氧化沟模型处理亚麻沤制废水的研究

利用液可清(ACF32)培养污泥,水解酸化、氧化沟工艺进行亚麻沤制废水处理。结果表明,该系统处理高浓度有机废水效果良好,COD去除率可达95%-97%,TN去除率可达78%-82%,TP去除率可达78%-86%。     

A Modified Nonparametric Prewhitened Covariance Estimator

Abstract. This paper proposes a fully modified version of the spectral matrix estimator (and the long‐run variance estimator as a special case) proposed originally by Xiao and Linton [Journal of Time Series Analysis (2002) Vol. 23, pp. 215–250], and derives its asymptotic results. A striking feature of the modified spectral matrix estimator is to achieve the convergence rate of O(T ^?8/9) in the mean squared error (MSE), which is usually achieved under the fourth‐order spectral window. However, this estimator does not sacrifice the positive definiteness of the resulting estimate for the rate improvement; it is Hermitian and positive definite in finite samples by construction. The faster convergence rate is established by a multiplicative bias correction of the crude spectral estimator under the second‐order spectral window. The approximations to some sensible definitions of the MSE of the estimator and the bandwidths that minimize the asymptotic MSEs are also derived. Monte Carlo results indicate that for a wide variety of processes the modified spectral matrix estimator reduces the bias without inflating the variance and thus improves the MSE, compared with the crude, bias‐uncorrected estimator.     

Determination of the vapor pressures of select polychlorinated dibenzo-p-dioxins and dibenzofurans at 75-275 °C

Vapor pressures were determined for several polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) at 75-275 °C, extending the available literature data to more relevant temperature regions and providing the first experimental data for 2,3,7-trichlorodibenzo-p-dioxin (2,3,7-TriCD). A modification of the effusion technique, based upon controlling the diffusion of the target compound and subsequent high resolution gas chromatography/low resolution mass spectrometry (HRGC/LRMS) analysis, was proven comparable to other accepted methods for determining the vapor pressures of semi-volatile organic compounds (SVOCs). Vapor pressures for octachlorodibenzo-p-dioxin (OCDD) and octachlorodibenzofuran (OCDF) were in excellent agreement with those reported in literature. The application of the current method for the vapor pressure determinations of eight polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) in the extended temperature range (up to 275 °C) is reported. The extension of the vapor pressures to such temperatures, unprecedented for the PCDDs/Fs, is important for vapor-particle partitioning modeling in regions relevant to PCDD/F formation and control. Estimates for the melting temperatures and enthalpies of sublimation and vaporization are also reported, the latter for which no experimentally determined values have been found in the literature. The use of the method to deliver reproducible, trace concentrations (ppt-ppb) of targets was applied to the calibration of the jet-REMPI/TOFMS as an online detector for low chlorinated PCDDs/Fs.     

超高密度磁记录的课题与展望

介绍了超高密度记录的研究开发状况 ,论述了垂直磁记录技术的课题以及采用TMR磁头的、记录密度为Subterabit in2 的记录 读出特性。作为高密度记录所必需的头 盘界面技术 ,提出了接触记录技术的课题 ,还就STM (Scanningtunnelingmicroscopy)存储器论述了未来超高密度技术     

Premodification of Pt/γAl2O3 with Cinchonidine for the Enantioselective Hydrogenation of Ethyl Pyruvate: Effect of Premodification Conditions on Reaction Rate and Enantioselection

The premodification of a 5 wt% Pt/-Al₂O₃ catalyst with cinchonidine (0.01 and 0.2 g g^-1 _catalyst) is described and discussed. Premodification is carried out by treating the catalyst with a solution of cinchonidine followed by solvent removal. Catalysts premodified in this way give the same ee and initial rate of reaction for the enantioselective hydrogenation of ethyl pyruvate as those using the standard in situ modification procedure. Investigations of different solvents for premodification and reaction (dichloromethane, ethanol) show that it is the solvent used for the reaction that controls the observed enantioselection. Premodified catalysts also display the initial transient behavior typically observed with in situ modified catalysts in which the ee increases with conversion in the early part of the reaction. Premodified catalysts show an enhanced rate of reaction when ethanol is used as the reaction solvent compared with in situ modified catalysts under the same conditions. Premodification using aerobic conditions gives the best results and premodified catalysts can be stored prior to use for up to a week without loss of catalytic performance.     

