bright emission are afforded by TBD, resulting in synergistic image‐guided photo‐chemo therapy with enhanced efficacies and mitigated side effects.     

基于变频技术降低空压机能耗的方法研究

本文主要是以变频器控制电机在空压机上的应用为背景,研究空压机变频调速控制方案,设计出变频调速、空气压缩、压力传感器、PLC调速器运行的控制方法。以解决在空压机变频改造中电机的调速性能、效率和运行可靠性提升的关键性问题。该研究为利用变频器来控制电机在空压机上的应用和普及提供理论依据。对于空压机的节能环保,提高产品性能和竞...     

具有简单线性补偿和准谐振导通的原边控制的单级反激式LED驱动器

A single-stage flyback driving integrated circuit （IC） for light-emitting diodes （LEDs） is proposed. With an average primary-side current estimation and negative feedback networks, the driver operates in the boundary conduction mode （BCM）, while the output current can be derived and regulated precisely. By means of a simple external resistor divider, a compensation voltage is produced on the ISEN pin during the turn-on period of the primary MOSFET to improve the line regulation performance. On the other hand, since the delay time between the time that the secondary diode current reaches zero and the turn-on time of the MOSFET can be automatically adjusted, the MOSFET can always turn on at the valley voltage even if the inductance of the primary winding varies with the output power, resulting in quasi-resonant switching for different primary inductances. The driving IC is fabricated in a Dongbu HiTek＇s 0.35μm bipolar-CMOS-DMOS process. An 18 W LED driver is finally built and tested. Results show that the driver has an average efficiency larger than 86%, a power factor larger than 0.97, and works under the universal input voltage （85-265 V） with the LED current variation within ±0.5%.     

EPON技术在平价商店物价监管平台建设中的应用

为满足物价部门对平价商店信息点价格数据采集和物价监管的需要,从网络系统的安全性、灵活性和易维护性等角度考虑,采用EPON组网技术,设计了一套平价商店物价监管网络服务支撑平台解决方案,并以六安市物价监管平台建设为例,阐述了网络建设中的网络架构、光分配网设计和多业务控制网关数据配置等具体实践。     

有线电视用户违章及稽查

当前,有线电视用户采用非法手段盗用有线电视信号、拖欠电视收视维护管理费甚至故意破坏有线电视传输网络设施等违章违法行为还比较普遍。分析有线电视用户的违章行为和产生违章行为的原因,介绍有线广播电视管理法规、用户稽查和违章行为的处理办法。     

移动电话资费管制的研究

伴随着中国电信行业,特别是移动电话用户数量的高速发展和有效市场竞争格局的初步建立,移动电话资费的调整、改革与管制等问题成为近几年社会各界关注的焦点.本文从电信管制理论出发,分析和介绍了电信资费管制理论的演进过程,进而对中国电信市场特别是移动电话资费的管制实践进行了系统研究,深入地分析了中国建立的新的移动电话资费管制体系,并对未来移动电话资费管制的发展趋势作了展望.     

用一种免疫遗传算法求解频率分配问题

频率分配是一NP完全问题,本文用一种基于免疫调节机制的免疫遗传算法来求解.该算法结构类似于遗传算法;核心思想是将个体集构造为抗体网络,利用免疫浓度调节机制在个体层次调节个体的多样性,同时利用免疫网络调节理论在种群层次调整个体多样性和群体收敛性之间的动态平衡,从而克服了一般遗传算法的不足.本文同时用该算法解决固定频率分配和最小跨度频率分配问题,取得了较好的效果.     

江西省中小河流岸坡整治技术集成及典型模式研究

本文在分析江西省中小河流存在的问题、治理现状等基础上,研究中小河流治理岸坡整治技术集成,并结合工程实例研究科学适用的解决方案和岸坡生态整治的典型模式,为江西省中小河流岸坡生态治理提供建议.