Optical and thermal properties of poly(ethylene oxide) doped with MnCl2 salt

The optical and thermal properties of prepared poly(ethylene oxide)/MnCl₂ films were studied as a function of MnCl₂ concentration at room temperature. The observed optical energy gap (E_opt) and energy gap tail (ΔE) were determined from the measured absorption spectra. It was found that the optical energy gap decreases with MnCl₂ concentration, and the absorption coefficient reduces sharply at concentration of 5 wt% MnCl₂ compared with the neat PEO. Differential scanning calorimetry (DSC) measurement shows that the heat of fusion increases with the MnCl₂ concentration, while the melting point decreases. Correlation between the observed optical energy gap and heat of fusion is presented.     

Degradation of polyethylene terephthalate films in the presence of lubricants for HFC 134a: a critical issue for hermetic motor insulation systems

Earlier studies conducted in the use of sealed tubes with polyalkylene glycol lubricants and polyethylene terephthalete (PET) films revealed that the PET films exhibited embrittlement and (visual) degradation. This led to an investigation of PET embrittlement mechanisms with the new lubricants used with HFC 134a. The lubricants studied were three polypropylene glycols (the monol, the diol and the completely end-capped glycols), pentaerythritol ester and a blend of monol and ester. The effects of moisture content, temperature and lubricant structure were studied. All lubricants in this study were of viscosity grade ISO-32 (150 SUS). The results were compared to PET film embrittlement in the presence of CFC 12 and mineral oil. This study reconfirmed the earlier findings that the PET films must be dried to lower than 0.1 wt.% moisture content for use in hermetic systems. This paper discusses the effect of the moisture content of the lubricant and the effect of the lubricant structure on PET films. The dependence of the various mechanisms on temperature is shown. Esters and end-capped polyalkylene glycols are recommended for use with HFC 134a.     

CVD金刚石膜生长过程的Raman分析

采用激光Raman散射分析法对CVD金刚石膜的生长过程进行研究 ,讨论在金刚石膜生长的不同阶段 ,膜内金刚石和非金刚石成分的相对含量及其残余应力的变化情况     

Deposition mechanisms in langmuir-blodgett films

As part of a study of the possible application of polymerisable Langmuir-Blodgett (LB) films as ultra-fine-line e-beam resists, an investigation of the variation of film structure of 22-tricosenoic acid with differing deposition conditions has been made. Unexpected effects with significant implications for deposition speed and resist sensitivity have been observed, and the new techniques for film characterisation developed during the investigation have resulted in a revised model of deposition explaining the observed independence of the disorder causing optical scattering and the macroscopic features observed by polarised microscopy.     

纳米4-H碳化硅薄膜的掺杂现象

对纳米晶SiC薄膜进行了P和B的掺杂,B掺杂效率比P高,其暗电导预前因子与激活能遵守Meyer-Neldel规则,并有反转Meyer-Neldel规则出现.掺杂效率比非晶态碳化硅薄膜高是纳米碳化硅薄膜的特点之一.非晶态中的隧穿和边界透射对输运有一定贡献.     

非晶软磁合金的巨磁阻抗效应及应用

近来在ＦｅＣｏＳｉＢ等Ｃｏ基非晶体丝带中现了巨磁阻抗效应，由于在一小的直流纵向偏置场下该效应能使丝带两端的交流电压发生大而灵敏的变化，因而在磁记录头和传顺技术中具有巨大的应用科学潜能，受到各国学者的关注，本文简单介绍了巨磁阻抗效应的来源，并综述了近年来非晶体软磁合金材料的的巨磁阻抗效应及应用的研究进展，文章最后说明了尚待深入解决的问题。     

工艺条件对薄片陶瓷材料凝胶流延成型的影响

利用有机单体的聚合原理，成功进行了陶瓷薄片材料的凝胶流延成型。讨论了工艺条件对成型的影响。使用惰性气氛保护克服了单体聚合反应中的氧气阻聚问题，浆料在一定温度和气氛条件下能够顺利完成聚合反应。所成型的坯体具有良好的强度和柔韧性，在1550℃经2h烧结，烧结样品显微结构均匀，没有发现晶粒异常长大现象，烧结体致密度达到97．7％。     

电容位移法精确测量磁性薄膜的磁致伸缩系数

介绍了一种精确测量磁性薄膜磁致伸缩系数方法－电容位移法，并自行研制组装了一套测量装置，通过误差分析，仪器的精确标定，对稀土－铁超磁致伸缩薄膜的磁致伸缩系数进行了测量，获得满意的结果。     

Properties of Edible Films from Total Milk Protein

The mechanical properties and water vapor permeability of edible films made from various total milk proteins (TMPs) were investigated. Two TMPs obtained from nonfat dry milk (NDM) by removing lactose and three TMPs obtained from a commercial source were studied. Lactose was extracted from NDM by ultrafiltration or suspension in ethanol followed by filtration. TMP concentrate obtained by ultrafiltration (UF) produced films with the lowest water vapor permeability (WVP) and the highest tensile strength at break. Commercial TMP concentrates produced films more ductile than those from the UF-TMP or retentate from ethanol extraction. Further research is needed to improve mechanical properties of UF-TMP films without increasing the WVP.     

薄膜波导光隔离器和光电子单片集成技术

叙述了Ｂｉ，Ａｌ：ＹＩＧ薄膜的液相外延生长，研究了这种薄膜材料的光吸收系数、法拉第旋转角、磁光优值及生长感生磁各向异性与Ｂｉ含量的关系。在此基础上，连续外延生长了作单模磁光波导的双层Ｂｉ，Ａｌ：ＹＩＣ薄膜。光纤偏振器的使用使薄膜波导光隔离器向实用化迈进了一步，恒磁薄膜作偏磁场为器件集成化作出了贡献。采用ＭＯＣＶＤ技术，在ＧＧＧ（钆镓石榴石）基片上同时外延生长Ⅲ－Ⅴ族半导体薄膜和钇铁石榴石（ＹＩＧ）薄膜，把光隔离器和磁光光源直接集成在一起，是一种非常有前景的光电子集成组件。