广西饮用水水源地远程可视化监管系统设计

结合广西地区饮用水源保护的实际情况设计了一种新型的可视化远程监控系统可实现无人值守在线可靠监 控, 主要用于水源地现场可视化反馈并协助执法人员对水源地进行有效的监管保护, 获取各种周围环境信息, 并通 过执行器进行遥控。终端装置采用 STM32F103RBT6 单片机控制, 并通过 GPRS 网络接入局域网与联网的 PC 主 机进行网络通信, 配有 OV2640 摄像头与各种传感器以获取现场图片与各种参数。该设计在满足应用要求的情况 下, 尽可能降低设备成本。通过对传统监控方案改进, 新方案具有一定的潜在应用前景。     

Pd deposited on Cu(110): a highly performant catalyst for the 1,3-butadiene hydrogenation reaction

The catalytic properties, with respect to the 1,3-butadiene hydrogenation reaction, of strained Pd films on Cu(110) (lattice mismatch 8%) has been probed as a function of the film thickness. The characterization of the adlayer has been made by the combined use of STM with LEED and AES. For deposits below 10¹⁵ Pd/cm² (i.e., about 1 ML) the catalytic activity is near zero. This is the consequence of the formation of a Pd–Cu surface alloy with tendency for Cu to migrate/segregate to the surface. The catalytic activity suddenly increases to reach a maximum value for about 3 ML; the activity is then one order of magnitude higher than that of the pure Pd(110) surface. This is the consequence of the presence of a strained Pd overlayer, with Pd surface atoms having very unusual geometry, and hence very peculiar electronic and chemical properties. The catalytic activity then decreases as the Pd coverage is increased, and tends to values near that of the pure Pd(110). Gradual relaxation of the film geometry towards that of the normal fcc Pd structure probably exists.     

Experimental and theoretical study on H2/CO2 separation by a five-step one-column psa process

An experimental and theoretical study is performed for bulk separation of H₂/CO₂ mixture (70/30 volume %) by PSA process with zeolite 5A, a process widely used commercially in conjunction with the catalytic steam reforming of natural gas or naphtha. For the optimized adsorption conditions of PSA, the characteristics of adsorption/desorption characteristics have been studied through breakthrough and desorption experiments under various conditions. The purge-to-feed ratio is important to the H₂ product purity only at a long adsorption step time. H₂ could be concentrated from 70% in the feed to 99.99% at H₂ recovery of 67.5%. The results of all five steps in PSA are successfully predicted by the LDF model considering an energy balance and nonlinear isotherm. For the model, the effective diffusivities (D,) are obtained separately from the uptake curves of H₂ and CO₂. The Langmuir-Freundlich isotherm is used to correlate the experimental equilibrium data and is very well fitted to the results.     

Parameter Estimation for Periodically Stationary Time Series

Abstract. The innovations algorithm can be used to obtain parameter estimates for periodically stationary time series models. In this paper, we compute the asymptotic distribution for these estimates in the case, where the innovations have a finite fourth moment. These asymptotic results are useful to determine which model parameters are significant. In the process, we also develop asymptotics for the Yule–Walker estimates.     

PVC芯层发泡管的研制

PVC芯层发泡管除具备实壁管的性能外,还具有抗冲强度高、适用温度变化大、建筑下水隔音等优点,并且节省原材料25％～30％。通过试验确定了生产工艺要点。产品质量达到或超过了等效采用美国ASTM F891同类产品标准的企业标准。